Abstract
Plate-tectonic paleogeodynamic setting of volcanic massive sulfide-bearing complexes of the Magnitogorsk island-arc megazone was reonstructed based on petrological-geochemical study and available geophysical data. The correlation between La/Yb ratio, Th, Yb, TiO2, and Zr concentrations in the basalts of ore regions, and ore volumes (Cu + Zn, in kt) in volcanic massive sulfide deposits was established. This indicates that the ore compositions and volumes in the ore-magmatic systems depend on the melting degree of suprasubduction mantle wedge. It was concluded that supraduction asthenospheric diapirs participated in the genesis of massive sulfide-bearing complexes. The obtained information can be used to predict new areas promising for massive sulfide mineralization.
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Notes
f ' = FeO + Fe2O3 + MgO + TiO2
al' = Al2O3/(FeO + Fe2O3 + MgO).
REFERENCES
Arculus, R.J., Aspects of magmagenesis in arcs, Lithos, 1994, vol. 33, pp. 189–208.
Avdeiko, G.P., Palueva, A.A., and Khleborodova, O.A., Geodynamic conditions of volcanism and magma formation in the Kurile–Kamchatka island-arc system, Petrology, 2006, vol. 14, no. 3, pp. 230–246.
Bailey, J.C., Frolova, T.I., and Burikova, I.A., Mineralogy, geochemistry and petrogenesis of Kurile island-are basalts, Contrib. Mineral. Petrol., 1989, vol. 102, pp. 265–280.
Berlyand, N.G., Glubinnoe stroenie i evolyutsiya litosfery Urala (Deep Structure and Evolution of the Lithosphere of the Urals), St. Petersburg: VSEGEI, 2007.
Bobokhov, A.S., Gorozhanin, V.M., and Kuz’min, S.A., Strontium-Isotope Dara on Felsic Voclanic rocks of the Magnitogorsk Megasynclinorium of the South Urals, Preprint Ufa: Prezidiumu BNTs UrO AN SSSR, 1989.
Bogatikov, O.A. and Tsvetkov, A.A., Magmaticheskaya evolyutsiya ostrovnykh dug (Magmatic Evolution of Island Arcs), Moscow: Nauka, 1988.
Bogatikov O.A., Kovalenko V.I., Sharkov E.V. Magmatizm, tektonika, geodinamika Zemli. Svyaz’ vo vremeni i v prostranstve (Magmatism, Tectonics, and Geodynamics of the Earth. Spatiotemporal Relation), Moscow: Nauka, 2010.
Borodaevskaya, M.B., Krivtsov, A.I., Shirai, E.P., Osnovy strukturno-formatsionnogo analiza kolchedanonosnykh provintsii (Principles of Strutucral-Formational Analysis of Sulfide-Bearing Provinces), Moscow: Nedra, 1977.
Chernyshev, I.V., Vikent’ev, I.V., Chugaev, A.V., et al., Sources of material for massive sulfide deposits in the Urals: evidence from the high-precision MC-ICP-MS isotope analysis of Pb in galena, Dokl. Earth Sci., 2008, vol. 418, no. 4, pp. 178–183.
Dobretsov, N.L. and Kirdyashkin, A.G., Glubinnaya geodinamika (Deep Geodynamics), Novosibirsk: SO RAN, 1994.
Dril’, S.I. and Elizarova, M.V., Geochemcial typification and sources of metamafic rocks of ophiolites of the western sector of the Mongolia–Okhotsk fold belt, Vulkanizm i geodinamika: Materialy II Vseros. simpoz. po vulkanologii i paleovulkanologii (Volcanism and Geodynamics of 2nd All-Russian Symposium on Volcanology and Paleovolcanology), Yekaterinburg: IGG UrO RAN, 2003, pp. 367–370.
Fershtater, G.B., Paleozoiskii intruzivnyi magmatizm Srednego i Yuzhnogo Urala (Paleozoic Intrusive Magmatism of the Middle and South Urals), Yekaterinburg: RIO UrO RAN, 2013.
Fox, J.S., Host-rock geochemistry and massive volcanogenic sulphide ores, Saskatchewan, Sask. Res. Council. Geol., 1978, vol. 2.
Franklin, J.M., Laydon, J.W., and Sangster, D.F., Volcanic-associated massive sulfide deposits, Econ. Geol., 1981, vol. 75, pp. 485–627.
Frolova, T.I. and Burikova, I.A., Geosinklinal’nyi vulkanizm (Geosynclinal Volcanism), Moscow: MGU, 1977.
