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Influence of Anderson and Keggin heteropoly compounds as precursors of oxide phases in hydrotreating catalysts on their performance

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Abstract

Unpromoted and nickel-promoted catalysts were synthesized on the basis of the Anderson heteropoly compounds (NH4)6 − x [X x(OH)6Mo6O18] · nH2O, where heteroatom X is Cr(III), Mn(II), Fe(II), Ni(II), Co(II), Cu(II), Zn(II), or Ga(III), and their activity in the thiophene hydrogenolysis reaction and hydrofining of diesel fraction was examined. It was shown that the most active hydrotreating catalysts under the test conditions in a flow unit were the samples with X = Ni, Mn, or Zn. The catalysts synthesized from the Keggin heteropoly compounds H4[SiMo12O40] · 17H2O, H3[PMo12O40] · 19H2O, H3[PVMo11O40] · nH2O, and (NH4) x [V(MoO3)12] · nH2O were tested in the hydrofining of light coker gas oil. The maximum activity was displayed by the catalysts prepared on the basis of the vanadium-containing heteropoly compounds H3[PVMo11O40] · nH2O and (NH4) x [V(MoO3)12] · nH2O.

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  1. Samara State Technical University, Samara, Russia

    N. N. Tomina, P. A. Nikul’shin & A. A. Pimerzin

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  1. N. N. Tomina
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  2. P. A. Nikul’shin
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  3. A. A. Pimerzin
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Correspondence to P. A. Nikul’shin.

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Original Russian Text © N.N. Tomina, P.A. Nikul’shin, A.A. Pimerzin, 2008, published in Neftekhimiya, 2008, Vol. 48, No. 2, pp. 92–99.

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Tomina, N.N., Nikul’shin, P.A. & Pimerzin, A.A. Influence of Anderson and Keggin heteropoly compounds as precursors of oxide phases in hydrotreating catalysts on their performance. Pet. Chem. 48, 92–99 (2008). https://doi.org/10.1134/S0965544108020035

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