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Thermodynamics of the Dissolution of Macrocyclic Compounds Based on 2-Phenylindene with Naphthylenediamine Fragments in DMF and Ethanol

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Abstract

The solubilities of compounds based on 1-imino-2-phenyl-1H-indene-3-amine with 1,4-diaminonaphthalene and 1,4-diaminonaphthalene-5-sulfonic acid fragments in DMF and ethanol at 298–318 K are studied via isothermal saturation with spectrophotometric monitoring of their concentrations. Patterns of the dissolution of 1 : 2, 2 : 1, and 2 : 2 products of condensation in DMF and ethanol are discussed. The thermodynamic parameters of the dissolution of the synthesized compounds were calculated.

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ACKNOWLEDGMENTS

This work was performed on equipment of the shared resource center at Ivanovo State University of Chemistry and Technology.

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Authors and Affiliations

  1. Ivanovo State University of Chemistry and Technology, 153000, Ivanovo, Russia

    G. R. Berezina

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  1. G. R. Berezina
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Correspondence to G. R. Berezina.

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Translated by K. Utegenov

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Berezina, G.R. Thermodynamics of the Dissolution of Macrocyclic Compounds Based on 2-Phenylindene with Naphthylenediamine Fragments in DMF and Ethanol. Russ. J. Phys. Chem. 93, 840–844 (2019). https://doi.org/10.1134/S0036024419050054

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  • DOI: https://doi.org/10.1134/S0036024419050054

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