Abstract
A Pt-Re catalyst-based rhenium and platinum recovery solvolyticometallurgical technique has been developed by chlorinating with chlorine gas mixed with dimethylformamide and hydrochloric acid. The two-stage process conducted with burning residue after the first phase chlorination results in additional platinum transfer into the solution and makes it possible to obtain 70–94% platinum recovery and 91–96% percent rhenium recovery
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Krein, O.E., Otkhody rasseyannykh redkikh metallov (Scattered Rare Metals Wastes), Moscow: Metallurgiya, 1985.
Kadeeva, N.L., Kashcheev, A.N., Shragina, G.M., et al. RF Patent no. 2175266, 2001.
Shoji, Torn, Nakanisti, Chihiro, Japanese. Patent no. 62 256 929 JP, 1987.
Nifontova, G.A., Study of Copper, Gold and Palladium Oxidization in Nitrogen, Sulfur and Halogen Bearing Donor-Acceptor Systems, Cand. Sci. (Chem.) Dissertation, Chernogolovka, 1988.
Chekmarev, A.M., Sol’vometallurgiya — perspektivnoe napravlenie metallurgii redkikh i tsvetnykh metallov (Solvolytic Metallurgy as Prospective Trend in Rare and Non-Ferrous Metals Metallurgy), Moscow: Atomenergoizdat, 2004.
Vradford, S.W. and Valdwin, S.G., US Patent no. 3985854, 1976.
Shipachev, V.A. and Gorneva, G.A., RF Patent no. 2204619, 2003.
Ter-Oganesyants, A.K., Anisimova, N.N., Kotukhova, G.P., and Glazkov, V.B., RF Patent no. 2261284, 2005.
Khan, A.S., Draenkov, N.A., Tatarintsev, A.N., et al., RF Patent no. 2003103936, 2004.
Borbat, V.F., Adeeva, L.N., Korneeva, I.N., RF Patent no. 2167213, 2001.
Trifonova, E.N., Drobot, N.F., Krenev, V.A., and Ermakov, V.A., RF Patent no. 2281340, 2006.
Drobot, N.F., Trifonova, E.N., Krenev, V.A., et al., Refractory Metals Oxidative Dissolution by Chlorinating in Aqueous Organic Environment, Koord. Khim., 2005, vol. 31, no. 4, p. 262.
Makitova, D.D., Krasochka, O.N., Atovmyan, L.O., et al., Composition and Structure of Crystal-Form Products of Metallic Palladium, Rhodium and Platinum Oxidation in Systems Acetonitril-Hydrochloric Acid and Dimetilformanid-Hydrochloric Acid, Koord. Khim., 1987, vol. 13, no. 3, p. 383.
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Original Russian Text © N.F. Drobot, T.A. Kupriyanova, V.A. Krenev, M.N. Filippov, 2008, published in Khimicheskaya Tekhnologiya, 2008, Vol. 9, No. 6, pp. 271–275.
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Drobot, N.F., Kupriyanova, T.A., Krenev, V.A. et al. Rhenium and platinum recovery from platinum and rhenium catalysts used. Theor Found Chem Eng 43, 539–543 (2009). https://doi.org/10.1134/S0040579509040319
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DOI: https://doi.org/10.1134/S0040579509040319