Russian Journal of Physical Chemistry A

, Volume 92, Issue 5, pp 909–917 | Cite as

Formation of Mixed-Ligand Complexes of Metals(II) with Monoamine Complexones and Amino Acids in Solution

  • D. F. Pyreu
  • S. N. Gridchin
Physical Chemistry of Solutions


The formation of mixed-ligand complexes in the M(II)–Nta, Ida–L (M = Cu(II), Ni, Zn, Co(II), L = Ser, Thr, Asp, Arg, Asn) systems, where Ida and Nta are the residues of iminodiacetic and nitrilotriacetic acids, respectively, is studied using pH measurements, calorimetry and spectrophotometry. The thermodynamic parameters (logK, ΔrG0, ΔrH, ΔrS) of their formation at 298.15 K and ionic strength I = 0.5 (KNO3) are determined. The most likely scenario of amino acid residue coordination in the composition of mixed complexes is discussed.


mixed-ligand complexation monoamine complexones amino acids calorimetry denticity 


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.


  1. 1.
    G. S. Chaga, J. Biochem. Biophys. Methods 49, 313 (2001).CrossRefGoogle Scholar
  2. 2.
    V. Gaberc-Porekar and V. Menart, J. Biochem. Biophys. Methods 49, 335 (2001).CrossRefGoogle Scholar
  3. 3.
    G. Sharma and J. P. Tandon, Talanta 18, 1163 (1971).CrossRefGoogle Scholar
  4. 4.
    P. C. Parikh and P. K. Bhattacharya, J. Indian Chem. Soc. 50, 804 (1973).Google Scholar
  5. 5.
    M. V. Chidambaram and P. K. Bhattacharya, Acta Chim. Hung. 75, 123 (1975).Google Scholar
  6. 6.
    E. V. Kozlovskii, T. B. Khochenkova, and D. F. Pyreu, Russ. J. Inorg. Chem. 53, 1158 (2008).CrossRefGoogle Scholar
  7. 7.
    I. Kiseleva, D. Pyreu, T. Krivonogikh, M. Bazanova, T. Hochenkova, and E. Kozlovskii, Polyhedron 51, 10 (2013).CrossRefGoogle Scholar
  8. 8.
    D. F. Pyreu, M. A. Bazanova, S. N. Gridchin, and E. V. Kozlovskii, Russ. J. Inorg. Chem. 61, 909 (2016).CrossRefGoogle Scholar
  9. 9.
    D. Pyreu, T. Molkova, S. Ryzkova, M. Bazanova, and S. Gridchin, J. Therm. Anal. Calorim. 124, 1003 (2016).CrossRefGoogle Scholar
  10. 10.
    V. A. Borodin, V. P. Vasil’ev, and E. V. Kozlovskii, Mathematical Problems of Chemical Thermodynamics (Nauka, Novosibirsk, 1985), p. 219 [in Russian].Google Scholar
  11. 11.
    G. Anderegg, F. Arnaud-Neu, R. Delgado, et al., Pure Appl. Chem. 77, 1445 (2005).CrossRefGoogle Scholar
  12. 12.
    G. Berthon, Pure Appl. Chem. 67, 1117 (1995).CrossRefGoogle Scholar
  13. 13.
    G. Anderegg, Pure Appl. Chem. 54, 2693 (1982).CrossRefGoogle Scholar
  14. 14.
    O. Yamauchi and A. Odani, Pure Appl. Chem. 68, 469 (1996).CrossRefGoogle Scholar
  15. 15.
    T. Szabo-Planka, A. Rockenbauer, and L. Korecz, Polyhedron 18, 1969 (1999).CrossRefGoogle Scholar
  16. 16.
    A. Rockenbauer, T. Szabo-Planka, Z. Arkosi, and L. Korecz, J. Am. Chem. Soc. 123, 7646 (2001).CrossRefGoogle Scholar
  17. 17.
    I. Nagypál, A. Gergely, and E. Farkas, J. Inorg. Nucl. Chem. 36, 699 (1974).CrossRefGoogle Scholar
  18. 18.
    J. Israeli and M. Cecchetti, Can. J. Chem. 46, 3821 (1968).CrossRefGoogle Scholar
  19. 19.
    T. Sakurai, O. Yamauchi, and A. Nakahara, Bull. Chem. Soc. Jpn. 49, 1579 (1976).CrossRefGoogle Scholar
  20. 20.
    T. Sakurai, O. Yamauchi, and A. Nakahara, Bull. Chem. Soc. Jpn. 49, 169 (1976).CrossRefGoogle Scholar
  21. 21.
    O. Yamauchi, T. Sakurai, and A. Nakahara, J. Am. Chem. Soc. 101, 4164 (1979).CrossRefGoogle Scholar
  22. 22.
    T. Ono, H. Shimanouchi, T. Sakurai, O. Yamauchi, and A. Nakahara, Bull. Chem. Soc. Jpn. 52, 2229 (1979).CrossRefGoogle Scholar
  23. 23.
    M. S. Bukharov, V. G. Shtyrlin, A. Sh. Mukhtarov, et al., Phys. Chem. Chem. Phys. 16, 9411 (2014).CrossRefGoogle Scholar
  24. 24.
    E. V. Kozlovskii and A. Ya. Fridman, Zh. Neorg. Khim. 36, 1500 (1991).Google Scholar
  25. 25.
    E. V. Kozlovskii, G. V. Chistyakova, and V. P. Vasil’ev, Zh. Neorg. Khim. 34, 853 (1989).Google Scholar

Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  1. 1.Ivanovo State UniversityIvanovoRussia
  2. 2.Ivanovo State University of Chemistry and TechnologyIvanovoRussia

Personalised recommendations