Abstract
The results of experimental studies of the composition and specific features of humic substance isolated from typical soils of natural zones are given. The stability constants of metal complexes with humic substance are evaluated. The obtained experimental data are used to calculate the occurrence forms of metals in natural waters in the zones of taiga, forests, and steppes. The occurrence forms of metals are shown to be determined by the general chemistry of natural waters rather than stability constants of complexes with organic matter.
Similar content being viewed by others
References
Batler, Dzh., Ionnye ravnovesiya (Ionic Equilibriums), Leningrad: Khimiya, 1973.
Varshal, G.M., Migration Forms of Fulvic Acids and Metals in Natural Waters, Extended Abstract of Doctoral (Chem.) Dissertation, Moscow: GEKhI RAN, 1994.
Varshal, G.M., Koshcheeva, I.Ya., Sirotkina, I.S., et al., Studying organic substances in surface waters and their interaction with metal ions, Geokhimiya, 1979, no. 4, pp. 598–608.
Venitsianov, E.V., and Lepikhin, A.P., Fizikokhimicheskie osnovy modelirovaniya migratsii i transfor-matsii tyazhelykh metallov v prirodnykh vodakh (Physicochemical Fundamentals of Simulation of Migration and Transformation of Heavy Metals in Natural Waters), Yekaterinburg: RosNIIVKh, 2002.
Vydra, F., Shtulik, K., and Yulakova, E., Inversionnaya vol’tamperometriya (Inversion Voltammetry), Moscow: Mir, 1980.
Derrfel’, K., Statistika v Analiticheskoi Khimii (Statistics in Analytical Chemistry), Moscow: Mir, 1994.
Zhulidov, A.V., Physicochemical and chemical state of metals in natural waters: toxicity for freshwater organisms, in Ekologicheskoe normirovanie i modelirovanie antropogennogo vozdeistviya na vodnye ekosistemy (Ecological Standardization and Simulation of Anthropogenic Impact on Aquatic Organisms), Leningrad: Gidrometeoizdat, 1988, issue 1, pp. 78–82.
Intsedi, Ya., Primenenie kompleksov v analiticheskoi khimii (The Use of Complexes in Analytical Chemistry), Budapest: Mir, 1979.
Kovalevskii, D.V., Studying HA Structure by NMR Methods 1N and 13S, Extended Abstract of Cand. Sci. (Chem) Dissertation, Moscow: Izd. MGU, 1998.
Lapin, I.A., and Krasyukov, V.N., The role of humic substances in the processes of complex formation and migration of heavy metals in surface waters, Vodn. Resur., 1986, no. 1, pp. 134–145.
Linnik, I.A., and Nabivanets, B.I., Formy migratsii metallov v presnykh poverkhnostnykh vodakh (Migration Forms of Metals in Fresh Surface Waters), Leningrad: Gidrometeoizdat, 1985.
Lur’e, Yu.Yu., Spravochnik po analiticheskoi khimii (Reference Book on Analytical Chemistry), Moscow: Khimiya, 1989.
Moiseenko, T.I., and Gashkina, N.A., The distribution of trace elements in surface continental waters and the character of their migration in water, Water Resour., 2007, vol. 34, no. 4, pp. 423–437.
Moiseenko, T.I., Kudryavtseva, L.P., and Gashkina, N.A., Rasseyannye elementy v poverkhnostnykh vodakh sushi: tekhnofil’nost’, bioakkumulyatsiya i ekotoksikologiya (Trace Elements in Surface Continental Waters: Technophilicity, Bioaccumulation and Ecotoxicology), Moscow: Nauka, 2006.
Nikanorov, A.M., and Zhulidov, A.V., Biomonitoring metallov v presnovodnykh ekosistemakh (Biomonitoring of Metals in Freshwater Ecosystems), Leningrad: Gidrometeoizdat, 1991.
Orlov, D.S., Khimiya pochv (Soil Chemistry), Moscow: Mir, 1985.
Rodyushkin, I.V., Main Regularities in Metal Distributions among Forms in Surface Waters of the Kola North, Cand. Sci. (Geol.-Miner.) Dissertation, St. Petersburg: Inst. of Limnology, 1995.
Skug, D., and Uest, D., Osnovy analiticheskoi khimii (Fundamentals of Analytical Chemistry), Moscow: Mir, 1979.
