Abstract
The solubility of DL-malic acid in methanol, ethanol, propanol, butanol, ethyl acetate and acetonitrile in the temperature range 283–318 K was measured by acid–base titration method. The solubility of DL-malic acid increased with elevating temperature. The solubility data were correlated by the modified Apelblat, Buchowski–Książczak, Van’t Hoff, Wilson, and non-random two-liquid equations. The calculation results showed that these equations provide good prediction with the acceptable ARD values and RMSD values among all the satisfactory fitting results given by each equation. The mixing Gibbs energy, enthalpy and entropy of real solution were derived based on the Wilson equation and the measured solubility data.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
REFERENCES
S. Nakayama, K. Tabata, T. Oba, K. Kusumoto, S. Mitsuiki, T. Kadokura, and A. Nakazato, J. Biosci. Bioeng. 114, 281 (2012).
S. Y. Moon, S. H. Hong, T. Y. Kim, and S. Y. Lee, Biochem. Eng. J. 40, 312 (2008).
J. W. Lee, M-S. Han, S. Choi, J. Yi, T. W. Lee, and S. Y. Lee, Comprehensive Biotechnology (Elsevier, Amsterdam, 2011).
X. Zhang, S. Zhang, X. Sun, Z. Yin, Q. Liu, X. Zhang, and Q. Yin, Front. Chem. Sci. Eng. 7, 490 (2013).
P. Cui, Q. Yin, J. Gong, Y. Wang, H. Hao, C. Xie, Y. Bao, M. Zhang, B. Hou, and J. Wang, Fluid Phase Equilib. 337, 354 (2013).
A. S. Myerson, Handbook of Industrial Crystallization (Butterworth-Heinemann, Oxford, 2002).
H. Yang and A. C. Rasmuson, J. Chem. Eng. Data 55, 5091 (2010).
Q. Zhang, Y. Yang, L. Cheng, C. Cao, Z. Ding, C. Wang, W. Yang, Y. Hu, and Y. Li, J. Chem. Thermodyn. 85, 148 (2015).
Y. Yuan, Y. Leng, H. Shao, C. Huang, and K. Shan, Fluid Phase Equilib. 377, 27 (2014).
I. M. Smallwood, Handbook of Organic Solvent Properties (Wiley, New York, 1996).
N. A. Lange and M. H. Sinks, J. Am. Chem. Soc. 52, 2602 (1930).
E. Manzurola and A. Apelblat, J. Chem. Thermodyn. 34, 1127 (2002).
A. Apelblat, E. Manzurola, and N. Abo Balal, J. Chem. Thermodyn. 38, 565 (2006).
M. M. L. Duarte, J. Lozar, G. Malmary, and J. Molinier, J. Chem. Eng. Data 34, 43 (1989).
L. Zhou, Q. Yin, Z. Guo, H. Lu, M. Liu, W. Chen, and B. Hou, J. Chem. Thermodyn. 105, 133 (2017).
M. A. Filippa and E. I. Gasull, Fluid Phase Equilib. 354, 185 (2013).
M. A. Varfolomeev, I. T. Rakipov, W. E. Acree, Jr., M. Brumfield, and M. H. Abraham, Thermochim. Acta 594, 68 (2014).
J. M. Hughes, D. Aherne, and J. N. Coleman, J. Appl. Polym. Sci. 127, 4483 (2013).
A. Apelblat and E. Manzurola, J. Chem. Thermodyn. 29, 1527 (1997).
A. Apelblat and E. Manzurola, J. Chem. Thermodyn. 31, 85 (1999).
G. M. Wilson, J. Am. Chem. Soc. 86, 127 (1964).
J. Fang, M. Zhang, P. Zhu, J. Ouyang, J. Gong, W. Chen, and F. Xu, J. Chem. Thermodyn. 85, 202 (2015).
Y. Cong, J. Wang, C. Du, S. Han, L. Meng, and H. Zhao, J. Chem. Thermodyn. 100, 60 (2016).
Y. Tong, Z. Wang, E. Yang, B. Pan, J. Jiang, L. Dang, and H. Wei, Fluid Phase Equilib. 427, 549 (2016).
J. Li, Z. Wang, Y. Bao, and J. Wang, Ind. Eng. Chem. Res. 52, 3019 (2013).
Author information
Authors and Affiliations
Corresponding author
Additional information
The article is published in the original.
Rights and permissions
About this article
Cite this article
Huang Chunxiang, Yun, F., Yongmei, X. et al. Correlation of Solubility and Solution Thermodynamics of DL-Malic Acid in Organic Solvents at Different Temperatures. Russ. J. Phys. Chem. 92, 2710–2717 (2018). https://doi.org/10.1134/S0036024418130149
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0036024418130149