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Flame Retardant Strategies and the Physical Barrier Effect of Nanoparticles to Improve the Thermal Performance of a Polymer

  • NANOMATERIALS AND NANOTECHNOLOGIES
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Abstract

An analysis of various types of flame retardants in polymer nanocomposites is presented. The mechanisms of action of fire retardants and their influence on the thermal stability and fire resistance of polymer composites are considered. The use of nanoparticles of inorganic compounds as flame retardants is shown to be promising. The synergistic effect of the use of nanoparticles together with traditional flame retardants is noted.

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REFERENCES

  1. Kiliaris, P. and Papaspyrides, C.D., Polymer/layered silicate (clay) nanocomposites: An overview of flame retardancy, Prog. Polym. Sci., 2010, vol. 35, pp. 902–958.

    Article  CAS  Google Scholar 

  2. Alarie, Y., Toxicity of fire smoke, Crit. Rev. Toxicol., 2002, vol. 32, pp. 259–289.

    Article  CAS  PubMed  Google Scholar 

  3. Hirschler, M.M., Fire hazard and toxic potency of the smoke from burning materials, J. Fire Sci., 1987, vol. 5, pp. 289–307.

    Article  CAS  Google Scholar 

  4. Shcheglov, P.P. and Ivannikov, V.L., Fire Retardancy of Polymeric Materials, Moscow: Stroiizdat, 1992.

    Google Scholar 

  5. Stefanidou, M. and Athanaselis, S., Health impacts of fire smoke inhalation, Inhalation Toxicol., 2008, vol. 20, pp. 761–766.

    Article  CAS  Google Scholar 

  6. Wilkie, C.A. and Morgan, A.B., Fire Retardancy of Polymeric Materials, Boca Raton, Fla.: CRC, 2010, Ch. 19, pp. 581–601.

    Google Scholar 

  7. Sutker, B.J., Flame retardants, in Ullman’s Encyclopedia of Industrial Chemistry, Gerhartz, W., Ed., Weinheim, Germany: Wiley-VCH, 2002, vol. 14, pp. 1–19.

    Google Scholar 

  8. Joseph, P. and Tretiakova-Mcnally, S., Reactive modifications of some chain- and stepgrowth polymers with phosphorus containing compounds: Effects on flame retardance—A review, Polym. Adv. Technol., 2011, vol. 22, pp. 395–406.

    Article  CAS  Google Scholar 

  9. Camino, G., Costa, L., Luda di Cortemiglia, M.P., Overview of fire retardant mechanisms, Polym. Degrad. Stab., 1991, vol. 33, pp. 131–154.

    Article  CAS  Google Scholar 

  10. Focke, W.W., Strydom, C.A., and Bartie, N., Thermal analysis of commercial inorganic flame retardants, S. Afr. J. Chem. Eng., 1997, vol. 9, no. 2, pp. 41–51.

    CAS  Google Scholar 

  11. Skinner, G.A., Flame retardancy: The approaches available, in Plastics Additives: An A–Z Reference, Pritchard, G., Ed., London, UK: Chapman and Hall, 1998, vol. 1, pp. 260–267.

    Google Scholar 

  12. Bourbigot, S. and Le Bras, M., Fundamentals: Flame retardant plastics, in Plastics Flammability Handbook: Principles, Regulation, Testing and Approval, Troitzsch, J., Ed., Munich, Germany: Hanser, 2004, pp. 134–148.

    Google Scholar 

  13. Morgan, A.B. and Wilkie, C.A., Flame Retardant Polymer Nanocomposites, New York, Wiley, 2007, pp. 191–193.

    Book  Google Scholar 

  14. Morgan, A.B. and Gilman, J.W., An overview of flame retardancy of polymeric materials: Application, technology, and future directions, Fire Mater., 2013, vol. 37, pp. 259–279.

    Article  CAS  Google Scholar 

  15. Laoutid, F., Bonnaud, L., Alexandre, M., Lopez-Cuesta, J., and Dubois, P., New prospects in flame retardant polymer materials: From fundamentals to nanocomposites, Mater. Sci. Eng., R, 2009, vol. 63, pp. 100–125.

