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Simulation and optimization of the deprotiation cascade of a heavy-water moderator

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Abstract

A simulation procedure and results of simulation are reported for the operation of a cascade of packed distillation columns for heavy water deprotiation. The mathematical model is based on the results of laboratory-scale tests of a rolled ribbon–screw structured packing developed at the Mendeleev University of Chemical Technology of Russia an a random spiral prismatic packing made from stainless steel. Use of the rolled ribbon–screw packing in the columns provides means to diminish the volume of the separation equipment without changing the cascade throughput capacity and separation factor.

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References

  1. Andreev, B.M., Magomedbekov, E.P., Raitman, A.A., Rozenkevich, M.B., Sakharovsky, Yu.A., and Khoroshilov, A.V., Separation of Isotopes of Biogenic Elements in Two-Phase Systems, Amsterdam: Elsevier, 2007.

    Google Scholar 

  2. Kinoshita, M., Computer-aided simulation procedure for water distillation columns, J. Nucl. Sci. Technol., 1984, vol. 21, no. 4, p. 299.

    Article  CAS  Google Scholar 

  3. Busigin, A. and Sood, S.K., FLOSHEET—a computer program for simulating hydrogen isotope separation systems, Fusion Technol., 1988, vol. 14, p. 529.

    CAS  Google Scholar 

  4. Ahn, D.H., Kim, K.R., Chung, H.S., Kim, Y.E., Jeong, I.J., Hong, S.Y., and Ko, J.W., Computer program development for D2O upgrader performance management, J. Korean Nucl. Soc., 1990, vol. 22, no. 1, p. 1.

    Google Scholar 

  5. Kalyanam, K.M., Sood, S.K., Fusca, F., and Busigin, A., Heavy water upgrader dynamic simulation, in Proc. Annu. Conf. Canadian Nuclear Society/Canadian Nuclear Association, 1997, vol. 18, no. 2, p. 15.

    Google Scholar 

  6. Chan, T.C. and van Hook, W.A., Vapor pressure isotope effects in aqueous systems. VIII, J. Solution Chem., 1976, vol. 5, p. 107.

    Article  CAS  Google Scholar 

  7. van Hook, W.A., Vapor pressures of the isotopic waters and ices, J. Phys. Chem., 1968, vol. 72, no. 2, p. 1234.

    Article  Google Scholar 

  8. Vertuzaev, E.D., Calculation of the scaling factor for industrial packed distillation and absorption columns, Khim. Prom–st., 1982, no. 8, p. 458.

    Google Scholar 

  9. Selivanenko, I.L. and Suvorkin, K.D., RF Patent 139117, 2012.

    Google Scholar 

  10. Magomedbekov, E.P., Belkin, D.Yu., Selivanenko, I.L., and Rastunova, I.L., Characteristics of the mass transfer of structured rolled ribbon-screw packings in isotope exchange columns during vacuum water distillation, Theor. Found. Chem. Eng., 2016, vol. 50, no. 4, p. 398.

    Article  CAS  Google Scholar 

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Correspondence to E. P. Magomedbekov.

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Original Russian Text © E.P. Magomedbekov, D.Yu. Belkin, I.L. Rastunova, A.B. Sazonov, I.L. Selivanenko, N.N. Kulov, 2017, published in Teoreticheskie Osnovy Khimicheskoi Tekhnologii, 2017, Vol. 51, No. 2, pp. 131–139.

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Magomedbekov, E.P., Belkin, D.Y., Rastunova, I.L. et al. Simulation and optimization of the deprotiation cascade of a heavy-water moderator. Theor Found Chem Eng 51, 133–141 (2017). https://doi.org/10.1134/S004057951702004X

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  • DOI: https://doi.org/10.1134/S004057951702004X

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