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Optical Study of Anisotropy in Organic Conductors D4[MBr4](Solvent)

  • PROCEEDINGS OF THE CONFERENCE “PHYSICAL CHEMISTRY IN RUSSIA AND BEYOND: FROM QUANTUM CHEMISTRY TO EXPERIMENT” (CHERNOGOLOVKA)
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Abstract

The polarized reflectance and optical conductivity spectra of layered organic conductors D4[MBr4](Solvent): θ-(BEDT-TTF)4HgBr4(DCB), θ-(BEDT-TTF)4CdBr4(DBB), θ-(d8-BEDT-TTF)4CdBr4(DBB), and θ-(BETS)4CdBr4(PhBr) (DCB and DBB = o-dichloro and o-dibromo-benzenes, BEDT-TTF and BETS are bis(ethylenedithio)tetrathia- and bis(ethylenedithio)tetraselena-fulvalene) are studied. The adjacent conducting layers of these compounds differ in the direction of their stacks of radical cations (the directions of the stacks are mutually perpendicular). It is shown that these conductors are characterized by high isotropy of the electronic system in the conducting plane and the quasi-two-dimensional nature of the electronic conductivity, which is in good agreement with the crystal structure.

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REFERENCES

  1. J. M. Williams, J. R. Ferraro, R. J. Thorn, K. D. Carlson, U. Geiser, H. H. Wang, A. M. Kini, and M. H. Whangbo, Organic Superconductors (Including Fullerenes). Synthesis, Structure, Properties, and Theory (Prentice Hall, Englewood Cliffs, NJ, 1992).

    Google Scholar 

  2. M. Dressel, Crystals 8, 332 (2018). https://doi.org/10.3390/cryst8090332

    Article  CAS  Google Scholar 

  3. E. I. Zhilyaeva, V. N. Semkin, E. I. Yudanova, R. M. Vlasova, S. A. Torunova, A. M. Flakina, G. A. Mousdis, K. V. Van, A. Graja, A. Lapinski, R. B. Lyubovskii, and R. N. Lyubovskaya, Russ. Chem. Bull. 59, 1360 (2010). https://doi.org/10.1007/s11172-010-0247-4

    Article  CAS  Google Scholar 

  4. R. Lyubovskaya, E. Zhilyaeva, G. Shilov, et al., Eur. J. Inorg. Chem. 3820 (2014). https://doi.org/10.1002/ejic.201402041

  5. E. I. Zhilyaeva, G. V. Shilov, S. A. Torunova, et al., Cryst. Eng. Commun. 16, 10103 (2014). https://doi.org/10.1039/c4ce01440e

    Article  CAS  Google Scholar 

  6. E. I. Zhilyaeva, K. A. Dzyuba, A. M. Flakina, G. V. Shilov, A. V. Kulikov, R. B. Lyubovskii, and R. N. Lyubovskaya, Russ. Chem. Bull. 60, 1636 (2013). https://doi.org/10.1007/s11172-013-0237-4

    Article  CAS  Google Scholar 

  7. E. I. Zhilyaeva, K. A. Dzyuba, S. A. Torunova, et al., Synth. Met. 209, 329 (2015). https://doi.org/10.1016/j.synthmet.2015.07.023

    Article  CAS  Google Scholar 

  8. M. G. Kaplunov and Yu. G. Borod’ko, Khim. Fiz. 6, 1529 (1987).

    CAS  Google Scholar 

  9. R. M. Vlasova, O. O. Drozdova, V. N. Semkin, et al., Phys. Solid State 41, 814 (1999). https://doi.org/10.1134/1.1130880

    Article  CAS  Google Scholar 

  10. M. Dressel and N. Drichko, Chem. Rev. 104, 5689 (2004). https://doi.org/10.1021/cr030642f

    Article  PubMed  CAS  Google Scholar 

  11. E. I. Zhilyaeva, O. A. Bogdanova, A. M. Flakina, et al., Synth. Met. 161, 799 (2011). https://doi.org/10.1016/j.synthmet.2011.02.002

    Article  CAS  Google Scholar 

  12. E. I. Zhilyaeva, O. A. Bogdanova, G. V. Shilov, et al., Synth. Met. 159, 1072 (2009). https://doi.org/10.1016/j.synthmet.2009.01.028

    Article  CAS  Google Scholar 

  13. E. I. Zhilyaeva, O. A. Bogdanova, A. M. Flakina, G. V. Shilov, R. B. Lyubovskii, and R. N. Lyubovskaya, Russ. Chem. Bull. 58, 1357 (2011). https://doi.org/10.1007/s11172-011-0202-z

    Article  CAS  Google Scholar 

  14. T. Mori, H. Mori, and S. Tanaka, Bull. Chem. Soc. Jpn. 72, 179 (1999). https://doi.org/10.1246/bcsj.72.179

    Article  CAS  Google Scholar 

  15. R. B. Lyubovskii, S. I. Pesotskii, S. V. Konovalikhin, et al., Synth. Met. 123, 149 (2001). https://doi.org/10.1016/S0379-6779(00)01381-3

    Article  CAS  Google Scholar 

  16. R. B. Lyubovskii, S. I. Pesotskii, O. A. Bogdanova, E. I. Zhilyaeva, A. M. Flakina, and R. N. Lyubovskaya, Russ. Chem. Bull. 58, 1363 (2011). https://doi.org/10.1007/s11172-011-0202-z

    Article  CAS  Google Scholar 

  17. H. Tajima, H. Kyoden, H. Mori, and S. Tanaka, Phys. Rev. B 62, 9378 (2000). https://doi.org/10.1103/PhysRevB.62.9378

    Article  CAS  Google Scholar 

  18. J. R. Ferraro, H. H. Wang, U. Geiser, et al., Solid State Commun. 68, 917 (1988). https://doi.org/10.1016/0038-1098(88)90134-2

    Article  CAS  Google Scholar 

  19. K. Kornelsen, J. Eldridge, H. H. Wang, and J. M. Williams, Solid State Commun. 74, 501 (1990). https://doi.org/10.1016/0038-1098(90)90336-A

    Article  CAS  Google Scholar 

  20. R. M. Vlasova, N. V. Drichko, B. V. Petrov, V. N. Semkin, E. I. Zhilyaeva, O. A. Bogdanova, R. N. Lyubovskaya, and A. Graja, Phys. Solid State 44, 8 (2002). https://doi.org/10.1134/1.1434475

    Article  CAS  Google Scholar 

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ACKNOWLEDGMENTS

The authors thank R.M. Vlasova and B.V. Petrov for measuring the reflectance spectra of compounds 1–3.

Funding

This work was performed in accordance with State Task no. 0089-2019-0011.

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Russia

    E. I. Zhilyaeva, G. V. Shilov, A. M. Flakina, S. A. Torunova & R. N. Lyubovskaya

  2. Johns Hopkins University, MD 21218, Baltimore, USA

    N. V. Drichko

Authors
  1. E. I. Zhilyaeva
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  2. N. V. Drichko
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  3. G. V. Shilov
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  4. A. M. Flakina
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  5. S. A. Torunova
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  6. R. N. Lyubovskaya
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Corresponding author

Correspondence to E. I. Zhilyaeva.

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Translated by D. Kharitonov

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Zhilyaeva, E.I., Drichko, N.V., Shilov, G.V. et al. Optical Study of Anisotropy in Organic Conductors D4[MBr4](Solvent). Russ. J. Phys. Chem. 94, 990–995 (2020). https://doi.org/10.1134/S0036024420050301

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