    Article  Google Scholar 

  16. Mack A. G. Flame retardants, halogenated, in Kirk-Othmer Encyclopedia of Chemical Technology, Seidel, A., Ed., New Jersey: Wiley, 2004, vol. 11, pp. 454–483.

    Google Scholar 

  17. Chanda, M. and Roy, S., Plastics Fundamentals, Properties, and Testing, Boca Raton, Fla.: CRC/Taylor and Francis, 2009.

    Google Scholar 

  18. Hatanaka, L., Ahmed, L., Sachdeva, S., Qingsheng, W., Zhengdong, C., and Mannan, M., Thermal degradation and flammability of nanocomposites composed of silica cross-linked to poly(methyl methacrylate), Plast., Rubber Compos., 2016, vol. 45, pp. 375–381.

    Article  CAS  Google Scholar 

  19. Touval, I., Flame retardants, antimony and other inorganic agents, in in Kirk-Othmer Encyclopedia of Chemical Technology, Seidel, A., Ed., New Jersey: Wiley, 2004, vol. 11, pp. 1–19.

    Google Scholar 

  20. Costa, L. and Giordano, G., Developmental neurotoxicity of polybrominated diphenylether (PBDE) flame retardants, Neurotoxicology, 2007, vol. 28, pp. 1047–1067.

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  21. Reistad, T., Mariussen, E., Ring, A., and Fonnum, F., In vitro toxicity of tetrabromobisphenol A on cerebellar granule cells: Cell death, free radical formation, calcium influx and extracellular glutamate, Toxicol Sci., 2007, vol. 96, pp. 268–278.

    Article  CAS  PubMed  Google Scholar 

  22. Aznar-Alemany, O., Aminot, Y., Vilà-Cano, J., and Köck-Schulmeyer, M., Halogenated and organophosphorus flame retardants in European aquaculture samples, Sci. Total Environ., 2018, vol. 612, pp. 492–500.

    Article  CAS  PubMed  Google Scholar 

  23. Shaw, S., Blum, A., Weber, R., Kannan, K., Rich, D., Lucas, D., et al., Halogenated flame retardants: Do the fire safety benefits justify the risks?, Rev. Environ. Health, 2010, vol. 25, pp. 261–305.

    Article  CAS  PubMed  Google Scholar 

  24. Talsness, C.E., Overview of toxicological aspects of polybrominated diphenyl ethers: a flame-retardant additive in several consumer products, Environ. Res., 2008, vol. 108, pp. 158–167.

    Article  CAS  PubMed  Google Scholar 

  25. Green, J., A review of phosphorus containing flame retardants, J. Fire Sci., 1992, vol. 10, pp. 470–487.

    Article  CAS  Google Scholar 

  26. Morgan, A.B., Flame retarded polymer layered silicate nanocomposites: A review of commercial and open literature systems, Polym. Adv. Technol., 2006, vol. 17, pp. 206–217.

    Article  CAS  Google Scholar 

  27. Green, J., Phosphorous containing flame retardants, in Fire Retardancy of Polymeric Materials, Grand, A.F. and Wilkie, C.A., Eds., New York: Marcel Dekker, 2000, pp. 148–170.

    Google Scholar 

  28. Schmitt, E., Phosphorus-based flame retardants for thermoplastics, Plast. Addit. Compd., 2007, vol. 9, pp. 26–30.

    Article  Google Scholar 

  29. Green, J., Mechanisms for flame retardancy and smoke suppression—A review, J. Fire Sci., 1996, vol. 14, pp. 426–442.

    Article  CAS  Google Scholar 

  30. Babushok, V. and Tsang, W., Inhibitor rankings for alkane combustion, Combust. Flame, 2000, vol. 124, pp. 488–506.

    Article  Google Scholar 

  31. Schartel, B., Phosphorus-based flame retardancy mechanisms—Old hat or a starting point for future development, Materials, 2010, vol. 3, pp. 4710–4745.

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  32. Weil, E.D. and Levchik, S.V., Flame retardants in commercial use or development for polyolefins, J. Fire Sci., 2008, vol. 26, p. 40.

    Google Scholar 

  33. Sundarrajan, S., Cishore, K., and Ganesh, K., A new polymeric flame retardant additive for vinyl polymers, Indian J. Chem., Sect. A: Inorg., Bio-inorg., Phys., Theor. Anal. Chem., 2001, vol. 40, pp. 41–45.

