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Structural–Thermodynamic Characteristics of Maleic Acid in Water–Organic Solvents

  • PHYSICAL CHEMISTRY OF SOLUTIONS
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Abstract

Results are presented from investigating the structure of maleic acid, processes of gas-phase protonation, and acid–base equilibria with the participation of maleic acid in water–ethanol and water–dimethylsulfoxide solutions. The рK values of maleic acid dissociation in water–ethanol and water–dimethylsulfoxide solvents are determined. It is established that the рK values grow along with the content of the nonaqueous component in a water–organic mixture. Analysis of the solvation contributions from all reagents participating in the acid dissociation of maleic acid in water–ethanol and water–dimethylsulfoxide solvents reveals that the main contribution to the increase in рK1 and рK2 comes from the desolvation of anions.

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Funding

This work was performed as part of a State Task from the RF Ministry of Science and Higher Education, project no. FZZW-2020-0009.

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Authors and Affiliations

  1. Ivanovo State University of Chemistry and Technology, 153000, Ivanovo, Russia

    N. V. Tukumova, N. V. Belova & T. R. Usacheva

  2. Faculty of Chemical Engineering, Industrial University of HoChiMinh City, 12 Nguyen Van Bao, Go Vap, 700000, Ho Chi Minh, Vietnam

    Tran Thi Dieu Thuan

Authors
  1. N. V. Tukumova
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  2. N. V. Belova
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  3. T. R. Usacheva
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  4. Tran Thi Dieu Thuan
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Corresponding authors

Correspondence to N. V. Tukumova or Tran Thi Dieu Thuan.

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Translated by Z. Smirnova

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Tukumova, N.V., Belova, N.V., Usacheva, T.R. et al. Structural–Thermodynamic Characteristics of Maleic Acid in Water–Organic Solvents. Russ. J. Phys. Chem. 95, 1342–1349 (2021). https://doi.org/10.1134/S0036024421070268

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  • DOI: https://doi.org/10.1134/S0036024421070268

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