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Simulation and Optimization of Hydrogen Fueled Mobile Power Plant Based on Methylcyclohexane–Toluene–Hydrogen Cycle

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Abstract

Increase in CO2 emissions from fossil fuels has threatened the future security of human race. The addition of a renewable and environment friendly energy source to the present energy mix is essentially required. Hydrogen economy is one of the potential solutions for the clean environment and sustainable energy. However, the economical and safe storage of hydrogen is the biggest hurdle in the success of hydrogen on a commercial scale. Hydrogen storage in the form of an organic hydride such as methylcyclohexane, is not only safe, but well developed technology. In the present study, a 2 megawatt hydrogen based mobile power plant is conceptualized and simulated. The concept of the methylcyclohexane-toluene-hydrogen system is employed where the hydrogen required for the gas turbine is obtained from the dehydrogenation of methylcyclohexane. The heat energy required for the highly endothermic dehydrogenation reaction is provided by the turbine exhaust gases. A base-case flowsheet is visualized and the parametric sensitivity of the mobile power plant is studied. The optimization of the operating variables yields the thermal efficiency of the plant as 35.44% and the required methylcyclohexane flowrate equal to 24.96 kmol/h. The modification of the base-case flowsheet, for the optimized conditions, by the regenerative scheme together with the interstage cooling of the two-stage compressor system increased the thermal efficiency of the mobile power plant to 36.79% and decreased the required amount of fresh methylcyclohexane flowrate to 24.04 kmol/h.

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REFERENCES

  1. BP Statistical Review of World Energy 2018, London: BP, 2018, 67th ed.

  2. The Hydrogen Economy: A Non-Technical Review, Nairobi: United Nations Environment Programme (UNEP), 2006.

  3. Elnashaie, S., Zhongxiang, C., and Prasad, P., Efficient production and economics of clean-fuel hydrogen, Int. J. Green Energy, 2007, vol. 4, p. 249.

    Article  CAS  Google Scholar 

  4. Juste, G.L, and Benavides, E.M., Feasibility analysis of hydrogen as additional fuel in aircraft propulsion, Int. J. Green Energy, 2008, vol. 5, p. 69.

    Article  CAS  Google Scholar 

  5. Scherer, G.W.H. and Newson, E., Analysis of the seasonal energy storage of hydrogen in liquid organic hydrides, Int. J. Hydrogen Energy, 1998, vol. 23, p. 19.

    Article  CAS  Google Scholar 

  6. Juangsa, F.B., Prananto, L.A., Mufrodi, Z., Budiman, A., Oda, T., and Aziz, M., Highly energy-efficient combination of dehydrogenation of methylcyclohexane and hydrogen-based power generation, Chem. Eng. Trans., 2018, vol. 70, p. 2089.

    Google Scholar 

  7. Taube, M., Rippin, D., Knecht, W., Hakimifard, D., Milisavljevic, B., and Gruenenfelder, N., A prototype truck powered by hydrogen from organic liquid hydrides, Int. J. Hydrogen Energy, 1985, vol. 10, p. 595.

    Article  CAS  Google Scholar 

  8. Cresswell, D.L. and Metcalfe, I.S., Energy integration strategies for solid oxide fuel cell systems, Solid State Ionics, 2006, vol. 177, p. 1905. https://doi.org/10.1016/j.ssi.2006.02.028

    Article  CAS  Google Scholar 

  9. Usman, M.R. and Cresswell, D.L., Options for on-board use of hydrogen based on the methylcyclohexane–toluene–hydrogen system, Int. J. Green Energy, 2013, vol. 10, no. 2, p. 177. https://doi.org/10.1080/15435075.2011.647168

    Article  CAS  Google Scholar 

  10. Sultan, O. and Shaw, H., Study of Automotive Storage of Hydrogen Using Recyclable Liquid Chemical Carriers, NASA STI/Recon Technical Report, Washington, DC: National Aeronautics and Space Administration (NASA), 1975.

  11. Taube, M., Rippin, D.W.T., Cresswell, D.L., and Knecht, W., A system of hydrogen-powered vehicles with liquid organic hydrides, Int. J. Hydrogen Energy, 1983, vol. 8, p. 213.

    Article  CAS  Google Scholar 

  12. Manser, S.R.H., Methylcyclohexane dehydrogenation kinetics, reactor design and simulation for a hydrogen powered vehicle, PhD Thesis, Zürich: Swiss Federal Inst. of Technology, 1992.

  13. Newson, E., Haueter, Th., Hottinger, P., Von Roth, F., Scherer, G.W.H., and Schucan, Th.H., Seasonal storage of hydrogen in stationary systems with liquid organic hydrides, Int. J. Hydrogen Energy, 1998, vol. 23, p. 905. https://doi.org/10.1016/S0360-3199(97)00134-1

    Article  CAS  Google Scholar 

  14. Bustamante, G.V.S.C., Swesi, Y., Pitault, I. Meille, V., and Heurtaux, F., A hydrogen storage and transportation mean, Proc. International Hydrogen Energy Congress Exhibition IHEC, Istanbul, 2005.

  15. Tsakiris, D.E., Catalytic production of hydrogen from liquid organic hydride, PhD Thesis, Manchester: Univ. of Manchester, 2007.

  16. Alhumaidan, F.S., Hydrogen storage in liquid organic hydrides: Producing hydrogen catalytically from methylcyclohexane, PhD Thesis, Manchester: Univ. of Manchester, 2008.