Frolova, T.I. and Burikova, I.A., Magmaticheskie formatsii sovremennykh geotektonicheskikh obstanovok: Uch. Posobie (Magmatic Formations of the Modern Geotectonic Settings: A Textbook), Moscow: MGU, 1997.
Geokhimicheskaya i metallogenicheskaya spetsializatsiya strukturno-veshchestvennykh kompleksov (Geochemical and Metallogenic Specialization of Lithotectonic Complexes), Mezhelovskii, N.V. and Gusev, G.S, Eds., Moscow: MPR RF GosGeo, 1999.
Gill, J., Orogenic Andesites and Tectonics, Berlin: Springer Verlag, 1981.
Glukhov, Yu.V., Makeev, B.A., Varlamov, D.A., et al., Cr-spinels with zinc-bearing epigenetic rims from Devonian conglobreccias of the Ichet’yu placer (Middle Timan), Litosfera, 2015, no. 2, pp. 103–120.
Hutchinson, R.W., Volcanogenic sulfide deposits and their metallogenic significance, Econ. Geol., 1973, vol. 68, pp. 1223–1246.
Istoriya razvitiya Ural’skogo paleookeana (History of the Evolution of the Uralian Paleoocean), Zonenshain, L.P and Matveenkov, V.V., Eds., Moscow: Inst. Okeanol., 1984.
Ivanov, S.N., Perfilyev, A.S., Yefimov, A.A., et al., Fundamental features in the structure and evolution of the Urals, Am. J. Sci., 1975, vol. 275, pp. 107–130.
Jonas, P., Tectonostratigraphy of oceanic crustal terrains hosting serpentinite—associated massive sulfide deposits in the Main Uralian Fault Zone (South Urals), Geowissenschaften, 2004, vol. 498.
Karpukhina, V.S. and Baranov, E.N., Formy nakhozhdeniya elementov-indikatorov v oreolakh kolchedannykh mestorozhdenii (Speciation of Indicator Elements in Aureoles of Sulfide Ddeposits), Moscow: Nauka, 1983.
Khodorevskaya, L.I., Influence of fluid regime on melting of oceanic crust (experimental data) at 900–1000°C, 5–10 kbar, Granity i evolyutsiya Zemli: mantiya i kora v granitoobrazovanii. Materialy III Mezhdunarodnoi geologicheskoi konferentsii, 28–31 avgusta 2017 g., Ekaterinburg, Rossiya (Granites and Evolution of the Earth: Mantle and Crust in the Granite Formation. Proc. 3rd International Geological Conference, 2017, Yekaterinburg, Russia), Yekaterinburg: IGG UrO RAN, 2017, pp. 328–329.
Kosarev, A.M. and Artyushkova, O.V., Dzhusa paleovolcanic complex: stratigraphic position, geochemical features, and geodynamic reconstructions, Geologicheskii sbornik (Geological Collection of Papers), Ufa: DizainPoligrafServis, 2007, vol. 6, pp. 174–180.
Kosarev, A.M., Puchkov, V.N., and Seravkin, I.B., Petrological–geochemical features of the Early Devonian–Eifelian island arc volcanic rocks of the Magnitogorsk zone: geodynamic implications, Litosfera, 2005, no. 4, pp. 22-42.
Kosarev, A.M., Puchkov, V.N., and Seravkin, I.B., Petrological–geochemical features of the Middle Devonian—Early Carbonaceous island arc and collisional volcanic rocks of the Magnitogorsk zone: geodynamic implication, Litosfera, 2006, no. 1, pp. 3–21.
Kosarev, A.M., Puchkov, V.N., and Seravkin, I.B., Pyrite potential of the Southern Urals: correlation of Cu and Zn resources with geochemical characteristics of basalts of ore regions, Dokl. Earth Sci., 2010, vol. 435, no. 2, pp. 1633–1636.
Kosarev, A.M., Seravkin, I.B., and Kholodnov, V.V., Geodynamic and petrological–geochemical aspects of the zoning of the Magnitogorsk sulfide megazone at the South Urals, Litosfera, 2014, no. 2, pp. 3–25.
Krivtsov, A.I., Paleovulkanizm evgeosinklinal’nykh zon Urala i kolchedanoobrazovanie (Paleovolcanic Eugeosynclinal Zones of the Urals and Sulfide Formation), M.: Nedra, 1979. 168 s.