Fedorov, A.A., and Kaziev, G.Z., Monitoring prirodnoi sredy (Environmental Monitoring), Moscow: Prometei, 2003.
Hartly, F., and Berges, K., Ravnovesiya v rastvorakh (Equilibria in Solutions), Moscow: Mir, 1983.
Shlefer, G.L., Kompleksoobrazovanie v rastvorakh (Complex Formation in Solutions), Moscow: Khimiya, 1969.
Eriksund, E., and Hurlen, T., Humic substances and their role in the environment, J. Electroanal. Chem., 1972, no. 36, pp. 311–317.
Ernst, R., and Allen, H.E., Mancy, K.H., Characterization of trace metal species and measurement of trace metal stability constants by electrochemical techniques, Water Res., 1975, vol. 9, no. 11, pp. 969–979.
Fish, W., and Morel, F.M.M., Characterization of organic copper-complexing agents released by daphnia magna, Can. J. Fish. Aquat. Sci., 1983, vol. 40, no. 8, pp. 1270–1277.
Florence, T.M., The speciation of trace elements in waters, Talanta, 1982, vol. 5, pp. 345–364.
Forstner, U., and Wittmann, G.T.W., Metall Pollution in the Aquatic Environment, London: Springer-Verlag, 1979.
Heath, A.G., Water Pollution and Fish Physiology, London: Lewis Publishers, 2002.
Housepian, B.K., and Shain, I., Corrosion potentiometry and potentiometric titration with dropping amalgam electrode, J. Electroanal. Chem., 1966, vol. 12, no. 397, pp. 347–353.
Isaha, S.K., Dutta, S.L., and Chakravarti, S.K., Polarographic study of metal-humic acid interaction. Determination of stability constants of Cd and Znhumic acid complexes at different pH, J. Indian Chem. Soc., 1979, vol. 56, no. 1, pp. 1128–1134.
Knight, D.M., and Morel, F.M.M., Copper complexation by siderophores from filamentous blue-green algae, Limnol. Oceanog., 1980, vol. 25, no. 1, pp. 62–71.
Mannio, J., Responses of Headwater Lakes to Air Pollution Changes in Finland. Añademic dissertation, New York: University of Helsinki, 2001.
Mantoura, R.F.C., Dickson, A., and Riley, J.P., The complexation of metals with humic materials in natural waters, Estuar. Coastal Mar. Sci., 1978, vol. 6, no. 15, pp. 387–408.
McKnight, D.M., and Morel, F.M.M., Copper complexation by siderophores from filamentous blue-green algae, Limnol. Oceanogr., 1980, vol. 25, no. 1, pp. 62–71.
Moiseenko, T.I., The fate of metals in arctic surface waters. Method for defining critical levels, The Science of the Total Environment, 1999, vol. 2, no. 36, pp. 19–39.
Paxeus, N., and Wedborg, M., Calcium binding in aquatic fulvic acid, Anal. Chim. Acta, 1985, no. 169, pp. 87–93.
Ramamoorthy, S., and Manning, P.G., Equilibrium studies of metal-ion complexes of interest to natural waters. Fulvate-phosphate, fulvate-NTA and NTA-phosphate complexes of Pb2+, Cd2+ and Zn2+, J. Inorg. Nucl. Chem., 1974, vol. 36, no. 3, pp. 695–698.
Schnitzer, M., and Khan, S.U., Reactions of humic substances with metal ions and hydrous oxides, Humic Substances in the Environment, New York: Marcel Dekker, 1972, pp. 203–251.
Stumm, W., and Bilinski, H., Trace metals in natural waters: difficulties of interpretation arising from our ignorance of their speciation, Advances in Water Pollution Research, no. 5, Pergamon Press, 1979, pp. 39–49.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © T.I. Moiseenko, M.I. Dinu, N.A. Gashkina, T.A. Kremleva, 2013, published in Vodnye Resursy, 2013, Vol. 40, No. 4, pp. 375–385.
Rights and permissions
About this article
Cite this article
Moiseenko, T.I., Dinu, M.I., Gashkina, N.A. et al. Occurrence forms of metals in natural waters depending on water chemistry. Water Resour 40, 407–416 (2013). https://doi.org/10.1134/S009780781304009X
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S009780781304009X