    Google Scholar 

  34. Davis, J., Flame retardants: Halogen-free systems (including phosphorus additives), in Plastics Additives: An A–Z Reference, Pritchard, G., Ed., London, UK: Chapman and Hall, 1998, vol. 1, pp. 277–286.

    Google Scholar 

  35. Levchik, S.V. and Weil, E.D., A review of recent progress in phosphorus-based flame retardants, J. Fire Sci., 2006, vol. 24, pp. 345–364.

    Article  CAS  Google Scholar 

  36. Van der Veen, I. and de Boer, J., Phosphorus flame retardants: Properties, production, environmental occurrence, toxicity and analysis, Chemosphere, 2012, vol. 88, pp. 1119–1153.

    Article  CAS  PubMed  Google Scholar 

  37. Weil, E.D. and Levchik, S.V., Flame retardants in commercial use or development for polyolefins, J. Fire Sci., 2008, vol. 26, p. 40.

    Google Scholar 

  38. Sundarrajan, S., Cishore, K., and Ganesh, K., A new polymeric flame retardant additive for vinyl polymers, Indian J. Chem., Sect. A: Inorg., Bio-inorg., Phys., Theor. Anal. Chem., 2001, vol. 40, pp. 41–45.

    Google Scholar 

  39. Horold, S., Phosphorus flame retardants in thermoset resins, Polym. Degrad. Stab., 1999, vol. 64, pp. 427–431.

    Article  CAS  Google Scholar 

  40. Plotnikova, G.V., Egorov, A.N., Khaliullin, A.K., Malysheva, S.F., and Shaikhudinova, S.I., Study of fire resistance of PVC plastisols with phosphorus-containing additives, Plast. Massy, 2002, no. 11, pp. 25–26.

  41. Lomakin, S.M. and Zaikov, G.E., Ecological Aspects of Polymer Flame Retardancy, Utrecht: The Netherlands: VSP, 1999, pp. 12–20.

    Google Scholar 

  42. Levchik, S.V. and Weil, E.D., New developments in flame retardancy of styrene thermoplastics and foams, Polym. Int., 2008, vol. 57, pp. 431–48.

    Article  CAS  Google Scholar 

  43. Laoutid, F., Bonnaud, L., Alexandre, M., Lopez-Cuesta, J.M., and Dubois, P., New prospects in flame retardant polymer materials: From fundamentals to nanocomposites, Mater. Sci. Eng. R, 2009, vol. 63, pp. 100–125.

    Article  Google Scholar 

  44. Zhang, S. and Horrocks, A.R., A review of flame retardant polypropylene fibres, Prog. Polym. Sci., 2003, vol. 28, pp. 1517–1538.

    Article  CAS  Google Scholar 

  45. Crews, G.M., Ripperger, W., Kersebohm, D., Seeholzer J., Guthne T. Melamine and guanamines, in Ullman’s Encyclopedia of Industrial Chemistry, Gerhartz, W., Ed., Weinheim, Germany: Wiley-VCH, 2002, vol. 22, pp. 1–18.

    Google Scholar 

  46. Levchik, S.V., Balabanovich, A.I., Levchik, G.F., and Costa, L., Effect of melamine and its salts on combustion and thermal decomposition of polyamide 6, Fire Mater., 1997, vol. 21, pp. 75–83.

    Article  CAS  Google Scholar 

  47. Gijsman, P., Steenbakkers, R., Furst, C., and Kersjes, J., Differences in the flame retardant mechanism of melamine cyanurate in polyamide 6 and polyamide 66, Polym. Degrad. Stab., 2001, vol. 78, pp. 219–224.

    Article  Google Scholar 

  48. Weil, E. and Levchik, S., Current practice and recent commercial developments in flame retardancy of polyamides, J. Fire Sci., 2002, vol. 22, pp. 251–264.

    Article  Google Scholar 

  49. Kiliaris, P., Papaspyrides, C.D., and Pfaendner, R., Polyamide 6 filled with melamine cyanurate and layered silicates: Evaluation of flame retardancy and physical properties, Macromol. Mater. Eng, 2008, vol. 293, pp. 740–751.

