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Adequacy of a stochastic model for choosing ligands for alloy electrodeposition from solutions of mixed-ligand and multivalent ion complexes

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Abstract

The adequacy of a stochastic model for choosing ligands which makes it possible to determine the regions of allowable values of the stability constants of complexes, the reduction of which occurs with the formation of an alloy, and choose ligands on the basis of these data is verified. Experimental data for alloy electrodeposition from solutions with complexes of different ligands and complexes of multivalent ions that are in published data show a good agreement with predictions by this model, which made it possible to formulate an important-for-practice condition of choosing ligands for joint reduction of complexes and the formation of an alloy.

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Authors and Affiliations

  1. Mendeleev University of Chemical Technology, Miusskaya pl. 9, Moscow, 125047, Russia

    E. G. Vinokurov

  2. All-Russian Institute of Scientific and Technical Information, Russian Academy of Sciences, ul. Baltiiskaya 14, Moscow, Russia

    V. V. Bondar’

Authors
  1. E. G. Vinokurov
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  2. V. V. Bondar’
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Correspondence to E. G. Vinokurov.

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Original Russian Text © E. G. Vinokurova and V. V. Bondar’, 2009, published in Teoreticheskie Osnovy Khimicheskoi Tekhnologii, 2009, Vol. 43, No. 3, pp. 308–312.

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Vinokurov, E.G., Bondar’, V.V. Adequacy of a stochastic model for choosing ligands for alloy electrodeposition from solutions of mixed-ligand and multivalent ion complexes. Theor Found Chem Eng 43, 293–297 (2009). https://doi.org/10.1134/S0040579509030087

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  • DOI: https://doi.org/10.1134/S0040579509030087

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