Skip to main content
Log in

Effect of Formic and Acetic Acid Additives on the Photocatalytic Reduction of Water by Cadmium Sulfide Particles

  • PHOTOCHEMISTRY, MAGNETOCHEMISTRY, MECHANOCHEMISTRY
  • Published:
Russian Journal of Physical Chemistry A Aims and scope Submit manuscript

Abstract

Methods of measurement of electromotive forces and gasometry have been used to study the reaction of photochemical reduction of water by suspensions of cadmium sulfide with additions of formic and acetic acids. It has been found that reactions occur on the electrode in suspensions with the release of hydrogen, oxidation of acids and sulfite ions. Hydrogen peroxide has been found in the composition of the products of the photochemical reaction, which interacts with acids and reduces the amount of hydrogen formed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1.
Fig. 2.
Fig. 3.

Similar content being viewed by others

REFERENCES

  1. T. Sakata and T. Kawai, in Energy Resources through Photochemistry and Catalysis, Ed. by M. Grätzel (Elsevier, Amsterdam, 1983), Chap. 10.

    Google Scholar 

  2. N. M. Soboleva, A. A. Nosonovich, and V. V. Goncharuk, J. Water Chem. Technol. 29, 72 (2007).

    Article  Google Scholar 

  3. E. A. Kozlova and V. N. Parmon, Russ. Chem. Rev. 86, 870 (2017).

    Article  CAS  Google Scholar 

  4. E. A. Kozlova and A. V. Vorontsov, Int. J. Hydrogen Energy 35, 7337 (2010).

    Article  CAS  Google Scholar 

  5. S. Protti, A. Albini, and N. Serpone, Phys. Chem. Chem. Phys. 16, 19790 (2014).

    Article  CAS  PubMed  Google Scholar 

  6. D. Jing, L. Guo, L. Zhao, et al., Int. J. Hydrogen Energy 35, 7087 (2010).

    Article  CAS  Google Scholar 

  7. X. H. Hao, L. J. Guo, X. Mao, et al., Int. J. Hydrogen Energy 28, 55 (2003).

    Article  CAS  Google Scholar 

  8. J. Zhu and M. Zach, Curr. Opin. Colloid Interface Sci. 14, 260 (2009).

    Article  CAS  Google Scholar 

  9. B. D. Alexer, P. J. Kulesza, L. Rutkowska, et al., J. Mater. Chem. 18, 2298 (2008).

    Article  Google Scholar 

  10. T. Bak, J. Nowotny, M. Rekas, and C. C. Sorrell, Int. J. Hydrogen Energy 27, 991 (2002).

    Article  CAS  Google Scholar 

  11. W. Choi, Catal. Surv. Asia 10 (1), 16 (2006).

    Article  CAS  Google Scholar 

  12. Y. Zou, C. Guo, X. Cao, et al., J. Environ. Chem. Eng. 9, 106270 (2021).

  13. L. Wei, D. Zeng, Z. Xie, et al., Front. Chem. 15 (April) (2021).

  14. M. Zhang, Y. Chen, J. Chang, et al., J. Am. Chem. Soc. Au. 1, 212 (2021).

    CAS  Google Scholar 

  15. Z. Mamaiyev and N. O. Balayeva, Catalysts 12, 1316 (2022).

    Article  Google Scholar 

  16. V. N. Parmon, Zh. Obshch. Khim. 62, 1703 (1992).

    CAS  Google Scholar 

  17. V. Preethi and S. Kanmani, Mater. Sci. Semicond. Process. 16, 561 (2013).

    Article  CAS  Google Scholar 

  18. N. Buehler, K. Meier, and J. F. Reber, J. Phys. Chem. 88, 3261 (1984).

    Article  CAS  Google Scholar 

  19. G. Zhang, W. Zhang, J. Crittenden, D. Minakata, Y. Chen, and P. Wang, J. Renewable Sustainable Energy 6, 033131 (2014).

