Abstract
The results of studies of the hydrodifluoride leaching of the perovskite concentrate have been presented. It has been shown that processing the perovskite concentrate using fluoride technology enables one to transform niobium and tantalum into a solution, along with fluoroammonium salts of titanium, iron, and silicon, and to isolate rare-earth elements in the form of complex fluoroammonium salts mixed with CaF2 within a few stages.
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References
Redkie i rasseyannye elementy: Khimiya i tekhnologiya (Rare and Scattered Elements: Chemistry and Technology), Korovin, S.S., Ed., Moscow: Mosk. Inst. Stali i Splavov, 1996, vol. 2.
Andreev, A.A., Fluoride technology of the production of titanium dioxide pigment, Vseross. nauchno-prakt. konf. po ftoridnym tekhnologiyam (Proc. All-Russ. Conf. on Fluoride Tecnnologies, Tomsk, 2009, p. 27.
Krysenko, G.F., Epov, D.G., Yudakov, A.A., Medkov, M.A., and Ivannikov, S.I., Processing of gold-containing technogenic waste using ammonium hydrofluoride, Khim. Tekhnol., 2011, vol. 12, no. 3, pp. 168–171.
Rakov, E.G., Ammonium fluorides, Itogi Nauki Tekh., Ser.: Neorg. Khim., 1988, vol. 15.
Boldyrev, V.V., Metody izucheniya kinetiki termicheskogo razlozheniya tverdykh veshchestv (Methods of Investigation of the Kinetics of Thermal Decomposition of Solids), Tomsk: Tomsk. Gos. Univ., 1958.
Mel'nichenko, E.I., Ftoridnaya pererabotka redkometall’nykh rud Dal’nego Vostoka (Fluoride-Based Processing of Rare Metal Ores of Far East), Vladivostok: Dal’nauka, 2002.
Redkie i rasseyannye elementy: Khimiya i tekhnologiya (Rare and Scattered Elements: Chemistry and Technology), Korovin, S.S., Ed., Moscow: Mosk. Inst. Stali i Splavov, 1996, vol. 1.
Gerasimova, L.G., Kalinnikov, V.T., Maiorov, V.G., Nikolaev, A.I., and Sklokin, L.I., RF Patent 2182887, 2002.
Medkov, M.A., Krysenko, G.F., Epov, D.G., and Mel’nichenko, E.I., Ammonium hydrofluoride as a promising reagent for complex processing of mineral raw materials, Problemy kompleksnogo osvoeniya georesursov: Mater. IV Vseross. nauchnoi konf. s uchastiem inostrannykh uchenykh (“Problems of Georesources Complex Development,” Proc. 4th All-Russ. Conf. with Foreing Researchers Participation), Khabarovsk: Inst. Gornogo Dela, 2011, vol. 1, pp. 376–383.
Mel’nichenko, E.I., Maslennikova, I.G., Epov, D.G., and Krysenko, G.F., Pyrohydrolys of an iron-and fluorine-containing by-product of ilmenite processing, Khim. Tekhnol., 2002, vol. 3, no. 7, pp. 20–23.
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Original Russian Text © G.F. Krysenko, D.G. Epov, M.A. Medkov, P.V. Sitnik, A.I. Nikolaev, 2015, published in Khimicheskaya Tekhnologiya, 2015, Vol. 16, No. 4, pp. 219–223.
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Krysenko, G.F., Epov, D.G., Medkov, M.A. et al. Processing of perovskite concentrate by ammonium hydrodifluoride. Theor Found Chem Eng 50, 588–592 (2016). https://doi.org/10.1134/S0040579516040163
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DOI: https://doi.org/10.1134/S0040579516040163