Abstract
Many companies use two-phase absorbents (CaCO3 suspension) for waste gases purification from SO2. A qualitative theoretical analysis of the absorption kinetics in the cases of two-phase absorbent, using the convection-diffusion type of model, is presented. It is shown that the low CaCO3 concentration lead to very small chemical reaction rate and as a result the absorption rate is limited by the physical absorption of SO2 in water, i.e. the process efficiency is very small. An average concentration model for quantitative analysis of the absorption process and an iterative numerical algorithm for the model equations solution is proposed.
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Chr. B. Boyadjiev, “On the purification of gases containing impurities of small concentrations,” Hungarian J. Ind. Chem. 30, 103–105 (2002).
Chr. B. Boyadjiev, “On the SO2 problem in power engineering,” in Proceedings of Energy Forum, Varna, Bulgaria, June 15–19, 2011, pp. 114–125.
Chr. B. Boyadjiev, “On the SO2 problem in power engineering,” in Proceedings Asia-Pacific Power and Energy Eng. Conf. (APPEEC 2012). Shanghai, China, March 27–29, 2012, vol. 1.
V. M. Ramm, Gas Absorption (Khimiya, Moscow, 1956) [in Russian].
F. R. E. Danckwerts, Gas-Liquid Reactions (McGraw-Hill, N.Y., 1970).
Chr. B. Boyadjiev, M. Doichinova, and P. Popova, “On the SO2 problem in power engineering,” Trans. of Academenergo 44–65 (2012).
Chr. B. Boyadjiev, P. Popova, and M. Doichinova, “On the SO2 problem in power engineering,” in Proceedings of 15th Workshop on Transport Phenomena in Two-Phase Flow, Sunny Beach Resort, Bulgaria, Sept. 17–22, 2011, pp. 104–115.
Chr. B. Boyadjiev, “Mechanism of gas absorption with two-phase absorbents,” Int. J. Heat and Mass Transfer 54, 3004–3008 (2011).
Chr. B. Boyadjiev, “Diffusion models and scale-up,” Int. J. Heat and Mass Transfer 49, 796–799 (2006).
Chr. B. Boyadjiev, Theoretical Chemical Engineering, Modelling and Simulation (Springer-Verlag, Berlin, Heidelberg, 2010).
M. Doichinova and Chr. B. Boyadjiev, “On the column apparatuses modelling,” Int. J. Heat and Mass Transfer 55, 6705–6715 (2012).
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Published in Russian in Teploenergetika.
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Boyadjiev, C. On the SO2 problem of solid fuel combustion. Therm. Eng. 61, 691–695 (2014). https://doi.org/10.1134/S0040601514090031
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DOI: https://doi.org/10.1134/S0040601514090031