Russian Journal of Physical Chemistry A

, Volume 92, Issue 5, pp 853–861 | Cite as

Radical Abstraction Reactions with Concerted Fragmentation in the Chain Decay of Nitroalkanes

  • E. T. Denisov
  • A. F. Shestakov
Chemical Kinetics and Catalysis


Reactions of the type X• + HCR2CH2NO2 → XH + R2C=CH2 + N•O2 are exothermic, due to the breaking of weak C–N bonds and the formation of energy-intensive C=C bonds. Quantum chemistry calculations of the transition state using the reactions of Et• and EtO• with 2-nitrobutane shows that such reactions can be categorized as one-step, due to the extreme instability of the intermediate nitrobutyl radical toward decay with the formation of N•O2. Kinetic parameters that allow us to calculate the energy of activation and rate constant of such a reaction from its enthalpy are estimated using a model of intersecting parabolas. Enthalpies, energies of activation, and rate constants are calculated for a series of reactions with the participation of Et•, EtO•, RO•2, N•O2 radicals on the one hand and a series of nitroalkanes on the other. A new kinetic scheme of the chain decay of nitroalkanes with the participation of abstraction reactions with concerted fragmentation is proposed on the basis of the obtained data.


rate constant density functional method model of intersecting parabolas nitroalkane abstraction with fragmentation free radicals energy of activation enthalpy of reaction chain decay of nitroalkanes 


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© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  1. 1.Institute of Problems of Chemical PhysicsRussian Academy of SciencesChernogolovka, Moscow oblastRussia

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