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Calculation of the solubilities of gases in paraffin hydrocarbons

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Abstract

A semiempirical equation is proposed to calculate the solubilities of gas systems containing H2, CO, CO2, N2, Ar, CH4, C2H6, and C3H8 in normal paraffin hydrocarbons from C5 to C20 and higher over wide temperature and pressure ranges. The applicability of the equation proposed is evaluated.

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References

  1. Wang, Y.-N., Li, Y.-W., Bai, L., Zhao, Y.-L., and Zhang, B.-J., Correlation for Gas-Liquid Equilibrium Prediction in Fischer-Tropsch Synthesis, Fuel, 1999, vol. 78, no. 8, p. 911.

    Article  CAS  Google Scholar 

  2. Ghosh, A., Chapman, W.G., and French, R.N., Gas Solubility in Hydrocarbons—A SAFT-Based Approach, Fluid Phase Equilib., 2003, vol. 209, no. 2, p. 229.

    Article  CAS  Google Scholar 

  3. Nikol’skii, B.P., Fizicheskaya khimiya (Physical Chemistry), Leningrad: Khimiya, 1987.

    Google Scholar 

  4. Sherwood, T.K., Reid, R.C., and Prausnitz, J.M., The Properties of Gases and Liquids, New York: McGraw-Hill, 1977. Translated under the title Svoistva gazov i zhidkostei. Spravochnoe posobie, Leningrad: Khimiya, 1982.

    Google Scholar 

  5. Ainshtein, V.G., Zakharov, M.K., and Nosov, G.A., Obshchii kurs protsessov i apparatov khimicheskoi tekhnologii (General Course in Unit Operations and Equipment of Chemical Engineering), Moscow: Logos, 2002.

    Google Scholar 

  6. Leites, I.L., Thermodynamic Principles of Efficient Technology of Absorption Gas Treatment, Doctoral (Eng.) Dissertation, Moscow: Res. Des. Inst. Nitrogen Ind. Org. Synth. Prod., 1979.

    Google Scholar 

  7. Leites, I.L. and Sergeeva, L.E., Gas Solubility Calculation, Teor. Osn. Khim. Tekhnol., 1973, vol. 7, no. 5, p. 691.

    CAS  Google Scholar 

  8. Brusilovskii, A.I., Fazovye prevrashcheniya pri razrabotke mestorozhdenii nefti i gaza (Phase Transitions in Oil and Gas Field Exploitation), Moscow: Graal’, 2002.

    Google Scholar 

  9. Smirnova, N.A., Molekulyarnye teorii rastvorov (Molecular Theories of Solutions), Leningrad: Khimiya, 1987.

    Google Scholar 

  10. Shestakov, V.A., An Empirical Equation of State Based on Parameters of the Liquid-Vapor Equilibrium, Zh. Fiz. Khim., 1998, vol. 72, no. 7, p. 1331 [Russ. J. Phys. Chem. (Engl. Transl.), vol. 72, no. 7, p. 1194].

    CAS  Google Scholar 

  11. Spravochnik po rastvorimosti (Handbook of Solubility), Kafarov, V.V., Ed., Moscow: Akad. Nauk SSSR, 1961.

    Google Scholar 

  12. Seidell, A., Solubilities of Organic and Inorganic and Metal Organic Compounds, New York: Van Nostrand, 1958.

    Google Scholar 

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Original Russian Text © V.Kh. Sosna, A.P. Shkurin, 2006, published in Teoreticheskie Osnovy Khimicheskoi Tekhnologii, 2006, Vol. 40, No. 6, pp. 679–682.

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Sosna, V.K., Shkurin, A.P. Calculation of the solubilities of gases in paraffin hydrocarbons. Theor Found Chem Eng 40, 639–643 (2006). https://doi.org/10.1134/S0040579506060133

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  • DOI: https://doi.org/10.1134/S0040579506060133

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