    Article  CAS  Google Scholar 

  50. Lu, S.Y. and Hamerton, I., Recent developments in the chemistry of halogen-free flame retardant polymers, Prog. Polym. Sci., 2002, vol. 27, pp. 1661–1712.

    Article  CAS  Google Scholar 

  51. Bourbigot, S., Le Bras, M., Duquesne, S., and Rochery, M., Recent advances for intumescent polymers, Macromol. Mater. Eng, 2004, vol. 289, pp. 499–551.

    Article  CAS  Google Scholar 

  52. Morgan, A.B. and Gilman, J.W., An overview of flame retardancy of polymeric materials: Application, technology, and future directions, Fire Mater., 2013, vol. 37, pp. 259–279.

    Article  CAS  Google Scholar 

  53. Duquesne, S., Jimenez, M., and Bourbigot, S., Fire retardancy and fire protection of materials using intumescent coatings—A versatile solution, in Fire Retardancy of Polymers: New Strategies and Mechanisms, Hull, T.R. and Kandola, B.K., Eds., Cambridge, UK: RSC, 2009, Ch. 16, pp. 240–254.

    Google Scholar 

  54. Kiliaris, P., Papaspyrides, C., and Pfaendner, R., Polyamide 6 filled with melamine polyphosphate and layered silicates: evaluation of flame retardancy and physical properties, Macromol. Mater. Eng., 2011, vol. 296, pp. 617–629.

    Article  CAS  Google Scholar 

  55. Bourbigot, S., Le Bras, M., Tremillon, J., Breant, P., and Delobel, R., Zeolites: New synergistic agents for intumescent thermoplastic formulations—Criteria for the choice of the zeolite, Fire Mater., 1996, vol. 20, pp. 145–158.

    Article  CAS  Google Scholar 

  56. Levchik, S., Levchik, G., Camino, G., Costa, L., and Lesnikovich, A., Mechanism of action of phosphorus-based flame retardants in nylon 6, III: Ammonium polyphosphate/manganese dioxide, Fire Mater., 1996, vol. 20, pp. 183–190.

    Article  CAS  Google Scholar 

  57. Anna, P., Marosi, G., and Bourbigot, S., Le Bras, M., and Delobel, R., Intumescent flame retardant systems of modified rheology, Polym. Degrad. Stab., 2002, vol. 77, pp. 243–247.

    Article  CAS  Google Scholar 

  58. Weil, E.D., Fire-protective and flame-retardant coatings—A state-of-the-art review, J. Fire Sci., 2001, vol. 29, pp. 259–296.

    Article  Google Scholar 

  59. Kodolov, V.I., Flame Retardants for Polymeric Materials, Moscow: Khimiya, 1980.

    Google Scholar 

  60. Witkowski, A., Stec, A., and Richard, H., The influence of metal hydroxide fire retardants and nanoclay on the thermal decomposition of EVA, Polym. Degrad. Stab., 2012, vol. 97, pp. 231–240.

    Article  Google Scholar 

  61. Atkinson, P.A., Haines, P.J., and Skinne, G.A., Inorganic tin compounds as flame retardants and smoke suppressants for polyester thermosets, Thermochim. Acta, 2000, vol. 360, pp. 29–40.

    Article  CAS  Google Scholar 

  62. Costa, L., Goberti, P., Paganetto, G., Camino, G., and Sgarzi, P., Thermal behaviour of chlorine-antimony fire-retardant systems, Polym. Degrad. Stab., 1990, vol. 30, pp. 13–28.

    Article  CAS  Google Scholar 

  63. Horn, W.E., Inorganic hydroxides and hydroxycarbonates: Their function and use as flame retardants, in Fire Retardancy of Polymeric Materials, Grand, A.F. and Wilkie, C.A., Eds., New York: Marcel Dekker, 2000, pp. 285–352.

    Google Scholar 

  64. Brown, S.C., Flame retardants: Inorganic oxide and hydroxide systems, in Plastics Additives: An A–Z Reference, Pritchard, G., Ed., London, UK: Chapman and Hall, 1998, pp. 288–296.

    Google Scholar 

  65. Hornsby, P.R., The application of magnesium hydroxide as a fire retardant and smoke-suppressing additive for polymers, Fire Mater., 1994, vol. 18, pp. 269–276.

