Skip to main content
Log in

Partial oxidation of methane in a multistage-compression chemical reactor

  • Published:
Theoretical Foundations of Chemical Engineering Aims and scope Submit manuscript

Abstract

A theory of noncatalytic partial oxidation of methane in a superadiabatic cyclic compression chemical reactor using the operating principle of internal combustion engine is developed. It is shown that in a two-stroke reactor the conversion of methane to syngas with a H2/CO ratio equal to 2 reaches 0.95 to 0.99 at low mixture compression ratios of 10 to 15. The energy efficiency (product-yield-to-power ratio) reaches 3 m3 of syngas per 1 kWh of power consumed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Arutyunov, V.S. and Krylov, O.V., Okislitel’noe prevrashchenie metana (Conversion of Methane by Oxidation), Moscow: Nauka, 1998.

    Google Scholar 

  2. Karim, G.A., Production of Synthesis Gas and Power in Reciprocating Internal Combustion Engines, British Chemical Engineering, 1963, vol. 8, no. 6, p. 392.

    CAS  Google Scholar 

  3. Kolbanovskii, Yu.A., Shchipachev, V.S., Chernyak, N.Ya., et al., Impul’snoe Szhatie Gazov v Khimii i Tekhnologii (Pulsed Gas Compression in Chemical Engineering), Kolbanovskii, Yu.A., Ed., Moscow: Nauka, 1982.

    Google Scholar 

  4. Plate, N.A., Kolbanovskii, Yu.A., and Ovsyannikov, A.A., Alternative Ways of Destroying Highly Toxic Chemical Substances for the Multiplan Conversion of the Defense Industry, Ross. Khim. Zh., 1994, no. 2, p. 48.

  5. Vasilik, N.Ya., Krupkin, V.G., Margolin, A.D., Pinchuk, V.V., and Shmelev, V.M., Optimization of the Working Processes in a Ballistic Plasma Gun with Multiple-Stage Heating, Teplofiz. Vys. Temp., 1998, vol. 36, no. 3, p. 380 [High Temp. (Engl. Transl.), vol. 36, no. 3, p. 358].

    Google Scholar 

  6. Shmelev, V.M., Non-Isentropic Compression of the Working Mixture in the Piston of an Internal Combustion Engine, Probl. Mashinostr. Avtomatiz., 1999, no. 2, p. 39.

  7. Shmelev, V.M., Non-Isentropic Compression of the Working Mixture in the Piston of a Six-Stroke Internal Combustion Engine, Dvigatelestroenie, 2000, no. 2, p. 9.

  8. Shmelev, V.M. and Nikolaev, V.M., Superadiabatic Compression of the Fuel Mixture in the Piston of an Internal Combustion Engine, Probl. Mashinostr. Avtomatiz., 2002, no. 4, p. 57.

  9. Shmelev, V.M., Nitric Oxide Production in a Multistage-Compression Chemical Reactor, Teor. Osn. Khim. Tekhnol., 2006, vol. 40,no. 5, p. 563 [Theor. Found. Chem. Eng. (Engl. Transl.), vol. 40, no. 5, p. 526].

    Google Scholar 

  10. Basevich, V.Ya., Belyaev, A.A., and Frolov, S.M., Global Kinetic Mechanisms for Calculating Turbulent Reacting Flows, Khim. Fiz., 1998, vol. 17,no. 9, p. 112.

    CAS  Google Scholar 

  11. Petersen, E.L., Davidson, D.F., and Hanson, R.K., Kinetic Modeling of Shock-Induced Ignition in Low-Dilution CH4/O2 Mixtures at High Pressures and Intermediate Temperatures, Combust. Flame, 1999, vol. 117, p. 272.

    Article  CAS  Google Scholar 

  12. Ramos, J.I., Internal Combustion Engine Modeling, New York: HPB, 1989, p. 422.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to V. M. Shmelev.

Additional information

Original Russian Text © V.M. Shmelev, V.M. Nikolaev, 2008, published in Teoreticheskie Osnovy Khimicheskoi Tekhnologii, 2008, Vol. 42, No. 1, pp. 21–28.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Shmelev, V.M., Nikolaev, V.M. Partial oxidation of methane in a multistage-compression chemical reactor. Theor Found Chem Eng 42, 19–25 (2008). https://doi.org/10.1134/S004057950801003X

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S004057950801003X

Keywords

Navigation