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Electrochemical Behavior of a Gold Electrode in the Aqueous Potassium Salt of Bridging 1,2,4,5-Tetraoxane

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Abstract

The behavior of a smooth gold electrode in aqueous solutions of the potassium salt of bridging 1,2,4,5-tetraoxane containing a biperoxide cyclic fragment was studied by cyclic voltammetry. The cathode process was analyzed in detail. It was shown that the process involves four electrons. The products of electrolysis of the potassium salt were studied, and a reaction mechanism was proposed.

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ACKNOWLEDGMENTS

We are grateful to the Multiaccess Center of the Institute of Organic Chemistry, Russian Academy of Sciences, for performing all the analyses given in this article.

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Authors and Affiliations

  1. Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    M. V. Polyakov, M. D. Vedenyapina, I. A. Yaremenko, P. S. Radulov & V. V. Kuznetsov

  2. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    A. M. Skundin

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  1. M. V. Polyakov
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  2. M. D. Vedenyapina
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  3. A. M. Skundin
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  4. I. A. Yaremenko
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  5. P. S. Radulov
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  6. V. V. Kuznetsov
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Correspondence to M. V. Polyakov or V. V. Kuznetsov.

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Translated by L. Smolina

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Polyakov, M.V., Vedenyapina, M.D., Skundin, A.M. et al. Electrochemical Behavior of a Gold Electrode in the Aqueous Potassium Salt of Bridging 1,2,4,5-Tetraoxane. Russ. J. Phys. Chem. 97, 1438–1444 (2023). https://doi.org/10.1134/S0036024423070221

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  • DOI: https://doi.org/10.1134/S0036024423070221

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