Abstract
The decomposition of TMC with hydrochloric acid solutions (15–25% HCl) at the boiling point of the reaction mixture and atmospheric pressure has been investigated. The processing conditions have been determined for efficient recovery of titanium (up to 99.3%) as photocatalytically active anatase and for extracting Fe (up to 99.6%) and V (98.8%) into the leaching solution. Subsequent treatment of the leach liquor with aqueous ammonia affords 99.3 wt % Fe2O3 and an iron-vanadium product containing 3.2 wt % V2O5.
Similar content being viewed by others
References
Reznichenko, V.A. and Sadykhov, G.B., Vanadium: Resources, Production, Consumption, and Recovery, Khim. Tekhnol., 2000, no. 3, p. 25.
Fedorov, S.G., Nikolaev, A.I., Brylyakov, Yu.E., Gerasimova, L.G., and Vasil’eva, N.Ya., Khimi-cheskaya pererabotka mineral’nykh kontsentratov Kol’skogo poluostrova (Chemical Processing of Mineral Concentrates from the Kola Peninsula), Apatity, Murmansk oblast: Kol’sk. Nauchn. Tsentr Ross. Akad. Nauk, 2003.
Leont’ev, L.I., Vatolin, N.A., Shavrin, S.V., and Shumakov, N.S., Pirometallurgicheskaya pererabotka kompleksnykh rud (Pyrometallurgical Processing of Complex Ores), Moscow: Metallurgiya, 1997.
Skiba, G.S., Korovin, V.N., Voskoboinikov, N.B., Kalinnikov, V.T., Zakharov, V.I., Nosova, L.A., Savel’ev, Yu.A., and Kozin, N.I., RF Patent 2149908 Byull. Izobret. 2000, no. 15.
Sole, Ê.Ñ Recovery of Titanium from the Leach Liquors of Titaniferous Magnetites by Solvent Extraction. Part II. Laboratory-Scale Studies, Hydrometallurgy, 1999, vol. 51, no. 3,. p. 263.
Motov, D.L., Fiziko-khimiya i sul’fatnaya tekhnologiya titano-redkometal’nogo syr’ya (Titanium-Rare Earth Raw Materials: Physical Chemistry and Sulfate Technology), Apatity, Murmansk oblast: Kolsk. Nauchn. Tsentr Ross. Akad. Nauk, 2002, vol. 1.
Haibei, W., Kaiki, J.S., Youbu, S., New Technology for Production of Synthetic Rutile by Pressure Leaching and Preparation of Sponge Titanium by Molten Salt Electrolysis, Xiyou Jinshu Cailiao Yu Gongcheng/Rare Metal Mater. Eng., 2006, vol. 35,suppl. 1, p. 78.
Parfenov, O.G. and Pashkov, G.L., Problemy sovremennoi metallurgii titana (Problems of Present-Day Titanium Metallurgy), Novosibirsk: Sib. Otd. Ross. Akad. Nauk, 2008.
Lokshin, E.P., Sedneva, T.A., and Kalinnikov, V.T., On the Processing of Sphene Concentrate, Khim. Tekhnol., 2008, no. 1, p. 3036.
Mahmoud, M.N.N., Afifi, A.A.I., and Ibrahim, I.A., Reductive Leaching of Ilmenite Ore in Hydrochloric Acid for Preparation of Synthetic Rutile, Hydrometallurgy, 2004, vol. 73, no. 1–2, p. 99.
Bol’shakov, K.A., Khimiya i tekhnologiya redkikh i rasseyannykh elementov (Rare and Trace Elements: Chemistry and Technology), Moscow: Vysshaya Shkola, 1969, vol. 2, p. 393.
Korovin, S.S., Drobot, D.V., and Fedorov, P.I., Redkie i rasseyannye elementy. Khimiya i tekhnologiya (Rare and Trace Elements. Chemistry and Technology), Moscow: Mosk. Inst. Stali i Splavov, 1999.
De-Rong, F., Jun-qing, Z., Yu-sheng, L., and Xiang, J., Preparation of an Iron-Doped TiO2 Nanoparticles by Microemulsion Method and Characterization, Zhongguo fenti jishu/China Powder Sci. Technol., 2005, vol. 11, no. 4, p. 17.
Sedneva, T.A., Lokshin, E.P., Belyaevskii, A.T., and Kalinnikov, V.T., Fluoride Ion Doping Effect on the Phase Transition and Photocatalytic Activity of Nanosized Titanium Dioxide, Perspekt. Mater., 2007, no. 6, p. 49.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © T.A. Sedneva, E.P. Lokshin, P.B. Gromov, E.K. Kopkova, E.A. Shchelokova, 2010, published in Khimicheskaya Tekhnologiya, 2010, Vol. 11, No. 6, pp. 349–359.
Rights and permissions
About this article
Cite this article
Sedneva, T.A., Lokshin, E.P., Gromov, P.B. et al. Decomposing the Titaniferous Magnetite Concentrate with Hydrochloric Acid. Theor Found Chem Eng 45, 753–763 (2011). https://doi.org/10.1134/S0040579511050125
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0040579511050125