Kuzmin, M.I., Geokhimiya magmaticheskikh porod fanerozoiskikh podvizhnykh poyasov (Geochemistry of Magmatic Rocks of Phanerozoic Mobile Belts), Novosibirsk: Nauka, 1985.
Lutts, B.G., Geokhimiya okeanicheskogo i kontinental’nogo magmatizma (Geochemistry of Oceanic and Continental Magmatism), Moscow: Nedra, 1980.
Marakushev, A.A., Petrogenez i rudoobrazovanie: (geokhimicheskie aspekty) (Petrogenesis and Ore Formation: Geochemical Aspect), Moscow: Nauka, 1979.
Marakushev, A.A., Periodicheskaya sistema ekstremal’nykh sostoyanii khimicheskikh elementov (Periodical System of the Extreme State of Chemical Elements), Moscow: Nauka, 1987.
Maslennikov, V.V., Sedimentogenez, gal’miroliz i ekologiya kolchedanonosnykh paleogidrotermal’nykh polei (na primere Yuzhnogo Urala) (Sedimentogenesis, Halmyrolysis, and Ecology of Sulfide Paleohydrothermal Fields: Evidence from the South Urals), Miass: Geotur, 1999.
Maslov, V.A. and Artyushkova, O.V., Stratigrafiya i korrelyatsiya devonskikh otlozhenii Magnitogorskoi megazony Yuzhnogo Urala (Stratigraphy and Correlation of Devonian Deposius of the Magnitogorsk Megazone), Ufa: DizainPoligrafServis, 2010.
Mednokolchedannye mestorozhdeniya Urala: Usloviya formirovaniya (Copper Sulfide Deposits of the Urals: Conditions of Formation), Prokin, V.A, Seravkin, I.B, and Buslaev, F.P., Eds., Yekaterinburg: UrO RAS, 1992.
Murdmaa, I.O., Fatsii okeanov (Oceanic Facies), Moscow: Nauka, 1987.
Nakamura, N., Determination of REE, Ba, Fe, Mg, Na and K in carbonaceous and ordinary chondrites, Geochim. Cosmochim. Acta, 1974, vol. 38, no. 5, pp. 757–775.
Paleozoiskii vulkanizm i kolchedannye mestorozhdeniya Yuzhnogo Urala (Paleozoic Volcanism and Sulfide Deposits of the South Urals), Yakovlev, G.F, Avdonin, V.V, and Borodaev, Yu.S., Eds., Moscow: MGU,1968.
Palme, H. and O’Neill, H.St.C., Cosmogeochemical estimates of mantle composition, Treaise on Geochemistry, Amsterdam: Elsever, 2003, vol. 2.
Pearce, J.A., Geochemical fingerprinting of oceanic basalts applications to ophiolite classification and the search for Archean oceanic crust, Lithos, 2008, vol. 100, pp. 14–48.
Pearce, J.A., Lippard, S.J., and Roberts, S., Characteristics and tectonic significance of supra-subduction zone ophiolites, Marginal Basin Geology: Volcanic and Associated Sedimentary and Tectonic Processes in Modern and Ancient Marginal Basins, Geol. Soc., London, Spec. Publ., 1984, vol. 16, pp. 77–94.
Perfil’ev, F.S., Formirovanie zemnoi kory Ural’skoi geosinklinali (Formation of the Earth Crust of the Uralian Geosyncline), Moscow: Nauka, 1979, vol. 328.
Petrologiya i geokhimiya ostrovnykh dug i okrainnykh morei (Petrology and Geochemistry of Island Arcs and Marginal Seas), Bogatikov, O.A, Eds., Moscow: Nauka, 1979.
Puchkov, V.N., Paleogeodinamika Yuzhnogo i Srednego Urala (Paleogeodynamics of the Southern and Middle Urals), Ufa: GILEM, 2000.
Puchkov, V.N., Geologiya Urala i Priural’ya (aktual’nye voprosy stratigrafii, tektoniki, geodinamiki i metallogenii) (Geology of the Urals and Cis-Urals: Urgent Questions of Stratigraphy, Tectonics, Geodynamics, and Metallogeny), Ufa: DizainPoligrafServis, 2010.
Puchkov, V.N., General features relating to the occurrence ofmineral deposits in the urals: what, where, when and why, Ore Geol. Rev., 2017, vol. 85, pp. 4–29.
