Skip to main content
Log in

Konovalov’s first law validity for nonideal multicomponent zeotropic mixtures

  • Published:
Theoretical Foundations of Chemical Engineering Aims and scope Submit manuscript

Abstract

Complete conditions for the validity of Konovalov’s first law in nonideal multicomponent zeotropic systems are found.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Serafimov, L.A., Frolkov, A.V., and Chelyuskina, T.V., Konovalov’s First Law Validity for Multicomponent Ideal Mixtures, Teor. Osn. Khim. Tekhnol., 2007, vol. 4, no. 4, p. 467 [Theor. Found. Chem. Eng. (Engl. Transl.), vol. 4, no. 4, p. 442].

    Google Scholar 

  2. Serafimov, L.A., Thermodynamic and Topological Analysis and Problems of Separation of Multicomponent Polyazeotropic Mixtures, Teor. Osn. Khim. Tekhnol., 1987, vol. 21,no. 1, p. 74.

    CAS  Google Scholar 

  3. Serafimov, L.A. and Frolkova, A.K., Investigation of the Modified Form of the Van der Waals-Storonkin Equation, Teor. Osn. Khim. Tekhnol., 1999, vol. 33,No. 4, pp. 305–312 [Theor. Found. Chem. Eng. (Engl. Transl.), vol. 33, No. 4, pp. 341–349].

    CAS  Google Scholar 

  4. Storonkin, A.V., Thermodynamically Possible Shapes of Isotherm-Isobars for Ternary Systems, Zh. Fiz. Khim., 1954, vol. 28,no. 11, p. 2021.

    CAS  Google Scholar 

  5. Storonkin, A.V., Termodinamika geterogennykh sistem (Thermodynamics of Heterogeneous Systems), Leningrad: Leningr. Gos. Univ., 1967.

    Google Scholar 

  6. Il’in, V.A. and Poznyak, E.G., Lineinaya algebra (Linear Algebra), Moscow: Nauka, 1978.

    Google Scholar 

  7. Myunster, A.V., Khimicheskaya termodinamika (Chemical Thermodynamics), Moscow: URSS, 2002.

    Google Scholar 

  8. Serafimov, L.A., Gol’berg, Yu.E., Kiva, V.N., and Vitman, T.A., Main Properties of Unit Manifolds and Their Location in Concentration Spaces, in Sbornik nauchnykh trudov Ivanovskogo energeticheskogo in-ta (Research Papers of Ivanovo Power Engineering Institute), Ivanovo, 1972.

  9. Reshetov, S.A., Flowsheet Presynthesis Elements for the Separation of Multicomponent Polyazeotropic Mixtures, Extended Abstract of Doctoral (Eng.) Dissertation, Moscow: Karpov Inst. Chem. Phys, 2003.

    Google Scholar 

  10. Serafimov, L.A., Chelyuskina, T.V., and Bushina, D.I., Specific Features of Temperature Scalar Field and Tie-Line Vector Field Diagrams for Three-Component Two-Phase Systems, Teor. Osn. Khim. Tekhnol., 2006, vol. 40,no. 6, p. 645 [Theor. Found. Chem. Eng. (Engl. Transl.), vol. 40, no. 6, p. 604].

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to L. A. Serafimov.

Additional information

Original Russian Text © L.A. Serafimov, A.K. Frolkova, T.V. Chelyuskina, 2008, published in Teoreticheskie Osnovy Khimicheskoi Tekhnologii, 2008, Vol. 42, No. 1, pp. 40–47.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Serafimov, L.A., Frolkova, A.K. & Chelyuskina, T.V. Konovalov’s first law validity for nonideal multicomponent zeotropic mixtures. Theor Found Chem Eng 42, 37–44 (2008). https://doi.org/10.1134/S0040579508010053

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0040579508010053

Keywords

Navigation