Abstract
Aromatization of light hydrocarbons (propane, butane, propane-propene mixture, and cat-cracker off-gases) on ZnO-zeolite and lanthanide-zeolite catalysts based on zeolite TsVM (SiO2/Al2O3 = 62) and industrial catalyst SGK-1 was studied. It was shown that the modification of catalysts with lanthanides leads to an increase in both the total yield of xylenes and the p-xylene selectivity, a change that is explained by the formation of branched intermediates and steric specifics of their further conversion.
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References
S. M. Csicsery, J. Catal. 17, 205 (1970).
Y. Ono, H. Kitagava, and Y. Sendoda, Sekiyu Gakkaishi 30, 77 (1987).
Kh. M. Minachev and A. A. Dergachev, Izv. Akad. Nauk SSSR, Ser. Khim., No. 6, 18 (1993).
S. Abasov, S. Agaeva, F. Babayeva, et al., Georgia Chem. J., No. 1, 43 (2001).
S. I. Abasov, S. B. Agayeva, and D. B. Tagiyev, in Catalysis in Application, Ed. by S. D. Jakson, J. S. J. Hargeaves, and D. Lennon (2003), p. 302.
S. B. Agayeva, S. I. Abasov, B. A. Dadashov, and D. B. Tagiyev, Process. Petrochem. Refin., No. 4, 46 (2003).
N. Kumar, R. Byggningsbacka, M. Korpi, et al., Appl. Catal., A 277, 97 (2002).
N. S. Gnep, J. Tejeda, and M. Guisnet, Bull. Soc. Chim. Fr., No. 1/2, 5 (1982).
W. J. Frilette, Haaqwo, and R. M. Lago, J. Catal. 67, 218 (1981).
B. A. Dadashev, E. N. Popova, F. A. Yunusova, et al., Zh. Fiz. Khim. 62, 315 (1982).
S. B. Agayeva, B. A. Dadashov, S. I. Abasov, and D. B. Tagiyev, Stud. Surf. Sci. Catal. 135, 15 (2001).
S. B. Agaeva, Protsessy Neftekhim. Neftepererab., No. 2, 61 (2003).
B. K. Nefedov, Khim. Tekhnol. Topl. Masel, No. 9, 18 (1985).
T. M. Zhorov, Thermodynamics of Chemical Processes: Petrochemical Synthesis, Petroleum Refining, Coal and Natural Gas Processing (Khimiya, Moscow, 1985) [in Russian].
S. A. Isaev, T. V. Vasina, and O. V. Bragin, Izv. Akad. Nauk SSSR, Ser. Khim., No. 10, 2228 (1991).
A. V. Smirnov, E. V. Mazin, V. V. Yuschenko, et al., J. Catal. 194, 266 (2000).
A. V. Smirnov, E. V. Mazin, O. A. Ponomoreva, et al., Stud. Surf. Sci. Catal. 135, 5 (2001).
K. V. Kel’tsev, Basics of Adsorption Techniques (Khimiya, Moscow, 1984) [in Russian].
D. Breck, Zeolite Molecular Sieves (Wiley, New York, 1974; Mir, Moscow, 1976).
Neft Gaz Neftekhim. Rubezh., No. 11, 100 (1989).
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Original Russian Text © S.B. Agaeva, B.A. Dadashev, D.B. Tagiev, S.I. Abasov, 2007, published in Neftekhimiya, 2007, Vol. 47, No. 3, pp. 181–185.
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Agaeva, S.B., Dadashev, B.A., Tagiev, D.B. et al. Product control in catalytic aromatization of C2+ hydrocarbons. Pet. Chem. 47, 162–166 (2007). https://doi.org/10.1134/S0965544107030036
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DOI: https://doi.org/10.1134/S0965544107030036