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Application of Layered Double Magnesium–Aluminum Oxides for the Purification of Aqueous Solutions from Dyes

  • TECHNOLOGY OF INORGANIC COMPOUNDS AND MATERIALS
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Abstract

The possibility of purifying aqueous solutions from dyes with the use of layered double magnesium–aluminum oxides is studied. Using stamp ink as an example, it has been demonstrated that the complete recovery of dye from the solution is attained at the time of contact between the liquid (L) and solid (S) phases of 120 min and S : L = 1 : 25. The same complete recovery of dye from the aqueous solution is attained upon repeated contact between the stamp-ink solution and the solid phase of the sorbent containing stamp ink. No desorption of dye from the sorbent into the aqueous solution is observed after 120 min of contact.

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REFERENCES

  1. Shea, K.E. and Dionysiou, D.D., Advanced oxidation processes for water treatment, J. Phys. Chem. Lett., 2012, vol. 3, no. 15, pp. 2112–2113.

    Article  Google Scholar 

  2. Ahmed, M.B., Zhou, J.L., Ngo, H.H., Guo, W., Thomaidis, N.S., and Xu, J., Progress in the biological and chemical treatment technologies for emerging contaminant removal from wastewater: A critical review, J. Hazard. Mater., 2017, vol. 323, pp. 274–298. https://doi.org/10.1016/j.jhazmat.2016.04.045

    Article  CAS  PubMed  Google Scholar 

  3. Teh CY, Budiman, P.M., Shak, K.P.Y., and Wu, T.Y., Recent advancement of coagulation–flocculation and its application in wastewater treatment, Ind. Eng. Chem. Res., 2016, vol. 55, no. 16, pp. 4363–4389. https://doi.org/10.1021/acs.iecr.5b04703

    Article  CAS  Google Scholar 

  4. Miller, D.J., Dreyer, D.R., Bielawski, Ch.W., Paul, D.R., and Freeman, B.D., Surface modification of water purification membranes, Angew. Chem., Int. Ed., 2017, vol. 56, no. 17, pp. 4662–4711.

    Article  CAS  Google Scholar 

  5. Perlov, A.G., Tekhnologiya ochistki prirodnykh vod (Natural Water Purification Technology), Moscow: ASV, 2016.

  6. Ali, I., New generation adsorbents for water treatment, Chem. Rev., 2012, vol. 112, no. 10, pp. 5073–5091. https://doi.org/10.1021/cr300133d

    Article  CAS  PubMed  Google Scholar 

  7. Dremicheva, E.S. and Laptedul’che, N.K., Peat as a sorbent for the purification of industrial wastewater, Voda: Khim. Ekol., 2015, no. 8, pp. 63–68.

  8. Khajeh, M., Laurent, S., and Dastafkan, K., Nanoadsorbents: Classification, preparation, and applications (with emphasis on aqueous media), Chem. Rev., 2013, vol. 113, no. 10, pp. 7728–7768. https://doi.org/10.1021/cr400086v

    Article  CAS  PubMed  Google Scholar 

  9. Bo, A., Sarina, S., Liu, H., Zheng, Z., Xiao, Q., Gu, Y., Ayoko, G.A., and Zhu, H., Efficient removal of cationic and anionic radioactive pollutants from water using hydrotalcite-based getters, ACS Appl. Mater. Interfaces, 2016, vol. 8, no. 25, pp. 16503–16510. https://doi.org/10.1021/acsami.6b04632

    Article  CAS  PubMed  Google Scholar 

  10. Zhou, J.Z., Wu, Y.Y., Liu, C., Orpe, A., Liu, Q., Xu, Z.P., Qian, G.R., and Qiao, S.Z., Effective self-purification of polynary metal electroplating wastewaters through formation of layered double hydroxides, Environ. Sci. Technol., 2010, vol. 44, no. 23, pp. 8884–8890. https://doi.org/10.1021/es102884v

    Article  CAS  PubMed  Google Scholar 

  11. Palmer, S.J. and Frost, R.L., Use of hydrotalcites for the removal of toxic anions from aqueous solutions, Ind. Eng. Chem. Res., 2010, vol. 49, no. 19, pp. 8969–8976.

    Article  CAS  Google Scholar 

  12. Yu, S., Wang, X., Chen, Z., Wang, J., Wang, S., Hayat, T., and Wang, X., Layered double hydroxide intercalated with aromatic acid anions for the efficient capture of aniline from aqueous solution, J. Hazard. Mater., 2017, vol. 321, pp. 111–120. https://doi.org/10.1016/j.jhazmat.2016.09.009

    Article  CAS  PubMed  Google Scholar 

  13. Klimovich, I.V., Synthetic analogs of hydrotalcite in processes for the removal of radioactive elements from solutions, Cand. Sci. (Chem.) Dissertation, Moscow, 2013.