    Article  CAS  Google Scholar 

  66. Hornsby, P.R., Wang, J., Cosstick, K., Rothon, R.N., Jackson, G., and Wilkinson, G., Mechanism of fire retardancy in polyamides filled with magnesium hydroxide, Prog. Rubber Plast. Technol., 1994, vol. 10, pp. 204–220.

    CAS  Google Scholar 

  67. Hirschler, M.M., Reduction of smoke formation from and flammability of thermoplastic polymers by metal oxides, Polymer, 1984, vol. 25, pp. 405–411.

    Article  CAS  Google Scholar 

  68. Rothon, R.N., Effects of particulate fillers on flame retardant properties of composites, in Particulate Filled Polymer Composites, Rothon, R.N., Ed., Shrewsbury, England: Rapra Technology Ltd., 2003, pp. 263–302.

    Google Scholar 

  69. Papazoglou, E.S., Flame retardants for plastics, in Handbook of Building Materials for Fire Protection, Harper, C.A., Ed., Ohio: McGraw-Hill, 2003, pp. 4.1–4.8.

    Google Scholar 

  70. Hornsby, P.R., Rothon, R.N., Fire retardant fillers for polymers, in Fire Retardancy of Polymers: New Applications of Mineral Fillers, Le Bras, M., Wilkie, C.A., Bourbigot, S., Duquesne, S., and Jama, C., Eds., London, UK: R. Soc. Chem., 2005, pp. 19–41.

    Google Scholar 

  71. Yang, Y., Shi, X., and Zhao, R., Flame retardancy behavior of zinc borate, J. Fire Sci., 1999, vol. 17, pp. 355–361.

    Article  CAS  Google Scholar 

  72. Shen, K., O’Connor, R., and Brown, S., Flame retardants: Borates, in Plastics Additives: An A–Z Reference, Pritchard, G., Ed., London, UK: Chapman and Hall, 1998, pp. 268–276.

    Google Scholar 

  73. Shen, K., Kochesfahani, S., and Jouffret, F., Zinc borates as multifunctional polymer additives, Polym. Adv. Technol., 2008, vol. 19, pp. 469–474.

    Article  CAS  Google Scholar 

  74. Durin-France, A., Ferry, L., Lopez Cuesta, J.-M., and Crespy, A., Magnesium hydroxide/zinc borate/talc compositions as flame retardants in EVA copolymer, Polym. Int., 2000, vol. 49, pp. 1101–1105.

    Article  CAS  Google Scholar 

  75. Samyn, F., Bourbigot, S., Duquesne, S., and Delobel, R., Effect of zinc borate on the thermal degradation of ammonium polyphosphate, Thermochim. Acta, 2007, vol. 456, pp. 134–144.

    Article  CAS  Google Scholar 

  76. Giudice, C.A. and Benlitez, J.C., Zinc borates as flame-retardant pigments in chlorine-containing coatings, Prog. Org. Coat., 2001, vol. 42, pp. 82–88.

    Article  CAS  Google Scholar 

  77. Seydibeyoglu, O. and Guner, F., Polyurethane-zinc borate composites with high oxidative stability and flame retardancy, Polym. Degrad. Stab., 2009, vol. 94, pp. 1072–1075.

    Article  Google Scholar 

  78. Hull, T., Witkowski, A., and Hollingbery, L., Fire retardant action of mineral fillers, Polym. Degrad. Stab., 2011, vol. 96, pp. 1462–1469.

    Article  CAS  Google Scholar 

  79. Yi, D., Yang, R., and Wilkie, C.A., Full scale nanocomposites: clay in fire retardant and polymer, Polym. Degrad. Stab., 2014, vol. 105, pp. 31–41.

    Article  CAS  Google Scholar 

  80. Lv, J., Qie, L., and Qu, B., Controlled synthesis of magnesium hydroxide nanoparticles with different morphological structures and related properties in flame retardant, Nanotechnology, 2004, vol. 15, pp. 1576–1581.

    Article  Google Scholar 

  81. Sertsova, A.A., Marakulin, S.I., and Yurtov, E.V., Metal compound nanoparticles: Flame retardants for polymer composites, Russ. J. Gen. Chem., 2017, vol. 87, pp. 1395–1402.

