Abstract
We discuss an equilibrium model of a fixed-bed solid fuel gasification process that takes into account macrokinetic constraints imposed on the rates of heterophase processes and allows the pyrolysis and gasification processes to be described in a fairly simple manner with the use of thermal analysis data. The results of calculations are compared with the measured parameters characterizing the Azeisk coal steam-air gasification process that were obtained in experiments on a laboratory setup.
Similar content being viewed by others
References
M. L. De Souza-Santos, Solid Fuels Combustion and Gasification. Modeling, Simulation, and Equipment Operation (Marcel Dekker Inc., New York, 2004).
B. M. Kaganovich, A. V. Keiko, V. A. Shamanskii, et al., Thermodynamic Modeling Technology. Reduction of Motion Models to Static Models (Nauka, Novosibirsk, 2010) [in Russian].
B. M. Kaganovich, S. P. Filippov, A. V. Keiko, and V. A. Shamanskii, “Thermodynamic models of extreme intermediate states and their applications in power engineering,” Thermal Engineering, 58(2), 143 (2011).
S. Jarungthammachote and A. Dutta, “Equilibrium modeling of gasification: Gibbs free energy minimization approach and its application to spouted-bed and spouted-fluid bed gasifiers,” Energy Convers., Manag. 49, 1345 (2008).
I. Hannula and E. Kurkela, “A semi-empirical model for pressurized air-blown fluidized-bed gasification of biomass,” Bioresource Technol. 101, 4608 (2010).
M. Puig-Arnavat, J. C. Bruno, and A. Coronas, “Modified thermodynamic equilibrium model for biomass gasification: a study of the influence of operating conditions,” Energy and Fuels 26, 1385 (2012).
N. S. Barman, S. Ghosh, and S. De, “Gasification of biomass in a fixed bed downdraft gasifier: a realistic model including tar,” Bioresource Technol. 107, 505 (2012).
D. A. Svishchev, A. N. Kozlov, and A. V. Keiko, “Consideration of macrokinetics in constructing thermodynamic models of fixed-bed gasification processes,” Nauch.-Tekhn. Vedom. SPbGTU, No. 1 (53) 18–24 (2008).
A. Kozlov, D. Svishchev, I. Donskoy, and A. V. Keiko, “Thermal analysis in numerical thermodynamic modeling of solid fuel conversion,” J. Therm. Analysis, Carorim. 109(3), 1311 (2012).
I. A. Kuzovatov, A. A. Groo, and S. G. Stepanov, “Numerical modeling of physicochemical processes in a fixed-bed gasifier,” Vychisl. Tekhnol. 10(5), 39–48 (2005).
I. G. Donskoi, V. A. Shamanskii, A. V. Keiko, et al., “An equilibrium model of fixed-bed coal gasification with distributed parameters,” in Proceedings of the 8th All-Russia Conference “Solid Fuel Combustion” with International Participation, Novosibirsk, November 13–16, 2012 (IT SO RAN, Novosibirsk, 2012), pp. 39.1–39.8.
Z. F. Chukhanov, Some Problems of Fuel and Power Engineering (Akad. Nauk SSSR, Moscow, 1961) [in Russian].
A. Kozlov, D. Svishchev, I. Donskoy, and A. V. Keiko, “Kinetics of thermochemical conversion of Azeisky coal,” in Proceedings of the 15th International Congress on Thermal Analysis and Calorimetry, Kinki Univ., Higashi-Osaka, Japan, August 20–24, 2012. [On a CD].
I. G. Donskoi and V. A. Shamanskii, “A numerical investigation of a coal gasification process and influence of operating parameters on its intensity,” in Proceedings of the 8th All-Russia Conference “Solid Fuel Combustion” with International Participation, Novosibirsk, November 13–16, 2012 (IT SO RAN, Novosibirsk, 2012), pp. 38.1–38.7.
B. M. Kaganovich, A. V. Keiko, V. A. Shamansky, and M. S. Zarodnyuk, “On the interrelations between kinetics and thermodynamics as the theories of trajectories and states,” in Chemical Kinetics, Ed. by V. Patel, (Intech, 2012), pp. 31–60.
A. V. Keiko, D. A. Svishchev, A. N. Kozlov, and I. G. Donskoi, “Studying the controllability of processes for thermochemical conversion of solid fuel in a bed,” Thermal Engineering, 59(4), 302 (2012).
Author information
Authors and Affiliations
Additional information
Original Russian Text © I.G. Donskoi, A.V. Keiko, A.N. Kozlov, D.A. Svishchev, V.A. Shamanskii, 2013, published in Teploenergetika.
Rights and permissions
About this article
Cite this article
Donskoi, I.G., Keiko, A.V., Kozlov, A.N. et al. Calculation of the fixed bed coal gasification regimes by the use of thermodynamic model with macrokinetic constraints. Therm. Eng. 60, 904–909 (2013). https://doi.org/10.1134/S0040601513120069
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0040601513120069