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Synthesis and Physicochemical Properties of Coordination Compound of Gadolinium(III) with 2,5-Dimetoxybenzoic Acid

  • COLLOIDAL CHEMISTRY AND ELECTROCHEMISTRY
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Abstract

A new coordination compound of gadolinium(III) with 2,5-dimethoxybenzoic acid was obtained via electrochemical synthesis. The composition of the coordination compound was investigated by means of C‒H analysis, X-ray spectral energy dispersive microanalysis, IR spectroscopy, and thermogravimetric analysis. The triplet level of 2,5-dimethoxybenzoic acid was determined from the luminescence spectra of the metal complex. The parameters of fine structure are determined using EPR spectra of the powder of the metal complex.

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REFERENCES

  1. V. T. Panyushkin and Yu. A. Afanas’ev, Lanthanides. Simple and Complex Compounds (Rost. Univ., Rostov-on-Don, 1980) [in Russian].

    Google Scholar 

  2. J.-C. G. Bunzli and S. V. Eliseeva, J. Rare Earths 28, 824 (2010). https://doi.org/10.1016/S1002-0721(09)60208-8

    Article  CAS  Google Scholar 

  3. J.-C. G. Bunzli, Chem. Rev. 110, 2729 (2010). https://doi.org/10.1021/cr900362e

    Article  CAS  PubMed  Google Scholar 

  4. J. Kido and Y. Okamoto, Chem. Rev. 102, 2357 (2002). https://doi.org/10.1021/cr010448y

    Article  CAS  PubMed  Google Scholar 

  5. V. V. Utochnikova and N. P. Kuzmina, Russ. J. Coord. Chem. 42, 679 (2016). https://doi.org/10.1134/S1070328416090074

    Article  CAS  Google Scholar 

  6. V. F. Zolin, Z. Alloys Compd. 380, 101 (2004). https://doi.org/10.1016/j.jallcom.2004.03.006

  7. M. Hilder, P. C. Junk, U. H. Kynast, and M. M. Lezhnina, Z. Photochem. Photobiol. A 202, 10 (2009). https://doi.org/10.1016/j.jphotochem.2008.10.026

    Article  CAS  Google Scholar 

  8. M. Latva, H. Takalo, V.-M. Mukkala, et al., J. Lumin. 75, 149 (1997). https://doi.org/10.1016/S0022-2313(97)00113-0

    Article  CAS  Google Scholar 

  9. S. B. Meshkova, J. Fluoresc. 10, 333 (2000). https://doi.org/10.1023/A:1009418227641

    Article  CAS  Google Scholar 

  10. M. Hilder, P. C. Junk, U. H. Kynast, and M. M. Lezhnina, Z. Photochem. Photobiol. A 202, 10 (2009). https://doi.org/10.1016/j.jphotochem.2008.10.026

    Article  CAS  Google Scholar 

  11. M. A. Katkova, A. G. Vitukhnovsky, and M. N. Bochkarev, Russ. Chem. Rev. 74, 1089 (2005). https://doi.org/10.1070/RC2005v074n12ABEH002481

    Article  CAS  Google Scholar 

  12. Z. A. Taha, A. M. Ajlouni, A. K. Hijazi, et al., J. Lumin. 161, 229 (2015). https://doi.org/10.1016/j.jlumin.2015.01.013

    Article  CAS  Google Scholar 

  13. D. I. Alexropoulos, K. R. Vignesh, B. S. Dolinar, et al., Polyhedron 151, 255 (2018). https://doi.org/10.1016/j.poly.2018.04.034

    Article  CAS  Google Scholar 

  14. S. N. Ivanin, V. Yu. Buz’ko, A. I. Goryachko, and V. T. Panyushkin, Russ. J. Phys. Chem. A 94, 1623 (2020). https://doi.org/10.1134/S0036024420080130

    Article  CAS  Google Scholar 

  15. S. N. Ivanin, V. Yu. Buz’ko, A. I. Goryachko, and V. T. Panyushkin, Russ. J. Inorg. Chem. 65, 880 (2020). https://doi.org/10.1134/S0036023620060066

    Article  CAS  Google Scholar 

  16. S. N. Ivanin, V. Yu. Buz’ko, A. I. Goryachko, and V. T. Panyushkin, Russ. J. Phys. Chem. A 95, 326 (2021). https://doi.org/10.1134/S0036024421020114

    Article  CAS  Google Scholar 

  17. M. A. Nazarenko, A. I. Oflidi, F. A. Kolokolov, and V. T. Panyushkin, Russ. J. Gen. Chem. 87, 1022 (2017). https://doi.org/10.1134/S1070363217050218

    Article  CAS  Google Scholar 

  18. V. Yu. Frolov, A. I. Oflidi, S. N. Bolotin, A. I. Shestavin, and V. T. Panyushkin, Russ. J. Appl. Chem. 81, 639 (2008). https://doi.org/10.1134/S1070427208040137

    Article  CAS  Google Scholar 

  19. K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds (Wiley, New York, 1986).

    Google Scholar 

  20. L. J. Bellami, The Infra-Red Spectra of Complex Molecules (Chapman and Hall, London, 1975).

    Book  Google Scholar 

  21. A. S. Kalyakina, E. Y. Sokolova, and A. A. Vaschenko, in Proceedings of the SID Mid-Europe Chapter Spring Meeting, 2013, p. 19.

  22. E. R. Trivedi, S. V. Eliseeva, J. Jankolovist, et al., J. Am. Chem. Soc. 136, 1526 (2014). https://doi.org/10.1021/ja4113337

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  23. M. Kleinerman, J. Chem. Phys. 51, 2370 (1969). https://doi.org/10.1063/1.1672355

    Article  CAS  Google Scholar 

  24. S. Stoll and A. Schweiger, J. Magn. Reson. 178, 42 (2006). https://doi.org/10.1016/j.jmr.2005.08.013

    Article  CAS  PubMed  Google Scholar 

  25. S. Stoll and A. Schweiger, Biol. Magn. Reson. 27, 299 (2007). https://doi.org/10.1063/1.3426295

    Article  CAS  Google Scholar 

  26. S. A. Altshuler and B. M. Kozyrev, Electron Paramagnetic Resonance of Compounds of Elements of the Intermediate Groups (Nauka, Moscow, 1972) [in Russian].

    Google Scholar 

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Funding

This work was performed on equipment belonging to the Scientific and Educational Center for Diagnostics of the Structure and Properties of Nanomaterials at the shared resource center of Kuban State University. It was supported by the RF Ministry of Science and Education, state task no. FZEN-2020-0022; and by the Russian Foundation for Basic Research and the Administration of Krasnodar krai as part of scientific project no. 19-43-233003 r_mol_a.

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Correspondence to S. N. Ivanin.

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Translated by M. Drozdova

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Nazarenko, M.A., Ivanin, S.N., Oflidi, A.I. et al. Synthesis and Physicochemical Properties of Coordination Compound of Gadolinium(III) with 2,5-Dimetoxybenzoic Acid. Russ. J. Phys. Chem. 95, 1948–1954 (2021). https://doi.org/10.1134/S0036024421090181

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