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Heat- and Fire-Resistant Composite Nanomaterials Based on Unsaturated Polyester Resins

  • NANOMATERIALS AND NANOTECHNOLOGIES
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Abstract

Heat- and fire-resistant of the composite nanomaterials based on unsaturated polyester resins are produced. Using ZnO nanoparticles and water as fire retardants are found to reduce the combustion rate and to increase the formation of the carbonized residue of composite nanomaterial based on polyester resin.

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REFERENCES

  1. Pang, K., Kotek, R., and Tonelli, A., Review of conventional and novel polymerization processes for polyesters, Prog. Polym. Sci., 2006, vol. 31, no. 11, pp. 1009–1037. https://doi.org/10.1016/j.progpolymsci.2006.08.008

    Article  CAS  Google Scholar 

  2. Fink, J.K., Unsaturated polyester resins, Reactive Polymers: Fundamentals and Applications: A Concise Guide to Industrial Polymers, Plastics Design Library, Oxford: William Andrew, 2018, 3rd ed., ch. 1, pp. 1–69.

    Google Scholar 

  3. Abu-Jdayil, B., Mourad, A.-H.I., and Hussain, A., Investigation on the mechanical behavior of polyester-scrap tire composites, Constr. Build. Mater., 2016, vol. 127, pp. 896–903. https://doi.org/10.1016/j.conbuildmat.2016.09.138

    Article  CAS  Google Scholar 

  4. Peng, G., Li, Q., Yang, Y., Wang, H., and Li, W., Effects of nano ZnO on strength and stability of unsaturated polyester composites, Polym. Adv. Technol., 2008, vol. 19, no. 11, pp. 1629–1634. https://doi.org/10.1002/pat.1179

    Article  CAS  Google Scholar 

  5. Evans, S.J., Haines, P.J., and Skinner, G.A., The thermal degradation of polyester resins II. The effects of cure and of fillers on degradation, Thermochim. Acta, 1997, vol. 291, nos. 1–2, pp. 43–49. https://doi.org/10.1016/S0040-6031(96)03102-4

    Article  CAS  Google Scholar 

  6. Abu-Jdayil, B., Mourad, A.-H., and Hussain, A., Thermal and physical characteristics of polyester–scrap tire composites, Constr. Build. Mater., 2016, vol. 105, pp. 472–479. https://doi.org/10.1016/j.conbuildmat.2015.12.180

    Article  CAS  Google Scholar 

  7. Terzopoulou, Z., Tsanaktsis, V., Nerantzaki, M., Achilias, D.S., Vaimakis, T., Papageorgiou, G.Z., and Bikiaris, D.N., Thermal degradation of biobased polyesters: Kinetics and decomposition mechanism of polyesters from 2,5-furandicarboxylic acid and long-chain aliphatic diols, J. Anal. Appl. Pyrolysis, 2016, vol. 117, pp. 162–175. https://doi.org/10.1016/j.jaap.2015.11.016

    Article  CAS  Google Scholar 

  8. Tibiletti, L., Longuet, C., Ferry, L., Coutelen, P., Mas, A., Robin, J.J., and Lopez-Cuesta, J.M., Thermal degradation and fire behavior of unsaturated polyesters filled with metallic oxides, Polym. Degrad. Stab., 2011, vol. 96, no. 1, pp. 67–75. https://doi.org/10.1016/j.polymdegradstab.2010.10.015

    Article  CAS  Google Scholar 

  9. Taguet, A., Cassagnau, P., and Lopez-Cuesta, J.-M., Structuration, selective dispersion and compatibilizing effect of (nano)fillers in polymer blends, Prog. Polym. Sci., 2014, vol. 39, no. 8, pp. 1526–1563. https://doi.org/10.1016/j.progpolymsci.2014.04.002

    Article  CAS  Google Scholar 

  10. Pan, L.L., Li, G.Y., Su, Y.C., and Lian, J.S., Fire retardant mechanism analysis between ammonium polyphosphate and triphenyl phosphate in unsaturated polyester resin, Polym. Degrad. Stab., 2012, vol. 97, no. 9, pp. 1801–1806. https://doi.org/10.1016/j.polymdegradstab.2012.06.002

    Article  CAS  Google Scholar 

  11. Mitchell, J.W., The history and future trends of non-halogenated flame retarded polymers, Non-Halogenated Flame Retardant Handbook, Morgan, A.B. and Wilkie, C.A., Eds., Salem, Mass.: Wiley-Scrivener, 2014, ch. 1, pp. 1–16. https://doi.org/10.1002/9781118939239.ch1

  12. Sertsova, A.A., Marakulin, S.I., and Yurtov, E.V., Metal compound nanoparticles: Flame retardants for polymer composites, Russ. J. Gen. Chem., 2017, vol. 87, no. 6, pp. 1395–1402. https://doi.org/10.1134/S1070363217060421

    Article  CAS  Google Scholar 

  13. Sousa, S.P.B., Ribeiro, M.C.S., Nóvoa, P.R.O., Pereira, C.M., and Ferreira, A.J.M., Mechanical behaviour assessment of unsaturated polyester polymer mortars filled with nano-sized Al2O3 and ZrO2 particles, Cienc. Tecnol. Mater., 2017, vol. 29, no. 1, pp. e167–e171. https://doi.org/10.1016/j.ctmat.2016.08.002

    Article  Google Scholar 

  14. Marakulin, S.I., Sertsova, A.A., and Yurtov, E.V., Effect of zinc oxide nanoparticles on the mechanism of thermal destruction of composite materials based on polymethyl methacrylate, Usp. Khim. Khim. Tekhnol., 2016, vol. 30, no. 12 (181), pp. 6–8.

  15. Duke, J.R., Jr., Hoisington, M.A., Langlois, D.A., and Benicewicz, B.C., High temperature properties of poly(styreneco-alkylmaleimide) foams prepared by high internal phase emulsion polymerization, Polymer, 1998, vol. 39, no. 18, pp. 4369–4378. https://doi.org/10.1016/S0032-3861(98)00115-3

    Article  CAS  Google Scholar 

  16. Cameron, N.R., High internal phase emulsion templating as a route to well-defined porous polymers, Polymer, 2005, vol. 46, no. 5, pp. 1439–1449. https://doi.org/10.1016/j.polymer.2004.11.097

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Mendeleev University of Chemical Technology of Russia, 125047, Moscow, Russia

    Hoang Thanh Hai, A. A. Sertsova, A. A. Harhoosh & E. V. Yurtov

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  1. Hoang Thanh Hai
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  2. A. A. Sertsova
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  3. A. A. Harhoosh
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  4. E. V. Yurtov
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Correspondence to E. V. Yurtov.

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Translated by V. Glyanchenko

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Hoang Thanh Hai, Sertsova, A.A., Harhoosh, A.A. et al. Heat- and Fire-Resistant Composite Nanomaterials Based on Unsaturated Polyester Resins. Theor Found Chem Eng 54, 719–725 (2020). https://doi.org/10.1134/S0040579520040090

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