Abstract
The temperature dependences of the specific heat capacities of nanosized samples of lanthanum magnesium cobaltite cuprate manganite LaMgCoCuMnO6 and lanthanum magnesium nickelite cuprate manganite LaMgNiCuMnO6 are studied via calorimetry in the temperature range of 298.15–673 K. Curve \(C_{p}^{ \circ }\)(T) shows that LaMgCoCuMnO6 and LaMgNiCuMnO6 undergo second-order phase transitions at 398 and 523 K, respectively. The standard specific heat capacities of the above compounds are calculated with independent means based on characteristic Debye temperatures determined via the Koref and Nernst–Lindemann equations. Their values agree satisfactorily with experimental data. The temperature dependences of functions S°(T), H°(T) – H°(298.15), and Фхх(T) are calculated.
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Funding
This work was supported under a contract between the Committee for Science, Ministry of Education and Science, Republic of Kazakhstan, and the Abishev Chemical Metallurgical Institute, grant nos. IRN: AR05131317, AR05131333).
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Translated by V. Glyanchenko
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Kasenov, B.K., Kasenova, S.B., Sagintaeva, Z.I. et al. Thermodynamic Properties of Nanosized Cobaltite (Nickelite) Cuprate Manganites LaMgCoCuMnO6 and LaMgNiCuMnO6. Russ. J. Phys. Chem. 94, 18–22 (2020). https://doi.org/10.1134/S0036024420010136
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DOI: https://doi.org/10.1134/S0036024420010136