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Thermodynamic Characteristics of Protolytic Equilibria of L-Alanayl-L-isoleucine in Aqueous Solutions

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Abstract

Potentiometry and calorimetry are used to study protolytic equilibria in aqueous solutions of L‑alanyl-L-isoleucine. The equilibrium constants and heat effects of the dipeptide dissociation reactions are determined. The standard thermodynamic characteristics of the investigated equilibria are calculated. The obtained results are compared to the corresponding data for related compounds.

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REFERENCES

  1. S. N. Gridchin and G. G. Gorboletova, Russ. J. Gen. Chem. 78, 429 (2008).

    Article  CAS  Google Scholar 

  2. G. G. Gorboletova, L. A. Kochergina, and V. P. Vasil’ev, Russ. J. Phys. Chem. A 75, 902 (2001).

    Google Scholar 

  3. S. N. Gridchin, G. G. Gorboletova, and D. F. Pyreu, Russ. J. Phys. Chem. A 81, 1941 (2007).

    Article  CAS  Google Scholar 

  4. S. N. Gridchin and D. F. Pyreu, Russ. J. Phys. Chem. A 89, 1 (2015).

    Article  CAS  Google Scholar 

  5. V. P. Vasil’ev, G. G. Gorboletova, and L. A. Kochergina, Russ. J. Phys. Chem. A 75, 1900 (2001).

    Google Scholar 

  6. G. G. Gorboletova and L. A. Kochergina, J. Term. Anal. Calorim. 87, 561 (2007).

    Article  CAS  Google Scholar 

  7. G. G. Gorboletova, S. N. Gridchin, and E. S. Sazonova, Russ. J. Phys. Chem. A 79, 1222 (2005).

    CAS  Google Scholar 

  8. S. N. Gridchin and D. F. Pyreu, Russ. J. Gen. Chem. 77, 1037 (2007).

    Article  CAS  Google Scholar 

  9. S. N. Gridchin, G. G. Gorboletova, and D. F. Pyreu, J. Term. Anal. Calorim. 90, 607 (2007).

    Article  CAS  Google Scholar 

  10. S. N. Gridchin, Russ. J. Gen. Chem. 83, 1315 (2013).

    Article  CAS  Google Scholar 

  11. S. N. Gridchin, Russ. J. Gen. Chem. 85, 810 (2015).

    Article  CAS  Google Scholar 

  12. S. N. Gridchin, Russ. J. Phys. Chem. A 90, 2170 (2016).

    Article  CAS  Google Scholar 

  13. V. A. Borodin, E. V. Kozlovskii, and V. P. Vasil’ev, Zh. Neorg. Khim. 31, 10 (1986).

    CAS  Google Scholar 

  14. D. Himmelblau, Applied Nonlinear Programming (McGraw-Hill, New York, 1971).

    Google Scholar 

  15. A. A. Bugaevskii and B. A. Dunai, Zh. Anal. Khim. 26, 205 (1971).

    CAS  Google Scholar 

  16. V. P. Vasil’ev, V. A. Borodin, and E. V. Kozlovskii, Application of PC in Analytical Chemistry Calculations (Vyssh. Shkola, Moscow, 1993) [in Russian].

    Google Scholar 

  17. V. P. Vasil’ev, Thermodynamic Properties of Electrolyte Solutions (Vysshaya Shkola, Moscow, 1982) [in Russian].

    Google Scholar 

  18. S. D. Varfolomeev, Chemical Enzymology (Akademiya, Moscow, 2005) [in Russian].

    Google Scholar 

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Funding

This work was performed at the Research Institute of the Thermodynamics and Kinetics of Chemical Processes as part of a State Task for research and development, topic no. FZZW-2020-0009.

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Correspondence to S. N. Gridchin.

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Gridchin, S.N., Nikol’skii, V.M. Thermodynamic Characteristics of Protolytic Equilibria of L-Alanayl-L-isoleucine in Aqueous Solutions. Russ. J. Phys. Chem. 95, 80–83 (2021). https://doi.org/10.1134/S0036024421010106

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  • DOI: https://doi.org/10.1134/S0036024421010106

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