Abstract
The heat capacity and volumetric properties of ammonium thiocyanate solutions in N-methylpyrrolidone are measured at 298.15 K by calorimetric and densimetric means. Concentration dependences of the partial and apparent molar heat capacities and volumes of the investigated systems are discussed. The standard partial molar heat capacity and volume of NH4CNS, and the standard heat capacity and volume of ammonium and thiocyanate ions in N-methylpyrrolidone at 298.15 K are calculated.
Similar content being viewed by others
REFERENCES
V. A. Vasilev and A. N. Novikov, Zh. Fiz. Khim. 67, 1387 (1993).
A. N. Novikov and V. A. Vasilev, Russ. J. Phys. Chem. A 80, 505 (2006).
A. N. Novikov, O. F. Lenina, and V. A. Vasilev, Russ. J. Phys. Chem. A 81, 1743 (2007).
A. N. Novikov and V. A. Vasilev, Russ. J. Phys. Chem. A 82, 1071 (2008).
A. N. Novikov, O. F. Lenina, and V. A. Vasilev, Russ. J. Phys. Chem. A 83, 392 (2009).
A. N. Novikov, Russ. J. Phys. Chem. A 83, 6 (2009).
A. N. Novikov, Russ. J. Phys. Chem. A 83, 334 (2009).
A. N. Novikov, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol. 52 (6), 16 (2009).
A. N. Novikov, Russ. J. Phys. Chem. A 87, 1448 (2013).
L. Yu. Rassokhina and A. N. Novikov, Russ. J. Phys. Chem. A 87, 1825 (2013).
A. N. Novikov, Extended Abstract of Doctoral (Chem.) Dissertation (Mendeleev Russ. Chem.-Technol. Univ., Moscow, 2011).
B. V. Mikhailin, A. F. Vorob’ev, and V. A. Vasilev, Zh. Fiz. Khim. 56, 1937 (1982).
A. F. Kapustinskii, M. S. Stakhanova, and V. A. Vasilev, Russ. Chem. Bull. 9, 1933 (1960).
J. L. Wuepper and A. I. Popov, J. Am. Chem. Soc. 91, 4352 (1969).
J. Rosenfarb and R. J. Baker, J. Phys. Chem. 82, 329 (1978).
Problems of Solution Chemistry. Achievements and Problems of the Solvation Theory: Structural and Thermodynamic Aspects, Ed. by V. K. Abrosimov, G. A. Krestov, G. A. Al’per (Nauka, Moscow, 1998) [in Russian].
S. F. Sun, J. Chem. Soc., Faraday Trans. 1 78, 2765 (1982).
A. J. Pasztor and C. M. Criss, J. Solution Chem. 7, 27 (1978).
F. Kawaizumi and R. Zana, J. Phys. Chem. 78, 627 (1974).
U. Sen, J. Phys. Chem. 81, 35 (1977).
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated by D. Kharitonov
Rights and permissions
About this article
Cite this article
Novikov, A.N., Kostyleva, E.I., Vasilev, V.A. et al. Heat Capacity and Volume Properties of Ammonium Thiocyanate in N-Methylpyrrolidone Solution at 298.15 K. Russ. J. Phys. Chem. 93, 991–992 (2019). https://doi.org/10.1134/S0036024419050236
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0036024419050236