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Russian Journal of Physical Chemistry A

, Volume 93, Issue 6, pp 1045–1048 | Cite as

Rate Constant of the Reaction between Ozone and Chloride Ion in an Aqueous Solution According to a Mechanism of Oxygen Atom Transfer

  • A. V. LevanovEmail author
  • O. Ya. Isaikina
  • V. V. Lunin
CHEMICAL KINETICS AND CATALYSIS
  • 23 Downloads

Abstract

The effect of concentrations of Cl and H+ ions, temperature, and ionic strength on the rate constant of the reaction between O3 and Cl(aq) is studied experimentally. The reaction proceeds according to a mechanism of oxygen transfer and results in the formation of molecular chlorine in acidic medium. A formula is proposed for calculating the dependence of the rate constant on these factors.

Keywords:

ozone chloride ion rate constant ionic strength molecular chlorine 

Notes

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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • A. V. Levanov
    • 1
    Email author
  • O. Ya. Isaikina
    • 1
  • V. V. Lunin
    • 1
  1. 1.Department of Chemistry, Moscow State UniversityMoscowRussia

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