Abstract—
The results of experiments on preparing pure (marketable) salt from crude salt of ammonium perrhenate are presented; the pure salt is rigidly standardized in elements–impurities and rhenium by recrystallization, sorption, and membrane electrodialysis. AP-0 salt is obtained from solutions purified from elements–impurities by recrystallization, AP-00 salt is obtained by sorption, and the salt purer than AP-00 is obtained by electrodialysis. The advantages and disadvantages of each of the methods are specified.
Similar content being viewed by others
REFERENCES
Goncharov, G.V., A brief analysis of the world markets of rhenium and molybdenum, Renii, vol’fram, molibden – 2016. Nauchnye issledovaniya, tekhnologicheskie razrabotki, promyshlennoe primenenie. Sbornik materialov Mezhdunarodnoi nauchno-prakticheskoi konferentsii (Proc. International Research and Practice Conference “Rhenium, Tungsten, and Molybdenum – 2016: Scientific Research, Technological Developments, and Industrial Applications”) (Moscow, 2016), Moscow: GINTSVETMET (Scientific Research Institute of Nonferrous Metals), 2016, pp. 12–27.
Palant, A.A., Troshkina, I.D., and Chekmarev, A.M., Metallurgiya reniya (The Metallurgy of Rhenium), Moscow: Nauka, 2007.
TU 48-7-1-90. Ammonii renievokislyi. Tekhnicheskie usloviya (TU 48-7-1-90: Ammonium Perrhenate. Technical Specifications), Moscow: Minist. Metall. SSSR, 1990.
GOST (State Standard) 31411–2009: Ammonium Perrhenate. Technical Specifications, 2010.
Zagorodnyaya, A.N., Abisheva, Z.S., Sharipova, A.S., and Sadykanova, S.E., Production of ammonium perrhenate from acidic wastewater from the washing of metallurgical gases of copper charge processing, Kompleksn. Ispol’z. Miner. Syr’ya, 2014, no. 2, pp. 57–63.
Korovin, S.S., Bukin, V.I., Fedorov, P.I., and Reznik, A.M., Redkie i rasseyannye elementy. Khimiya i tekhnologiya (Rare and Trace Elements: Chemistry and Technology), Moscow: Nats. Issled. Tekhnol. Univ. MISIS, 2003, part 3.
Agapova, L.Ya., Zagorodnyaya, A.N., Abisheva, Z.S., Kilibaeva, S.K., and Altenova, A.N., The application of electrodialysis for the production of pure ammonium perrhenate from industrial salt, Kompleksn. Ispol’z. Miner. Syr’ya, 2014, no. 3, pp. 71–77.
Olbrikh, A., Yan, M., Meeze-Marktsheffel’, Y., and Tsertani, R., RF Patent 2514941, Izobret., Polezn. Modeli, 2014, no. 13.
Lyapin, S.B., Shtyrlov, P.Yu., Khaitmitov, A.A., Guro, V.P., and Atakuziev, A.A., An ion-exchange method for purifying ammonium perrhenate from potassium impurity, Gorn. Vestn. Uzb., 2004, no. 2 (17), pp. 59–60.
Pirmatov, E.A., Chamantaev, K.K., Pirmatov, A.E., and Dulenin, A.P., On the possibility of purifying ammonium perrhenate from impurities by ion exchange, Trudy Respublikanskoi nauchno-prakticheskoi konferentsii “Problemy i perspektivy razvitiya Pribalkhash’ya” (Proc. Republican Research and Practice Conference “Problems and Prospects of the Development of the Balkhash Region”) (Balkhash, 2007), Balkhash: Balkhash. Gumanitarno-Tekh. Univ., 2007, pp. 95–98.
Leszczyńska-Sejda, K., Benke, G., Chmielarz, A., Krompiec, S., Michalik, S., and Krompiec, M., Synthesis of perrhenic acid using ion exchange method, Hydrometallurgy, 2007, vol. 89, nos. 3–4, pp. 289–296. https://doi.org/10.1016/j.hydromet.2007.09.002
Leszczyńska-Sejda, K., Majewski, T., Benke, G., Piętaszewski, J., Anyszkiewicz, K., Michałowski, J., and Chmielarz, A., Production of high-purity ammonium perrhenate for W–Re–Ni–Fe heavy alloys, J. Alloys Compd., 2012, vol. 513, pp. 347–352. https://doi.org/10.1016/j.jallcom.2011.10.047
Temerov, S.A. and Novozhilova, V.I., RF Patent 2355640, Izobret., Polezn. Modeli, 2009, no. 14.
Temerov, S.A., Varfolomeev, N.V., Novozhilova, V.I., and Loseva, M.P., RF Patent 2485053, Izobret., Polezn. Modeli, 2013, no. 17.
Zagorodnyaya, A.N., Linnik, K.A., Sharipova, A.S., and Abisheva, Z.S., Effect of a supersaturation coefficient on the behavior of impurity elements in the recrystallization of technical grade ammonium perrhenate, Kompleksn. Ispol’z. Miner. Syr’ya, 2016, no. 3, pp. 22–29.
Zagorodnyaya, A.N., Linnik, K.A., Sharipova, A.S., Abisheva, Z.S., and Zhumabekov, Zh.Zh., Purification of technical grade ammonium perrhenate solutions from impurity elements by sorption, Kompleksn. Ispol’z. Miner. Syr’ya, 2015, no. 3, pp. 17–26.
International Centre for Diffraction Data (ICDD), Powder diffraction file-2, release 2009. http://www.icdd.com. Accessed February 19, 2018.
GOST (State Standard) 10896-78: Ion Exchangers. Preparations for Tests, 1999.
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated by S. Lebedev
Rights and permissions
About this article
Cite this article
Zagorodnyaya, A.N., Abisheva, Z.S., Agapova, L.Y. et al. Purification of Crude Ammonium Perrhenate from Potassium by Recrystallization, Sorption, and Membrane Electrodialysis. Theor Found Chem Eng 53, 841–847 (2019). https://doi.org/10.1134/S0040579519050233
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0040579519050233