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Exergetic analysis of reactions with participation of solid phases

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Abstract

The chemical and thermal components of exergy of solid-phase reaction systems have been analyzed. Chemical exergy is the measure of energy maintenance of chemical reaction; therefore, chemical exergy is intrinsic, not for a particular substance, but rather for a reaction mixture with a particular composition. The temperature dependence of the chemical exergy of the exothermic reaction mixture has a maximum and the temperature dependence of the chemical exergy of endothermic reaction mixture has a minimum. Equations for calculating the exergy components have been suggested, which assume the possibility of the presence of structural polymorphism for the crystal components of reaction mixture.

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Authors and Affiliations

  1. Sukhoi Gomel’ State Technical University, Gomel’, Belarus

    Ya. O. Shablovskii

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  1. Ya. O. Shablovskii
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Correspondence to Ya. O. Shablovskii.

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Original Russian Text © Ya.O. Shablovskii, 2013, published in Teoreticheskie Osnovy Khimicheskoi Tekhnologii, 2013, Vol. 47, No. 5, pp. 558–565.

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Shablovskii, Y.O. Exergetic analysis of reactions with participation of solid phases. Theor Found Chem Eng 47, 577–584 (2013). https://doi.org/10.1134/S0040579513040301

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