Abstract
Ethane aromatization on gallium-and platinum-modified pentasil zeolites (ZSM-5) with different framework constitutions was studied. The optimal zeolite composition and reaction conditions were determined and the synergistic effect of the promoters was revealed. The dependence of the catalyst activity on the SiO2/Al2O3 molar ratio was established. The highest yield of aromatic hydrocarbons (∼30%) and the highest selectivity for their formation from ethane (∼63%) were attained on the (2%Ga–0.3%Pt)/HZSM-5 bimetallic catalyst having SiO2/Al2O3 = 30.
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References
V. S. Arutyunov and A. L. Lapidus, Gazov. Prom-st., No. 3, 104 (2003).
O. B. Braginskii, World Petrochemical Industry (Nauka, Moscow, 2003) [in Russian].
R. V. Zainutdinov, Neftegazov. Vertikal 65(16), 96 (2001).
O. V. Bragin, Usp. Khim. 50, 1994 (1981).
M. A. Baňares, Catal. Today 51, 319 (1999).
A. Hagen and F. Roessner, Catal. Rev. Sci. Eng. 42, 403 (2000).
Kh. M. Minachev, A. L. Lapidus, and A. A. Dergachev, in Proceedings of DMGK-Conference, Hamburg, 2001, p. 189.
Kh. M. Minachev and A. A. Dergachev, Izv. Akad. Nauk, Ser. Khim., No. 6, 1071 (1998).
D. Seddon, Catal. Today, No. 6, 351 (1998).
T. Inui, Y. Marino, F. Okazumi, and A. Miyamoto, Stud. Surf. Sci. Catal. 37, 487 (1987).
R. V. Dmitriev, D. P. Shevchenko, E. S. Shpiro, et al., Stud. Surf. Sci. Catal. 69, 381 (1991).
R. Fricke, H. Kosslick, G. Lischke, and M. Richter, Chem. Rev. 100, 2303 (2000).
A. L. Lapidus, M. N. Mikhailov, A. A. Dergachev, and I. V. Mishin, Dokl. Akad. Nauk 408, 1 (2006).
A. L. Lapidus, M. N. Mikhailov, A. A. Dergachev, et al., React. Kinet. Catal. Lett. 87, 249 (2006).
E. S. Shpiro, D. P. Shevchenko, M. S. Kharson, et al., Zeolites 12, 670 (1992).
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Original Russian Text © A.L. Lapidus, A.A. Dergachev, V.A. Kostina, A.A. Silakova, 2008, published in Neftekhimiya, 2008, Vol. 48, No. 2, pp. 83–86.
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Lapidus, A.L., Dergachev, A.A., Kostina, V.A. et al. Ethane aromatization on Ga-Pt pentasil zeolites. Pet. Chem. 48, 83–86 (2008). https://doi.org/10.1134/S0965544108020011
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DOI: https://doi.org/10.1134/S0965544108020011