  14. Majoni, S. and Hossenlopp, J.M., Anion exchange kinetics of nanodimensional layered metal hydroxides: Use of isoconversional analysis, J. Phys. Chem. A, 2010, vol. 114, no. 49, pp. 12858–12869.

    Article  CAS  Google Scholar 

  15. Radha, A.V., Vishnu Kamath, P., and Shivakumara, C., Conservation of order, disorder, and “crystallinity” during anion-exchange reactions among layered double hydroxides (LDHs) of Zn with Al, J. Phys. Chem. B, 2007, vol. 111, no. 13, pp. 3411–3418.

    Article  CAS  Google Scholar 

  16. Prasanna, S.V. and Vishnu Kamath, P., Anion-exchange reactions of layered double hydroxides: Interplay between Coulombic and H-bonding interactions, Ind. Eng. Chem. Res., 2009, vol. 48, no. 13, pp. 6315–6320. https://doi.org/10.1021/ie9004332

    Article  CAS  Google Scholar 

  17. Shan, R.R., Yan, L.G., Yang, Y.M., Yang, K., Yu, S.J., Yu, H.Q., Zhu, B.C., and Du, B., Highly efficient removal of three red dyes by adsorption onto Mg–Al-layered double hydroxide, Ind. Eng. Chem. Res., 2015, vol. 21, pp. 561–568. https://doi.org/10.1016/j.jiec.2014.03.019

    Article  CAS  Google Scholar 

  18. Ahmed, I.M. and Gasser, M.S., Adsorption study of anionic reactive dye from aqueous solution to Mg–Fe–CO3 layered double hydroxide, Appl. Surf. Sci., 2012, vol. 259, pp. 650–656.

    Article  CAS  Google Scholar 

  19. Lei, C., Zhu, X., Zhu, B., Jiang, C., Le, Y., and Yu, J., Superb adsorption capacity of hierarchical calcined Ni/Mg/Al layered double hydroxides for Congo red and Cr(VI) ions, J. Hazard. Mater., 2017, vol. 321, pp. 801–811. https://doi.org/10.1016/j.jhazmat.2016.09.070

    Article  CAS  PubMed  Google Scholar 

  20. Abdelkader, N.B.H., Bentouami, A., Derriche, Z., Bettahar, N., and de Ménorval, L.-C., Synthesis and characterization of Mg–Fe layer double hydroxides and its application on adsorption of Orange G from aqueous solution, Chem. Eng. J., 2011, vol. 169, nos. 1–3, pp. 231–238. https://doi.org/10.1016/j.cej.2011.03.019

    Article  CAS  Google Scholar 

  21. Koilraj, P. and Srinivasan, K., High sorptive removal of borate from aqueous solution using calcined ZnAl layered double hydroxides, Ind. Eng. Chem. Res., 2011, vol. 50, no. 11, pp. 6943–6951. https://doi.org/10.1021/ie102395m

    Article  CAS  Google Scholar 

  22. Chitrakar, R., Sonoda, A., Makita, Y., and Hirotsu, T., Calcined Mg–Al layered double hydroxides for uptake of trace levels of bromate from aqueous solution, Ind. Eng. Chem. Res., 2011, vol. 50, no. 15, pp. 9280–9285. https://doi.org/10.1021/ie1023468

    Article  CAS  Google Scholar 

  23. Xue, X., Gu, Q., Pan, G., Liang, J., Huang, G., Sun, G., Ma, S., and Yang, X., Nanocage structure derived from sulfonated β-cyclodextrin intercalated layered double hydroxides and selective adsorption for phenol compounds, Inorg. Chem., 2014, vol. 53, no. 3, pp. 1521–1529. https://doi.org/10.1021/ic402494m

    Article  CAS  PubMed  Google Scholar 

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Authors and Affiliations

  1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 119071 , Moscow, Russia

    E. P. Krasavina & S. A. Kulyukhin

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  1. E. P. Krasavina
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  2. S. A. Kulyukhin
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Correspondence to E. P. Krasavina.

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Translated by E. Glushachenkova

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Krasavina, E.P., Kulyukhin, S.A. Application of Layered Double Magnesium–Aluminum Oxides for the Purification of Aqueous Solutions from Dyes. Theor Found Chem Eng 53, 827–831 (2019). https://doi.org/10.1134/S0040579519050117

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