Skip to main content
Log in

Ethane aromatization on Ga-Pt pentasil zeolites

  • Published:
Petroleum Chemistry Aims and scope Submit manuscript

Abstract

Ethane aromatization on gallium-and platinum-modified pentasil zeolites (ZSM-5) with different framework constitutions was studied. The optimal zeolite composition and reaction conditions were determined and the synergistic effect of the promoters was revealed. The dependence of the catalyst activity on the SiO2/Al2O3 molar ratio was established. The highest yield of aromatic hydrocarbons (∼30%) and the highest selectivity for their formation from ethane (∼63%) were attained on the (2%Ga–0.3%Pt)/HZSM-5 bimetallic catalyst having SiO2/Al2O3 = 30.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. V. S. Arutyunov and A. L. Lapidus, Gazov. Prom-st., No. 3, 104 (2003).

  2. O. B. Braginskii, World Petrochemical Industry (Nauka, Moscow, 2003) [in Russian].

    Google Scholar 

  3. R. V. Zainutdinov, Neftegazov. Vertikal 65(16), 96 (2001).

    Google Scholar 

  4. O. V. Bragin, Usp. Khim. 50, 1994 (1981).

    CAS  Google Scholar 

  5. M. A. Baňares, Catal. Today 51, 319 (1999).

    Article  Google Scholar 

  6. A. Hagen and F. Roessner, Catal. Rev. Sci. Eng. 42, 403 (2000).

    Article  CAS  Google Scholar 

  7. Kh. M. Minachev, A. L. Lapidus, and A. A. Dergachev, in Proceedings of DMGK-Conference, Hamburg, 2001, p. 189.

  8. Kh. M. Minachev and A. A. Dergachev, Izv. Akad. Nauk, Ser. Khim., No. 6, 1071 (1998).

  9. D. Seddon, Catal. Today, No. 6, 351 (1998).

  10. T. Inui, Y. Marino, F. Okazumi, and A. Miyamoto, Stud. Surf. Sci. Catal. 37, 487 (1987).

    Google Scholar 

  11. R. V. Dmitriev, D. P. Shevchenko, E. S. Shpiro, et al., Stud. Surf. Sci. Catal. 69, 381 (1991).

    Article  CAS  Google Scholar 

  12. R. Fricke, H. Kosslick, G. Lischke, and M. Richter, Chem. Rev. 100, 2303 (2000).

    Article  CAS  Google Scholar 

  13. A. L. Lapidus, M. N. Mikhailov, A. A. Dergachev, and I. V. Mishin, Dokl. Akad. Nauk 408, 1 (2006).

    Google Scholar 

  14. A. L. Lapidus, M. N. Mikhailov, A. A. Dergachev, et al., React. Kinet. Catal. Lett. 87, 249 (2006).

    Article  CAS  Google Scholar 

  15. E. S. Shpiro, D. P. Shevchenko, M. S. Kharson, et al., Zeolites 12, 670 (1992).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to A. L. Lapidus.

Additional information

Original Russian Text © A.L. Lapidus, A.A. Dergachev, V.A. Kostina, A.A. Silakova, 2008, published in Neftekhimiya, 2008, Vol. 48, No. 2, pp. 83–86.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Lapidus, A.L., Dergachev, A.A., Kostina, V.A. et al. Ethane aromatization on Ga-Pt pentasil zeolites. Pet. Chem. 48, 83–86 (2008). https://doi.org/10.1134/S0965544108020011

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0965544108020011

Keywords

Navigation