Skip to main content
Log in

Volumetric properties of near-eutectic liquid Li–Pb alloys

  • Published:
Thermophysics and Aeromechanics Aims and scope

Abstract

The density and the thermal expansion of liquid lithium–lead alloys with Pb content of 83.0 and 84.3 at. % was measured using gamma-ray attenuation technique over the temperature range from liquidus to 1000 K. The density change during solid–liquid phase transition was directly measured for the first time for Li15.7Pb84.3 alloy. A comparison of the obtained results with literature data has been carried out.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. S. Malang, A.R. Raffray, and N.B. Morley, An example pathway to a fusion power plant system based on lead–lithium breeder: comparison of the dual-coolant lead-lithium (DCLL) blanket with the helium-cooled lead-lithium (HCLL) concept as initial step, Fusion Engng Design, 2009, Vol 84, P. 2145–2157.

    Article  Google Scholar 

  2. M. Hansen and K. Anderko, Constitution of Binary Alloys, McGraw-Hill, N.Y., 1958.

    Google Scholar 

  3. E. Mas de les Valls, L.A. Sedano, L. Batet, I. Ricapito, A. Aiello, O. Gastaldi, and F. Gabriel, Lead-lithium eutectic material database for nuclear fusion technology, J. Nuclear Materials, 2008, Vol 376, P. 353–357.

    Article  ADS  Google Scholar 

  4. P. Hubberstey, T. Sample, and M.G. Barker, Is Pb-17Li really the eutectic alloy? A redetermination of the leadrich section of the Pb–Li phase diagram (0.0 < X Li (at %) < 22.1), J. Nuclear Materials, 1992, Vol. 191–194, P. 283–287.

    Google Scholar 

  5. H. Okamoto, Li–Pb (Lithium–Lead), J. Phase Equilibria, 1993, Vol. 14, P. 770–771.

    Google Scholar 

  6. ASM Alloy Phase Diagram Database, URL: http://www1.asminternational.org/asmenterprise/apd/default.aspx.

  7. Springer Materials, URL: http://materials.springer.com.

  8. A.V. Semenov, A.V. Beznosov, A.A. Molodtsov, V.L. Konstantinov, and O.V. Baranova, Experimental studies of heat transfer for lead-lithium eutectics and corrosion properties, Voprosy Atomnoi Nauki i Tekhniki. Seriya: Termoyadernyi Sintez, 2006, No. 2, P. 40–49.

    Google Scholar 

  9. Y. Edao, H. Noguchi, and S. Fukada, Experiments of hydrogen isotope permeation, diffusion and dissolution in Li–Pb, J. Nuclear Materials, 2011, Vol 417, P. 723–726.

    Article  ADS  Google Scholar 

  10. State Diagrams of Binary Metal Systems, N.P. Lyakishev (Ed.), Vol. 3, Book 1, Mashinostroenie, Moscow, 2001.

  11. R.A. Khairulin, S.V. Stankus, and A.S. Kosheleva, The interdiffusion in melts of tin-lead system of eutectic and near-eutectic composition, High Temp., 2008, Vol 46, P. 212–217.

    Article  Google Scholar 

  12. S.V. Stankus and R.A. Khairulin, Measurement of the thermal properties of platinum in the temperature interval 293 K–2300 K by the method of penetrating radiation, High Temp., 1992, Vol 30, P. 386–391.

    Google Scholar 

  13. S.V. Stankus and P.V. Tyagel'sky, Thermal properties of Al2O3 in the melting region, Int. J. Thermophysics, 1994, Vol 15, P. 309–316.

    Article  ADS  Google Scholar 

  14. S.V. Stankus, R.A. Khairulin, and A.V. Baginsky, Thermodynamic and transfer properties of liquid perfluorobenzene and perfluorotriethyl amine, Thermophysics and Aeromechanics, 2001, Vol 8, P. 293–302.

    Google Scholar 

  15. O.F. Nemets and Yu.V. Gofman, Handbook of Nuclear Physics, Naukova dumka, Kiev, 1975.

    Google Scholar 

  16. E. Zen, Validity of "Vegard's law", American Mineralogist, 1956, Vol. 41, P. 523–524.

    Google Scholar 

  17. U. Jauch, G. Haase, V. Karcher, and B. Schulz, Thermophysical properties in the system Li–Pb. Pt. I–III, Kernforschungszentrum Karlsruhe Report 4144, 1986.

    Google Scholar 

  18. S.V. Stankus and R.A. Khairulin, The density of alloys of tin-lead system in the solid and liquid states, High Temp., 2006, Vol 44, P. 389–395.

    Article  Google Scholar 

  19. S.V. Stankus, R.A. Khairulin, and A.G. Mozgovoi, An experimental investigation of the density and thermal expansion of advanced materials and heat-transfer agents of liquid-metal systems of fusion reactor: Lead-lithium eutectic, High Temp., 2006, Vol 44, P. 829–837.

    Article  Google Scholar 

  20. B. Schulz, Thermophysical properties of the Li(17)Pb(83) alloy, Fusion Engng Design, 1991, Vol 14, P. 199–205.

    Article  Google Scholar 

  21. B.B. Alchagirov, A.G. Mozgovoi, T.M. Taova, and T.A. Sizhazhev, Thermal properties of promising tritium reproducing materials and coolants of the liquid metal blanket of fusion reactor: Lead-lithium eutectics, Perspektivnye Materialy, 2005, No. 6, P. 35–42.

    Google Scholar 

  22. J. Saar and H. Ruppersberg, Calculation of C p(T) for liquid Li/Pb alloys from experimental ρ(T) and (∂p/∂T)S data, J. Phys. F: Metal Physics, 1987, Vol 17, P. 305–314.

    Article  ADS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to R. A. Khairulin.

Additional information

The work was financially supported by the Russian Foundation for Basic Research (Grant No. 15-08-00275_a).

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Abdullaev, R.N., Agazhanov, A.S., Khairulin, R.A. et al. Volumetric properties of near-eutectic liquid Li–Pb alloys. Thermophys. Aeromech. 23, 247–253 (2016). https://doi.org/10.1134/S0869864316010116

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0869864316010116

Key words

Navigation