Pushkarev, E.V., Petrologiya Uktusskogo dunit-klinopiroksenit-gabbrovogo massiva (Srednii Ural) (Petrology of the Uktus Dunite–Clinopyroxenite–Gabbro Massif (Middle Urals)), Yekaterinburg: UrO RAN, 2000.
Ringwood, A.E., Sostav i petrologiya mantii Zemli (Composition and Petrology of the Earth’s Mantle), London–New York: McGraw, 1975.
Ryabchikov, I.D., Orlova, G.P., Kalenchuk, G.E., et al., Experimental study of mobilization of copper and nickel sulfides by aqueous—alkaline fluids at high temperature and pressure of 20 kbar, Dokl. Akad. Nauk SSSR, 1987, vol. 296, no. 2, pp. 437–440.
Scarrow, J.H., Hetzel, R., Gorozhanin, V.M., et al., Four decades of geochronological work in the southern and Middle Urals: a review, Mountain Building in the Uralides: Pangea to the Present. Geophys. Monogr., 2002, vol. 132, pp. 233–255.
Seravkin, I.B., Vulkanizm i kolchedannye mestorozhdeniya Yuzhnogo Urala (Volcanism and Sulfide Deposits of the South Urals), Moscow: Nauka, 1986.
Seravkin, I.B. and Tsvetkova, A.A., Structure of the Magnitogorsk meganticlinorium based on paleovolcanological reconstructions and geophysical data, Vulkanizm i rudoobrazovanie Urala (Volcanism and Ore Formation of the Urals), Ufa: BFAN SSSR, 1982, pp. 9–32.
Sharapov, V.N., Akimtsev, V.A., Dorovskii, V.N., et al., Dinamika razvitiya rudno-magmaticheskikh sistem zon spredinga (Dynamics of Evolution of the Ore-Magmatic Systems of the Spreading Zones), Novosibirsk: SO RAN, NITs OIGGM, 2000.
Sharfman, V.S., Paleovulkanologicheskie rekonstruktsii (Paleovolcanological Reconstructions), Moscow: Nedra, 1989.
Simonov, V.A., Kurenkov S.A., and Stupakov, S.I., Boninitic series in the paleospreading complexes of the Polar Urals, Dokl. Akad. Nauk SSSR, 1998, vol. 361, no. 2, pp. 232–235.
Smirnov, V.I., Sulfide deposits, Genezis endogennykh rudnykh mestorozhdenii (Genesis of Endogenous Ore Deposits), Moscow: Nedra, 1968, pp. 586–647.
Smolkin, V.F., Borisova, V.V., Svetov, S.A., and Borisov, A.E., Late Archean komatiites of the Ura Bay–Titovka structure, northwestern Kola Region, Petrology, 2000, vol. 8, no. 2, pp. 177–200.
Sobolev, A.V., Portnyagin M.V., Dmitriev L.V., et al., Petrology of ultramafic lavas and associated rocks of the Troodos Massif, Cyprus, Petrology, 1993, vol. 1, no. 4, pp. 331–361.
Saunders, A.D. and Tarney, J., Geochemical characteristics of basaltic volcanism within back-arc basins, Marginal Basin Geology: Volcanic and Associated Sedimentary and Tectonic Processes in Modern and Ancient Marginal Basins, Geol. Soc., London, Spec. Publ., 1984, vol. 16, pp. 59–76.
Spadea, P., D’Antonio, M., Kosarev, A., et al., Arc-continent collision in the Southern Urals: petrogenetic aspects of the forearc-arc complex, Mountain Building in the Uralides: Pangea to the Present. Geophys. Monogr., 2002, vol. 132, pp. 101–134.
Stratigrafiya i korrelyatsiya srednepaleozoiskikh vulkanogennykh kompleksov osnovnykh mednokolchedannykh raionov Yuzhnogo Urala (Stratigraphy and Correlation of the Middle Paleozoic Volcanogenic Complexes of Main Copper Sulfide Districts of the South Urals) Maslov, V.A, Cherkasov, V.A, Tishchenko, V.T, Eds., Ufa: UNTs RAS, 1993.
Sun, S.S. and McDonough, W.F., Chemical and systematics of oceanic basalts: implication for mantle compositions and processes, Magmatism in the Ocean Basins, eds.
Saunders, A.D. and Norry, M.J., Geol. Soc., London: Spec. Publ., 1989, vol. 42, pp. 315–345.
