Skip to main content
Log in

Synthesis of nanosized powders and coatings of calcium phosphates

  • Nanotechnologies and Nanomaterials
  • Published:
Theoretical Foundations of Chemical Engineering Aims and scope Submit manuscript

Abstract

Hydroxyapatite powders with a particle size of nearly 100 nm, i.e., rather close to bone crystals shaped as 60 × 20 × 5-nm flattened prisms, were synthesized by the pyrolysis of a solution of calcium oleate in tributylphosphate. The possibility of synthesizing hydroxyapatite coatings on different ceramic materials was demonstrated. The pyrolysis of a solution of strontium oleate in tributylphosphate was established to produce the Sr10(PO4)6(OH)2 compound isotypical to hydroxyapatite, which in turn creates prospects for synthesizing materials based on hydroxyapatite with some calcium atoms substituted by strontium.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Veresov, A.G., Putlyaev, V.I., and Tret’yakov, Yu.D., Chemistry of Inorganic Biomaterials Based on Calcium Phosphate, Ross. Khim. Zh., 2004, vol. 48, no. 4, p. 52.

    CAS  Google Scholar 

  2. Tkalcec, E., Sauer, M., Nonninger, R., and Schmidt, H., Sol-Gel-Derived Hydroxyapatite Powders and Coatings, J. Mater. Sci., 2001, vol. 36, no. 21, p. 5253.

    Article  CAS  Google Scholar 

  3. Liu, Dean-Mo., Troczynski, T., and Tseng, W.J., Water-Based Sol-Gel Synthesis of Hydroxyapatite: Process Development, Biomaterials, 2001, vol. 22, no. 13, p. 1721.

    Article  CAS  Google Scholar 

  4. Masuda, Y., Matubara, K., and Sakka, S., Synthesis of Hydroxyapatite from Metal Alkoxides through Sol-Gel Technique, J. Ceram. Soc. Jpn., 1990, vol. 98, no. 10, p. 1266.

    Google Scholar 

  5. Bigi, A., Cojazzi, G., Panzavolta, S., et al., Chemical and Structural Characterization of the Mineral Phase from Cortical and Trabecular Bone, J. Inorg. Biochem., 1997, vol. 68, no. 1, p. 45.

    Article  CAS  Google Scholar 

  6. Becker, R.O., Spadaro, J.A., and Berg, E.W., The Trace Elements of Human Bone, J. Bone Joint Surg. Am., 1968, vol. 50, no. 2, p. 326.

    CAS  Google Scholar 

  7. Canalis, E., Giustina, A., and Bilezikian, J.P., Mechanisms of Anabolic Therapies for Osteoporosis, N. Engl. J. Med., 2007, vol. 357, no. 9, p. 905.

    Article  CAS  Google Scholar 

  8. Steblevskaya, N.I., Medkov, M.A., Batyrbaeva, N.V., and Kurilenko, L.N., Extraction of Europium from Nitrate Solutions in the Presence of Polyfunctional Organic Compounds, Russ. J. Inorg. Chem., 2007, vol. 52, no. 4, p. 635.

    Article  Google Scholar 

  9. Khol’kin, A.I. and Patrusheva, T.N., Ekstraktsionnopiroliticheskii metod: Poluchenie funktsional’nykh oksidnykh materialov (Extraction-Pyrolytic Method: Production of Functional Oxide Materials), Moscow: KomKniga, 2006.

    Google Scholar 

  10. Gorbenko, F.P., Kuchkina, E.D., and Olevinskii, M.I., Extraction of Rhodanide Complexes of Alkaline-Earth Elements, Zh. Anal. Khim., 1968, vol. 23, no. 9, p. 1301.

    CAS  Google Scholar 

  11. Rudnev, V.S., Multiphase Anode Layers and Prospects of Their Application, Prot. Met., 2008, vol. 44, no. 3, p. 263.

    Article  CAS  Google Scholar 

  12. Rudnev, V.S., Kilin, K.N., Malyshev, I.V., et al., Plasma-Electrolytic Oxidation of Titanium in Zr(SO4)2-Containing Bath, Prot. Met. Phys. Chem. Surf., 2010, vol. 46, no. 6, p. 704.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to M. A. Medkov.

Additional information

Original Russian Text © M.A. Medkov, D.N. Grishchenko, N.I. Steblevskaya, I.V. Malyshev, V.S. Rudnev, V.G. Kudryavyi, 2011, published in Khimicheskaya Tekhnologiya, 2011, Vol. 12, No. 6, pp. 343–347.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Medkov, M.A., Grishchenko, D.N., Steblevskaya, N.I. et al. Synthesis of nanosized powders and coatings of calcium phosphates. Theor Found Chem Eng 46, 541–545 (2012). https://doi.org/10.1134/S0040579512050053

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0040579512050053

Keywords

Navigation