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Dissolution of ulexite in ammonium carbonate solutions

Abstract

The dissolution of ulexite in ammonium carbonate solutions is investigated. The effect of concentration, particle size, stirring speed, and reaction temperature is examined. It is found that the dissolution rate increases with increasing concentration and reaction temperature, and with decreasing particle size. No effect of stirring speed was observed on the conversion. It is determined that the dissolution rate fits to the first order pseudo-homogeneous reaction model.

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References

  1. Çetin, E., Eroğlu İ and Özkar, S., Kinetics of Gypsum Formation and Growth during the Dissolution of Colemanite in Sulfuric Acid, j. cryst. growth, 2001, vol. 231, p. 559

    Article  Google Scholar 

  2. Alkan, M. and Doğan, M., Dissolution Kinetics of Colemanite in Oxalic Acid Solutions, Chem. Eng. Process., 2004, vol. 43, p. 867.

    Article  CAS  Google Scholar 

  3. Yesilyurt, M., Determination of the Optimum Conditions for the Boric Acid Extraction from Colemanite Ore in HNO3 Solutions, Chem. Eng. Process., 2004, vol. 43, p. 1189.

    Article  CAS  Google Scholar 

  4. Küçük, Ö. and Kocakerim, M.M., Optimization of Dissolution of Ulexite in Water Saturated with Sulphur Dioxide, Chem. Eng. Process., 2005, vol. 44, p. 1005

    Article  Google Scholar 

  5. May, F.H. and Levasheff, V.V., US Patent 3?018 163, 1962.

  6. Alkan, M., Kocakerim, M.M., and Çolak, S., Dissolution Kinetics of Colemanite in Water Saturated CO2, J. Chem. Technol. Biotechnol., 1985, vol. 35A, p. 382.

    CAS  Google Scholar 

  7. Alkan, M., Oktay, M., Kocakerim, M.M., and Karagölge, Z., Dissolution Kinetics of Some Borate Minerals in CO2-Saturated Water, Hydrometallurgy, 1991, vol. 26, p. 255.

    Article  CAS  Google Scholar 

  8. Kocakerim, M.M., Çolak, S., Davies, T., and Alkan, M., Dissolution Kinetics of Ulexite in CO2 Saturated Water, Can. Metall. Q., 1993, vol. 32, p. 393.

    CAS  Google Scholar 

  9. Künkül, A., Yapici, S., Kocakerim, M.M., and Copur, M., Dissolution Kinetics of Ulexite in Ammonium Solutions Saturated with CO2, Hydrometallurgy, 1997, vol. 44, p. 135.

    Article  Google Scholar 

  10. Erdoğan, Y., Aksu, M., Demirbaş, A., and Abali, Y., Analyses of Boronic Ores and Sludges and Solubilities of Boron Minerals in CO2-Saturated Water, Resour. Conservat. Recycl., 1998, vol. 24, p. 275.

    Article  Google Scholar 

  11. Künkül, A., Demirkiran, N and Baysar, A., Dissolution Kinetics of Ulexite in Ammonium Sulfate Solutions, Ind. Eng. Chem. Res., 2003, vol. 42, p. 982.

    Article  Google Scholar 

  12. Tunç, M., Kocakerim, M.M., Küçük, Ö., and Aluz, M., Dissolution of Colemanite in (NH4)2SO4 Solutions, Korean J. Chem. Eng., 2007, vol. 24, p. 55

    Article  Google Scholar 

  13. Künkül, A. and Demirkiran, N., Dissolution Kinetics of Calcined Ulexite in Ammonium Carbonate Solutions, Korean J. Chem. Eng., 2007, vol. 26, p. 947.

    Article  Google Scholar 

  14. Demirkiran, N., Leaching Kinetics of Calcined Ulexite in Ammonium Nitrate Solutions, J. Chem. Eng. Jpn., 2007, vol. 40, p. 755.

    Article  CAS  Google Scholar 

  15. Demirkiran, N. and Künkül, A., Dissolution Kinetics of Ulexite Prepared under Different Calcination Temperatures, Braz. J. Chem. Eng., 2008, vol. 25, p. 751.

    CAS  Google Scholar 

  16. Demirkiran, N., A Study on Dissolution of Ulexite in Ammonium Acetate Solutions, Chem. Eng. J., 2008, vol. 141, p. 180.

    Article  CAS  Google Scholar 

  17. Demirkiran, N., Dissolution Kinetics of Ulexite in Ammonium Nitrate Solutions, Hydrometallurgy, 2009, vol. 95, p. 198.

    Article  CAS  Google Scholar 

  18. Demirkiran, N. and Künkül, A., Dissolution Kinetics of Ulexite in Perchloric Acid Solutions, Int. J. Miner. Process., 2007, vol. 83, p. 76.

    Article  CAS  Google Scholar 

  19. Ekmekyapar, A., Demirkiran, N., and Künkül, A., Dissoltion Kinetics of Ulexite in Acetic Acid Solutions, Chem. Eng. Res. Des., 2008, vol. 86, p. 1011.

    Article  CAS  Google Scholar 

  20. Teir, S., Eloneva, S., and Zevenhoven, R., Production of Precipitated Calcium Carbonate from Calcium Silicates and Carbon Dioxide, Energ. Convers. Manage., 2005, vol. 46, p. 2954.

    Article  CAS  Google Scholar 

  21. Xiang, L., Wen, Y., Wang, Q., and Jin, Y., Synthesis of Dispersive CaCO3 in the Presence of MgCl2, Mater. Chem. Phys., 2006, vol. 98, p. 236.

    Article  CAS  Google Scholar 

  22. Levenspiel, O., Chemical Reaction Engineering, New York: Wiley, 1972.

    Google Scholar 

  23. Arzutu M.E., Kocakerim, M.M., and Çopur, M., Leaching of Malachite Ore in NH3-Saturated Water, Ind. Eng. Chem. Res., 2004, vol. 43, p. 4118.

    Article  Google Scholar 

  24. Küçük, Ö. and Kocakerim, M.M., Dissolution of Ulexite-Containing Clay Minerals in Sulfur Dioxide-Saturated Water, Ind. Eng. Chem. Res., 2005, vol. 44, p. 1728

    Article  Google Scholar 

  25. Kurtbaş, A., Kocakerim, M. M., Küçük, Ö. and Yartşı, A., Dissolution of Colemanite in Aqueous Solutions Saturated with Both Sulfur Dioxide (SO2) Gas and Boric Acid, Ind. Eng. Chem. Res., 2006, vol. 45, p. 1857

    Article  Google Scholar 

  26. Şengul H., Ozer, A.K., and Gulaboglu, M.S., Benefication of Mardin-Mazdaği (Turkey) Calcareous Phosphate Rock using Dilute Acetic Acid Solutions, Chem. Eng. J., 2006, vol. 122, p. 135.

    Article  Google Scholar 

  27. Zhu, Z., Zhang, H., Lü, Z., and Chen, D., Oxidative Dissolution of Cobalt Oxalate and Manganese Oxalate in Acetic Acid Solutions, Chem. Eng. Process., 2007, vol. 46, p. 159.

    Article  CAS  Google Scholar 

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Correspondence to N. Demirkiran.

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Demirkiran, N., Künkül, A. Dissolution of ulexite in ammonium carbonate solutions. Theor Found Chem Eng 45, 114–119 (2011). https://doi.org/10.1134/S0040579511010039

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  • DOI: https://doi.org/10.1134/S0040579511010039

Keywords

  • Boric Acid
  • Dissolution Kinetic
  • Precipitate Calcium Carbonate
  • Colemanite
  • Shrink Core Model