Tatsumi, Y., Hamilton, D.L., and Nesbitt, R.W., Chemical characteristics of phase released from a subducted lithosphere and origin of arc magmas: evidence from high-pressure experiments and natural rocks, J. Volcanol. Geotherm. Res., 1986, vol. 29, pp. 293–309.
Tesalina, S.G., Maslennikov, V.V., and Surin, T.N., Aleksandrinskoe medno-tsinkovo-kolchedannoe mestorozhdenie (Vostochno-Magnitogorskaya paleoostrovoduzhnaya duga, Ural) (Aleksandrinskoe Copper–Zing–Sulfide Deposit (Eastern Magnitogorsk Paleoisland Arc, Urals), Miass: IMin UrO RAN, 1998. 228 s.
Trondhjemites, Dacites and Related Rocks, Barker, F., Eds., Amsterdam: Elsevier, 1979.
Vikentiev, I.V., Usloviya formirovaniya i metamorfizm kolchedannykh rud (Conditions of Formation and Metamorphism of Sulfide Ores), Moscow: Nauchnyi mir, 2004.
Vikent’ev, I.V., Chernyshev, I.V., Chugaev, A.V., and Shatagin, K.N., Lead isotope systematics of sulfide deposits of the Urals based on precisionMC-ICP-MS isotope data, Izotopnoe datirovanie protsessov rudoobrazovaniya, magmatizma, osadkonakopleniya i metamorfizma (Isotope Dating of Ore Formation, Magmatism, Sedimentation, and Metamorphism), Moscow: GEOS, 2006, Vol. 1, pp. 155–160.
Vikentiev, I.V., Borisova, A.Yu., Karpukhina, V.S., et al., Direct data on the ore potential of acid magmas of the Uzel’ginskoe Ore Field (Southern Urals, Russia), Dokl. Earth Sci., 2012, vol. 443, no. 1, pp. 401–405.
Volynets, O.N., Antipin, V.S., Perepelov, A.B., and Anoshin, G.N., Geochemistry of island-arc volcanic series with reference to geodynamics (Kamchatka), Geol. Geofiz., 1990, no. 5, pp. 3–13.
Vulkanizm Yuzhnogo Urala (Volcanism of the South Urals), Seravkin, I.B, Kosarev, A.M, Salikhov, D.N, Eds., Moscow: Nauka, 1992.
Vysotskii, S.V., Ofiolitovye assotsiatsii ostrovoduzhnykh sistem Tikhogo okeana (Ophiolite Associations of the Island-Arc Systems of the Pacific Ocean), Vladivostok: DVO AN SSSR, 1989.
Yazeva, R.G., Geochemical Criteria for Formational Analysis of Copper-Bearing Complexes of the Uralian Eugeosyncline, Preprint. Sverdlovsk: UNTs AN SSSR, 1985.
Zaikov, V.V., Vulkanizm i sul’fidnye kholmy paleookeanicheskikh okrain (Volcanism and Sulfide Mounds of Paleooeanic Margins), Moscow: Nauka, 2006.
Zaikov, V.V., Maslennikov, V.V., Zaikova, E.V., and Harrington, R., Rudno-formatsionnyi i rudno-fatsial’nyi analiz kolchedannykh mestorozhdenii Ural’skogo paleookeana (Ore-Formation and Ore-Facies Analysis of Sulfide Deposits of the Uralian Paleoocean), Miass: IMin UrO RAN, 2001.
Zaikov, V.V., Melekestseva, I.Yu., Artem’ev, D.I., et al., Geologiya i kolchedannoe orudenenie yuzhnogo flanga Glavnogo Ural’skogo razloma (Geology and Sulfide Mineralization of the Southern Flank of the Main Ural Fault), Miass: IMin UrO RAN, 2009.
ACKNOWLEDGMENTS
We are grateful to I.V. Vikentiev and A.I. Khanchuk for support and discussion of materials. Authors are grateful to reviewers for their great work on analyzing our materials and for valuable highly qualified comments that significantly improved the manuscript.
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The work was supported by the State Task no. 0246-2019-0078 and program no. 8 of the Presidium of the Russian Academy of Sciences.
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Kosarev, A.M., Puchkov, V.N., Seravkin, I.B. et al. Volcanic Massive Sulfide Complexes of the Magnitogorsk Paleoisland Arc Megazone in the Southern Urals: Models of Ore-Magmatic System and Geodynamic Reconstructions. Petrology 30, 82–106 (2022). https://doi.org/10.1134/S0869591122010052
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DOI: https://doi.org/10.1134/S0869591122010052