Abstract
The density of solutions of 1,4-dioxane (DO) in monoethanolamine (MEA) in 0–0.2 ppm DO concentrations and the temperature range of 25–75°C is measured to examine solvophobic effects in solvents with spatial networks of hydrogen bonds. Apparent and excess molar volumes of DO in a MEA–DO mixture are calculated. The obtained concentration and temperature dependences of the bulk properties of DO show there were no solvophobic effects in the studied liquid system, which is explained by the insufficient lability of the H-bond network in MEA in the investigated range of temperatures. The results are compared to similar literature data on the H2O–DO and ethylene glycol (EG)–DO systems. The hydrophobic effect was detected earlier in the H2O–DO system; based on the bulk properties, the solvophobic effect was not observed in the EG–DO system in the temperature range of 25–75°C.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
REFERENCES
M. N. Rodnikova, Zh. Fiz. Khim. 67, 275 (1993).
M. H. Rodnikova, Structural Self-Organization in Solutions and at the Phase Boundary, Ed. by M. N. Rodnikova (LKI, Moscow, 2008) [in Russian].
Aldrich Handbook (1989).
Y. Maham, C. -N. Liew, and A. E. Mather, J. Solution Chem. 31, 743 (2002). https://doi.org/10.1023/A:1021133008053
E. Quijada-Maldonado, G. W. Meindersma, and A. B. de Haan, J. Chem. Thermodyn. 57, 500 (2013). https://doi.org/10.1016/j.jct.2012.08.024
M. N. Rodnikova, F. M. Samigullin, I. A. Solonina, and D. A. Sirotkin, J. Struct. Chem. 55, 256 (2014). https://doi.org/10.1134/S0022476614020097
O. A. Osipov, V. I. Minkin, and A. D. Garnovskii, Dipole Moments: Handbook (Vyssh. Shkola, Moscow, 1971) [in Russian].
M. N. Buslaeva, V. G. Tsvetkov, V. G. Markova, et al., Zh. Koord. Khim. 9, 752 (1983).
D. M. Chapman and R. E. Hester, J. Phys. Chem. A 101, 3382 (1997). https://doi.org/10.1021/jp962932o
J. Buschmann, E. Moller, and P. Luger, Acta Crystallogr. 42, 873 (1986). https://doi.org/10.1107/S0108270186094222
R. B. Torres, A. C. M. Marchiore, and P. L. O. Volpe, J. Chem. Thermodyn. 38, 526 (2006). https://doi.org/10.1016/j.jct.2005.07.012
M. N. Rodnikova, I. A. Solonina, G. I. Egorov, et al., Russ. J. Phys. Chem. A 86, 330 (2012). https://doi.org/10.1134/S0036024412020239
G. I. Egorov and D. M. Makarov, Russ. J. Phys. Chem. A 82, 1778 (2008).
G. I. Egorov and D. M. Makarov, Russ. J. Phys. Chem. A 83, 693 (2009).
M. N. Rodnikova, N. N. Breslavskaya, I. A. Solonina, S. P. Dolin, and T. M. Val’kovskaya, Russ. J. Inorg. Chem. 58, 180 (2013).
Funding
This work was performed as part of a State Task for the Institute of General and Inorganic Chemistry in the field of basic scientific research. It was supported by the Russian Foundation for Basic Research, grant no. 19-03-00215.
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated by D. Kharitonov
Rights and permissions
About this article
Cite this article
Solonina, I.A., Rodnikova, M.N., Egorov, G.I. et al. Bulk Properties of the Monoethanolamine–1,4-Dioxane System. Russ. J. Phys. Chem. 94, 709–712 (2020). https://doi.org/10.1134/S0036024420040196
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0036024420040196