  20. H. Yan, J. Yang, G. Ma, et al., J. Catal. 266, 165 (2009).

    Article  CAS  Google Scholar 

  21. M. J. Berr, A. Vaneski, C. Mauser, et al., Small 8, 291 (2012).

    Article  CAS  PubMed  Google Scholar 

  22. J. A. Nasir, Z. Rehman, S. N. A. Shah, et al., J. Mater. Chem. A 8, 20752 (2020).

    Article  CAS  Google Scholar 

  23. Y. X. Li, Y. Z. Me, S. Q. Peng, et al., Chemosphere 63, 1312 (2006).

    Article  CAS  PubMed  Google Scholar 

  24. Y. Li, J. Du, S. Peng, et al., Int. J. Hydrogen Energy 33, 2007 (2008).

    Article  CAS  Google Scholar 

  25. V. Kumaravel, M. D. Imam, A. Badreldin, et al., Catalysts 9, 276 (2019).

    Article  CAS  Google Scholar 

  26. H. Bahruji, M. Bowker, P. R. Davies, et al., J. Photochem. Photobiol., A 216, 115 (2010).

    Article  CAS  Google Scholar 

  27. F. Lv and W. Hung, Cell Rep. Phys. Sci. 2, 100652 (2021).

  28. C. Zhang, S. Chu, B. Liu, et al., Appl. Surf. Sci. 569, 150987 (2021).

  29. Y. Chen, D. Yang, Y. Gao, et al., AAAS Res., 9798564 (2021).

  30. X. Liu, M. Sayed, C. Bie, et al., J. Materiom. 7, 419 (2021).

    Article  CAS  Google Scholar 

  31. S. E. Braslavsky, A. M. Braun, A. E. Cassano, et al., Pure Appl. Chem. 83, 913 (2011).

    Article  Google Scholar 

  32. V. M. Arakelyan, V. M. Arutyunyan, G. E. Shakhnazaryan, G. M. Stepanyan, and A. R. Oganesyan, Al’tern. Energet. Ekol. 43 (11), 78 (2006).

    Google Scholar 

  33. O. A. Fedyaeva and E. G. Poshelyuzhnya, Russ. J. Phys. Chem. A 92, 1636 (2018).

    Article  CAS  Google Scholar 

  34. O. A. Fedyaeva, E. G. Poshelyuzhnya, and M. V. Trenikhin, Russ. J. Phys. Chem. A 92, 1457 (2018).

    Article  CAS  Google Scholar 

  35. Workshop on Physical Chemistry, Ed. by I. V. Kudryashov (Vyssh. Shkola, Moscow, 1986) [in Russian].

    Google Scholar 

  36. G. A. Golikov, Manual of Physical Chemistry (Vyssh. Shkola, Moscow, 1988) [in Russian].

    Google Scholar 

  37. Brief Reference Book of Physical and Chemical Quantities, Ed. by A. A. Ravdel’ and A. M. Ponomareva (Ivan Fedorov, St. Petersburg, 2003) [in Russian].

  38. Unified Methods for Water Analysis, Ed. by Yu. Yu. Lur’e (Vyssh. Shkola, Moscow, 1991) [in Russian].

    Google Scholar 

  39. V. G. Baru and F. F. Vol’kenshtein, Effect of Irradiation on the Surface Properties of Semiconductors (Nauka, Moscow, 1978) [in Russian].

    Google Scholar 

  40. V. S. Vavilov and N. P. Kekelidze, Effect of Radiation on Semiconductors (Nauka, Moscow, 1998) [in Russian].

    Google Scholar 

  41. O. A. Fedyaeva, Vestn. Irkut. Tekh. Univ. 52 (5), 134 (2011).

    Google Scholar 

  42. M. Bideau, B. Claudel, and L. Faure, J. Photochem. 39, 107 (1987).

    Article  CAS  Google Scholar 

  43. H. Harada, T. Sacata, and T. Ueda, J. Am. Chem. Soc. 107, 1773 (1985).

    Article  CAS  Google Scholar 

  44. T. Sacata, T. Kawai, and K. Hashimoto, J. Phys. Chem. 88, 2344 (1984).

    Article  Google Scholar 

  45. M. Bideau, B. Claudel, and M. Otterbein, J. Photochem. 14, 291 (1980).

    Article  CAS  Google Scholar 

  46. E. R. Carraway, A. J. Hoffman, and M. R. Hoffman, Environ. Sci. Technol. 25, 786 (1991).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to O. A. Fedyaeva.

Ethics declarations

The authors declare that they have no conflicts of interest.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Fedyaeva, O.A., Poshelyuzhnaya, E.G. Effect of Formic and Acetic Acid Additives on the Photocatalytic Reduction of Water by Cadmium Sulfide Particles. Russ. J. Phys. Chem. 97, 2331–2337 (2023). https://doi.org/10.1134/S0036024423100114

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036024423100114

Keywords:

Navigation