    Article  CAS  Google Scholar 

  82. Tang Haoa, Zhou Xiao-baib, and Liu Xiao-lua, Effect of magnesium hydroxide on the flame retardant properties of unsaturated polyester resin, Procedia Eng., 2013, vol. 52, pp. 336–341.

    Article  Google Scholar 

  83. Khoang, T.Kh., Sertsova, A.A., Kharkhush, A.A., and Yurtov, E.V., Fire- and heat-resistant composite nanomaterials based on unsaturated polyester resins, Khim. Tekhnol., 2019, vol. 20, no. 3, pp. 121–127.

    Google Scholar 

  84. Yuezhan Feng, Chengen He, Yingfeng Wen, and Xingping Zhou, Multi-functional interface tailoring for enhancing thermal conductivity, flame retardancy and dynamic mechanical property of epoxy/Al2O3 composites, Compos. Sci. Technol., 2018, vol. 160, pp. 42–49.

    Article  CAS  Google Scholar 

  85. Laachachi, A., Leroyb, E., Cocheza, M., Ferriola, M., and Lopez, CuestaJ.M., Use of oxide nanoparticles and organoclays to improve thermal stability and fire retardancy of poly(methyl methacrylate), Polym. Degrad. Stab., 2005, vol. 89, pp. 344–352.

    Article  CAS  Google Scholar 

  86. Guoxin Li, Junfen Yang, Tingshu He, Yonghua Wu, and Guozheng Liang, An investigation of the thermal degradation of the intumescent coating containing MoO3 and Fe2O3, Surf. Coat. Technol., 2008, vol. 202, pp. 3121–3128.

    Article  CAS  Google Scholar 

  87. Sertsova, A.A., Subcheva, E.N., and Yurtov, E.V., Synthesis and study of structure formation of layered double hydroxides based on Mg, Zn, Cu, and Al, Russ. J. Inorg. Chem., 2015, vol. 60, pp. 23–32.

    Article  CAS  Google Scholar 

  88. Yuan Liu, Yanshan Gao, Qiang Wang, and Weiran Lin, Synergistic effect of layered double hydroxides with other flame retardant additives for polymer nanocomposites: A critical review, Dalton Trans., 2018, vol. 47, pp. 14827–14840.

    Article  CAS  PubMed  Google Scholar 

  89. Cui, Y., Liu, X., Tian, Y., Ding, N., and Wang, Z., Controllable synthesis of three kinds of zinc borates and flame retardant properties in polyurethane foam, Colloids Surf.: A, 2012, vol. 414, pp. 274–280.

    Article  CAS  Google Scholar 

  90. Mergen, A., Ipek, Y., Bolek, H., and Oksuz, M., Production of nano zinc borate (4ZnO · B2O3 · H2O) and its effect on PVC, J. Eur. Ceram. Soc., 2012, vol. 32, pp. 2001–2005.

    Article  CAS  Google Scholar 

  91. Baltaci, B., Caka, G., Bayram, G., Eroglu, I., and Ozkar, S., Surfactant modified zinc borate synthesis and its effect on the properties of PET, Powder Technol., 2013, vol. 244, pp. 38–44.

    Article  CAS  Google Scholar 

  92. Gao, P. and Zhang, Y., Synthesis and characterization of zinc borate nanowhiskers and their inflaming retarding effect in polystyrene, J. Nanomater., 2015, pp. 1–6.

  93. Li, S., Long, B., Wang, Z., Tian, Y., Zheng, Y., and Zhang, Q., Synthesis of hydrophobic zinc borate nanoflakes and its effect on flame retardant properties of polyethylene, Solid State Chem., 2010, vol. 183, pp. 957–962.

    Article  CAS  Google Scholar 

  94. Witkowski, A., Stec, A., and Hull, T., The influence of metal hydroxide fire retardants and nanoclay on the thermal decomposition of EVA, Polym. Degrad. Stab., 2012, vol. 97, pp. 2231–2240.

    Article  CAS  Google Scholar 

  95. Jiao, C.M., Wang, Z.Z., Ye, Z., Hu, Y., and Fan, W.C., Flame retardation of ethylene–vinyl acetate copolymer using nano magnesium hydroxide and nano hydrotalcite, J. Fire Sci., 2006, vol. 24, pp. 47–64.