  17. Yolcular, S. and Olgun, Ö., Hydrogen storage in the form of methylcyclohexane, Energy Sources, 2008, vol. 30, p. 149.

    Article  CAS  Google Scholar 

  18. Usman, M.R., Kinetics of methylcyclohexane dehydrogenation and reactor simulation for “on-board” hydrogen storage, PhD Thesis, Manchester: Univ. of Manchester, 2010.

  19. Usman, M.R., Catalytic dehydrogenation of methylcyclohexane over monometallic catalysts for on-board hydrogen storage, production, and utilization, Energy Sources, Part A, 2011, vol. 33, p. 2231.

    CAS  Google Scholar 

  20. Campbell, C.R., Hydrogen storage and fuel processing strategies, PhD Thesis, Newcastle: Newcastle Univ., 2014.

  21. Usman, M.R. and Cresswell, D.L., Prototype reactor simulation for on-board use of hydrogen in a hybrid MTH (methylcyclohexane-toluene-hydrogen)-gasoline system and a simplified dynamic modelling for the startup, Chem. Eng. Res. Des., 2015, vol. 104, p. 125.

    Article  CAS  Google Scholar 

  22. Akram, M.S., Kinetic study and reactor simulation of methylcyclohexane dehydrogenation reaction for a mobile power plant, PhD Thesis, Lahore: Univ. of the Punjab, 2018.

  23. Rohrer, J.C. and Sinfelt, J.H., Interaction of hydrocarbons with Pt-Al2O3 in the presence of hydrogen and helium, J. Phys. Chem., 1962, vol. 66, p. 1193.

    Article  CAS  Google Scholar 

  24. Jossens, L.W. and Petersen, E.E., Fouling of a platinum reforming catalyst accompanying the dehydrogenation of methylcyclohexane, J. Catal., 1982, vol. 73, p. 377.

    Article  CAS  Google Scholar 

  25. Usman, M.R., Aslam, R., and Alotaibi, F., Hydrogen storage in a recyclable organic hydride: kinetic modelling of methylcyclohexane dehydrogenation over 1.0wt%Pt/θ-Al2O3, Energy Sources, Part A, 2011, vol. 33, p. 2264.

    CAS  Google Scholar 

  26. Akram, M.S., Munir, D., and Usman, M.R., Associative adsorption kinetics: A novel kinetic model for the dehydrogenation of methylcyclohexane, Prog. React. Kinet. Mech., 2014, vol. 39, no. 4, p. 404. https://doi.org/10.3184/146867814X14120122636502

    Article  CAS  Google Scholar 

  27. El-Sawi, M., Infortuna, F.A., Lignola, P.G., Parmaliana, A., Frusteri, F., and Giordano, N., Parameter estimation in the kinetic model of methylcyclohexane dehydrogenation on a Pt-Al2O3 catalyst by sequential experiment design, Chem. Eng. J., 1989, vol. 42, p. 137.

    Article  CAS  Google Scholar 

  28. Schildhauer, T.H., Newson, E., and Müller, S., The equilibrium constant for methylcyclohexane-toluene system, J. Catal., 2001, vol. 198, p. 355.

    Article  CAS  Google Scholar 

  29. Abdallah, M.M., Mohammad, E.M., Tawfiag, A.J., Ala’aeldin, Abdalrahim, and Hamdnalla, Thermodynamic optimization of GARRI (1) combined cycle power plant by using ASPEN HYSYS simulation, Int. J. Recent Innovation Trends Comput. Commun., 2016, vol. 4, no. 1, p. 69.

    Google Scholar 

  30. Matsuda, H. and Uchida, K., Renewal work of power plant for high efficiency GTCC power plant with 1500°C-class gas turbine, Mitsubishi Heavy Ind. Tech. Rev. (Engl. Ed.), 2010, vol. 47, p. 15.

  31. Horlock, J.H., Advanced Gas Turbine Cycles, Amsterdam: Pergamon, 2003.

    Google Scholar 

  32. Usman, M.R., Cresswell, D.L., and Garforth, A.A., Detailed reaction kinetics for the dehydrogenation of methylcyclohexane over Pt catalyst, Ind. Eng. Chem. Res., 2012, vol. 51, p. 158.

    Article  CAS  Google Scholar 

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ACKNOWLEDGMENTS

Muhammad R. Usman acknowledges Dr. Ashish Gujarathi for having useful discussions.

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Authors and Affiliations

  1. Institute of Energy and Environmental Engineering, University of the Punjab, Lahore, Pakistan

    Muhammad S. Akram

  2. Petroleum and Chemical Engineering Department, Sultan Qaboos University, Muscat, Oman

    Muhammad R. Usman

  3. Engineering Research Centre, University of the Punjab, Lahore, Pakistan

    Muhammad R. Usman

  4. Institute of Chemical Engineering and Technology, University of the Punjab, Lahore, Pakistan

    Muhammad R. Usman

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  1. Muhammad S. Akram
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Correspondence to Muhammad R. Usman.

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Muhammad S. Akram, Muhammad R. Usman Simulation and Optimization of Hydrogen Fueled Mobile Power Plant Based on Methylcyclohexane–Toluene–Hydrogen Cycle. Theor Found Chem Eng 55, 545–561 (2021). https://doi.org/10.1134/S0040579521030015

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