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Statistical analysis of the kinds of vapor-liquid equilibrium diagrams of three-component systems with binary and ternary azeotropes

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Abstract

The kinds of K-ordered region diagrams have been established for 3962 three-component systems containing only binary azeotropes and for 402 three-component systems containing ternary azeotropes. The number of diagrams of each kind and the number of kinds having common features have been determined. The diagrams have been analyzed statistically in terms of their types, the number and kinds of azeotropes, and types of singular points.

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References

  1. Zharov, V.T. and Serafimov, L.A., Fiziko-khimicheskie osnovy distillyatsii i rektifikatsii (Physical and Chemical Foundations of Simple and Fractional Distillation), Leningrad: Khimiya, 1975.

    Google Scholar 

  2. Zhvanetskii, I.B., Reshetov, S.A., and Sluchenkov, V.Yu., Classification of K-Ordered Regions in the Distillation Line Diagram of a Ternary Zeotropic System, Zh. Fiz. Khim., 1988, vol. 62, no. 7, p. 1944.

    CAS  Google Scholar 

  3. Petlyuk, F.B. and Serafimov, L.A., Mnogokomponentnaya rektifikatsiya. Teoriya i raschet (Multicomponent Distillation: Theory and Design), Moscow: Khimiya, 1983.

    Google Scholar 

  4. Petlyuk, F.B., Tsaranova, D.A., Isaev, B.A., and Serafimov, L.A., Presynthesis and Evaluation of Possible Separation Flowsheets for Zeotropic Systems, Teor. Osn. Khim. Tekhnol., 1985, vol. 19, no. 4, p. 514.

    CAS  Google Scholar 

  5. Kiva, V.N., Kreinina, L.A., and Timofeev, V.S., Sistemy s odnim azeotropom i simmetrichnoi oblast’yu distillyatsii (Systems with One Azeotrope and a Symmetric Distillation Region), Available from ONIITEKhim, 1984, Cherkassy, no. 688khp-D84.

  6. Kiva, V.N., Kreinina, L.A., and Timofeev, V.S., Sistemy s odnim azeotropom i asimmetrichnoi oblast’yu distillyatsii (Systems with One Azeotrope and an Asymmetric Distillation Region), Available from ONIITEKhim, 1984, Cherkassy, no. 689khp-D84.

  7. Serafimov, L.A., Gol’berg, Yu.E., Kiva, V.N., and Vitman, T.A., Properties of 6h = 1 Manifolds and Their Arrangement in Concentration Spaces, Sbornik trudov Ivanovskogo energeticheskogo institute (Transactions of Ivanovo Power Engineering Institute), Ivanovo:, 1972, issue 14, p. 166.

    Google Scholar 

  8. Reshetov, S.A., Sluchenkov, V.Yu., and Zhvanetskii, I.B., Classification of K-Ordered Region Diagrams for Ternary Systems with One Binary Azeotrope, Zh. Fiz. Khim., 1989, vol. 63, no. 1, p. 250.

    CAS  Google Scholar 

  9. Zhvanetskii, I.B., Reshetov, S.A., and Sluchenkov, V.Yu., Classification of K-Ordered Region Diagrams for Ternary Systems with Two or Three Binary Azeotropes, Zh. Fiz. Khim., 1989, vol. 63, no. 6, p. 1653.

    CAS  Google Scholar 

  10. Reshetov, S.A., Zhvanetskii, I.B., Sluchenkov, V.Yu., and Orlova, E.V., Classification of K-Ordered Region Diagrams for Three-component Systems with a Ternary Azeotrope, Zh. Fiz. Khim., 1990, vol. 64, no. 5, p. 1384.

    CAS  Google Scholar 

  11. Reshetov, S.A., Sluchenkov, VYu., Ryzhova, VS., and Zhvanetskii, I.B., K-Ordered Region Diagrams with an Arbitrary Number of 6h = 1 lines, Zh. Fiz. Khim., 1990, vol. 64, no. 9, p. 2498.

    CAS  Google Scholar 

  12. Reshetov, S.A., Statistical Analysis of Data for Three-Component Vapor-Liquid Equilibrium Diagrams of Various Topological Types, Teor. Osn. Khim. Tekhnol., 2009, vol. 43, no. 3, p. 295.

    Google Scholar 

  13. Reshetov, S.A. and Kravchenko, S.V., Statistics of Liquid-Vapor Phase Equilibrium Diagrams for Various Ternary Zeotropic Mixtures, Teor. Osn. Khim. Tekhnol., 2007, vol. 41, no. 4, p. 439 [Theor. Found. Chem. Eng. (Engl. Transl.), vol. 41, no. 4, p. 451].

    Google Scholar 

  14. Wilson, G.M., Vapor-Liquid Equilibrium. XI. A New Expression for the Excess Free Energy of Mixing, J. Am. Chem. Soc., 1964, vol. 86, no. 2, p. 127.

    Article  CAS  Google Scholar 

  15. Renon, H.M. and Prausnitz, J.M., Local Composition in Thermodynamic Excess Functions for Liquid Mixtures, AIChEJ., 1968, vol. 14, no. 1,p. 135.

    Article  CAS  Google Scholar 

  16. Abrams, D.S. and Prausnitz, J.M., Statistical Thermodynamics of Liquid Mixtures: A New Expression for the Excess Gibbs Energy of Partly or Completely Miscible Systems, AIChEJ., 1975, vol. 21, no. 1, p. 116.

    Article  CAS  Google Scholar 

  17. Reshetov, S.A., Data Bank on the Physicochemical Properties of Components and Their Mixtures: RSA DB, Sbornik trudov XVI Mezhd. nauchnoi konf. “Matematicheskie metody v tekhnike i tekhnologiyakh” (Proc. XVI Int. Conf. on Mathematical Methods in Engineering and Technology), St. Petersburg, 2003, vol. 3, p. 66.

    Google Scholar 

  18. Reshetov, S.A., Bank dannykh po fiziko-khimicheskim svoistvam komponentov i ikh smesei RSA DB (Data Bank on the Physicochemical Properties of Components and Their Mixtures: RSA DB), Moscow: MITKhT, 2007.

    Google Scholar 

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Authors and Affiliations

  1. Moscow State Academy of Fine Chemical Technology, pr. Vernadskogo 86, Moscow, 119571, Russia

    S. A. Reshetov & S. V. Kravchenko

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  1. S. A. Reshetov
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  2. S. V. Kravchenko
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Correspondence to S. A. Reshetov.

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Original Russian Text © S.A. Reshetov, S. V. Kravchenko, 2010, published in Teoreticheskie Osnovy Khimicheskoi Tekhnologii, 2010, Vol. 44, No. 3, pp. 294–307.

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Reshetov, S.A., Kravchenko, S.V. Statistical analysis of the kinds of vapor-liquid equilibrium diagrams of three-component systems with binary and ternary azeotropes. Theor Found Chem Eng 44, 279–292 (2010). https://doi.org/10.1134/S0040579510030073

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