    Article  CAS  Google Scholar 

  96. Fomin, D.L. and Deberdeev, R.Y., The effect of aluminium and magnesium hydroxides on the properties of plasticised polyvinyl chloride, Int. Polym. Sci. Technol., 2018, vol. 41, pp. 47–50.

    Article  Google Scholar 

  97. Sertsova, A.A., Koroleva, M.Y., Yurtov, E.V., Pravednikova, O.B., Dutikova, O.S., and Gal’braikh, L.S., Fire-resistant polymer nanocomposites based on metal oxides and hydroxides, Theor. Found. Chem. Eng., 2010, vol. 44, pp. 772–777.

    Article  CAS  Google Scholar 

  98. Mishra, S., Sonawane, S., Singh, R., Bendale, A., and Patil, K., Effect of nano-Mg(OH)2 on the mechanical and flame-retarding properties of polypropylene composites, Polym. Sci., 2004, vol. 94, pp. 116–122.

    CAS  Google Scholar 

  99. Si, M., Feng, J., Hao, J., Xu, L., and Du, J., Synergistic flame retardant effects and mechanisms of nano-Sb2O3 in combination with aluminum phosphinate in poly(ethylene terephthalate), Polym. Degrad. Stab., 2014, vol. 100, pp. 70–78.

    Article  CAS  Google Scholar 

  100. Gallo, E., Schartel, B., Acierno, D., and Russo, P., Flame retardant biocomposites: Synergism between phosphinate and nanometric metal oxides, Eur. Polym. J., 2011, vol. 47, pp. 1390–1401.

    Article  CAS  Google Scholar 

  101. Trifonov, S.A., Malygin, A.A., D’yakova, A.K., Lopez-Cvesta, J.-M, and Sinozero, N., Thermal stability of polymer compositions with modified alumina, Ross. Khim. Zh., 2008, vol. 52, no. 1, pp. 42–47.

    CAS  Google Scholar 

  102. Lopez-Cuesta, J.-M., Flame-retardant polymer nanocomposites, in Advances in Polymer Nanocomposites: Types and Applications, Gao, F., Ed., Cambridge, UK: Woodhead, 2012, pp. 540–564.

    Google Scholar 

  103. Lubna Ahmed, Bin Zhang, Logan C. Hatanaka, and M. Sam Mannan, Application of polymer nanocomposites in the flame retardancy study, J. Loss Prev. Process Ind., 2018, vol. 55, pp. 381–391.

    Article  CAS  Google Scholar 

  104. Castrovinci, A. and Camino, G., Fire-retardant mechanisms in polymer nano-composite materials, in Multifunctional Barriers for Flexible Structure: Textile, Leather and Paper, Duquesne, S., Magniez, C., and Camino, G., Eds., Berlin: Springer, 2007, vol. 97, pp. 87–108.

    Google Scholar 

  105. Cinausero, N., Azema, N., Lopez-Cuesta, J.-M., Cochez, M., and Ferriol, M., Synergistic effect between hydrophobic oxide nanoparticles and ammonium polyphosphate on fire properties of poly (methyl methacrylate) and polystyrene, Polym. Degrad. Stab., 2011, vol. 96, pp. 1445–1454.

    Article  CAS  Google Scholar 

  106. Nazare, S., Kandola, B.K., and Horrocks, A.R., Flame-retardant unsaturated polyester resin incorporating nanoclays, Polym. Adv. Technol., 2006, vol. 17, pp. 294–303.

    Article  CAS  Google Scholar 

  107. Sertsova, A.A., Marakulin, S.I., and Yurtov, E.V., Nanoparticles of metal compounds—A flame retardant for polymer composite materials, Ross. Khim. Zh., 2015, vol. 59, no. 3, pp. 78–85.

    Google Scholar 

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Harhoosh, A.A., Yurtov, E.V. & Bakhareva, N.I. Flame Retardant Strategies and the Physical Barrier Effect of Nanoparticles to Improve the Thermal Performance of a Polymer. Theor Found Chem Eng 56, 545–553 (2022). https://doi.org/10.1134/S0040579522040133

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