Abstract
Flower-like V–Al–O nanobelts have been successfully prepared by a one-pot hydrothermal approach. The nanomaterial was characterized by X-ray diffraction, Fourier transform infrared spectrometry, temperature programmed reduction, energy dispersive X-ray spectrometry, scanning electron microscopy, transmission electron microscopy and N2 adsorption–desorption isotherms. The characterization results revealed that the V–Al–O products consist of one-dimensional nanobelts with lengths of a few microns, widths of 50–100 nm, and thicknesses of 20–30 nm. In addition, the V–Al–O nanomaterial was explored as catalyst for the ammoxidation of 3,4-, 2,4-, and 2,6-dichlorotoluenes to the corresponding dichlorobenzonitriles. It was found that the as-prepared V–Al–O nanostructures exhibited excellent catalytic performance with the yields of 3,4-, 2,4-, and 2,6-DCBN reaching up to 78.0, 77.1, and 73.6%, respectively, at temperature of 360°C, as a result of their novel morphological characteristics.
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REFERENCES
T. Li, W. Zeng, B. Miao, et al., Mater. Lett. 106, 144 (2015).
Y. Xiao, S. Liu, F. Li, et al., Adv. Funct. Mater. 4052, 22 (2012).
W. Jiang, J. Ni, K. Yu, and Z. Zhu, Appl. Surf. Sci. 3253, 257 (2011).
C. Cao, Z. Chen, X. An, and H. Zhu, J. Phys. Chem. C 95, 112 (2008).
Q. Wang, B. Liu, X. Wang, et al., J. Mater. Chem. 21647, 22 (2012).
A. Martin and B. Lücke, Catal. Today 61, 57 (2000).
A. Martin, N. V. Kalevaru, B. Lücke, and J. Sans, Green Chem. 481, 4 (2002).
A. Martin and V. N. Kalevaru, ChemCatChem 1504, 2 (2010).
P. Anbarasan, T. Schareina, and M. Beller, Chem. Soc. Rev. 5049, 40 (2011).
L. Xu, Y. Zhang, Y. Deng, et al., Mater. Res. Bull. 3620, 48 (2013).
N. Dropka, V. N. Kalevaru, A. Martin, et al., J. Catal. 8, 240 (2006).
N. Dhachapally, V. N. Kalevaru, A. Brückner, and A. Martin, Appl. Catal. A 111, 443 (2012).
J. Radnik, N. Dhachapally, V. N. Kalevaru, et al., Catal. Commun. 97, 71 (2015).
G. Silversmit, H. Poelman, R. De Gryse, et al., Catal. Today 344, 118 (2006).
N. Dhachapally, V. N. Kalevaru, J. Radnik, and A. Martin, Chem. Commun. 8394, 47 (2011).
M. Florea, R. Prada-Silvy, and P. Grange, Catal. Lett. 63, 87 (2003).
R. Dwivedi, P. Sharma, A. Sisodiya, et al., J. Catal. 245, 345 (2017).
Y. Zhang, J. Zhang, Y. Zhong, et al., Appl. Surf. Sci. 124, 263 (2012).
F. Wang, Y. Liu, and C. Liu, Electrochim. Acta 2662, 55 (2010).
J. R. Sohn, I. J. Doh, and Y. I. Pae, Langmuir 6280, 18 (2002).
Y. Meng, T. Wang, S. Chen, et al., Appl. Catal. B 161, 160 (2014).
G. Dabrowska, P. Tabero, and M. Kurzawa, J. Phase Equilib. Diffus. 220, 30 (2009).
N. R. Shiju, M. Anilkumar, S. P. Mirajkar, et al., J. Catal. 484, 230 (2005).
B. H. Babu, K. T. V. Rao, Y. W. Suh, et al., New J. Chem. 1892, 42 (2018).
F. Jiang, S. Deng, L. Niu, and G. Xiao, J. Catal. (China) 1833, 34 (2013).
A. Martin, N. V. Kalevaru, B. Lücke, et al., Green Chem. 481, 4 (2002).
X. Xie and W. Shen, Nanoscale 50, 1 (2009).
X. Li and C. Huang, Catal. Lett. 1489, 150 (2020).
ACKNOWLEDGMENTS
This work was partially supported by the National Natural Science Foundation of China (Grant 51572201) and Scientific Research Program of Hubei Provincial Education Department (B2020129).
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Li, X., Yang, S. & Huang, C. Synthesis and Сharacterization of V–Al–O Nanobelts and Their Catalytic Performance. Russ. J. Phys. Chem. 95 (Suppl 2), S259–S263 (2021). https://doi.org/10.1134/S0036024421150140
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DOI: https://doi.org/10.1134/S0036024421150140