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Patterns of phenol oxidation process with an aqueous solution of hydrogen peroxide

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Abstract

This paper presents experimental data on the study of catalytic systems based on titanium silicalite (TS-1) for liquid-phase oxidation of phenol. The influence of the main parameters of the process of liquid phase oxidation of phenol with aqueous solution of hydrogen peroxide on the catalyst; the formed titanium silicalite (initial molar ratio of phenol/hydrogen peroxide, temperature) has been studied based on the basic parameters of the process, including the degree of conversion of hydrogen peroxide, the degree of conversion of phenol, the selectivity of the formation of catechol, hydroquinone and 1,4-benzoquinone, and the ratio of products in the reaction mass.

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References

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Authors and Affiliations

  1. Alekseev Nizhny Novgorod State Technical University, Nizhny Novgorod, Russia

    S. M. Danov, S. V. Orekhov, A. E. Fedosov, M. E. Fedosova & A. I. Shishkin

Authors
  1. S. M. Danov
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  2. S. V. Orekhov
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  3. A. E. Fedosov
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  4. M. E. Fedosova
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  5. A. I. Shishkin
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Corresponding author

Correspondence to S. V. Orekhov.

Additional information

Original Russian Text © S.M. Danov, S.V. Orekhov, A.E. Fedosov, M.E. Fedosova, A.I. Shishkin, 2015, published in Khimicheskaya Tekhnologiya, 2015, Vol. 16, No. 3, pp. 157–162.

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Danov, S.M., Orekhov, S.V., Fedosov, A.E. et al. Patterns of phenol oxidation process with an aqueous solution of hydrogen peroxide. Theor Found Chem Eng 50, 525–529 (2016). https://doi.org/10.1134/S0040579516040096

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  • DOI: https://doi.org/10.1134/S0040579516040096

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