Russian Journal of Physical Chemistry A

, Volume 92, Issue 4, pp 663–668 | Cite as

Hydrogenation of Anthracene and Dehydrogenation of Perhydroanthracene on Pt/C Catalysts

  • A. N. Kalenchuk
  • A. E. Koklin
  • V. I. Bogdan
  • V. V. Lunin
Chemical Kinetics and Catalysis
  • 8 Downloads

Abstract

The hydrogenation of anthracene on a heterogeneous catalyst containing 3 wt % Pt/C (Aldrich) at 215, 245, and 280°C and the pressures of 40 and 90 atm is studied. The hydrogenation of anthracene to a completely hydrogenated product is considered in detail. The final product (perhydroanthracene) consists of five conformational isomers with total selectivity of more than 99%. The ratio of perhydroanthracene isomers in the end product is shown to be determined by the conditions (P, T) of hydrogenation. The rate of hydrogenation is found to slow upon an increase in the degree of benzene ring saturation. A mixture of perhydroanthracene isomers is dehydrogenated in an autoclave at 260−325°C on 3 wt % Pt/C catalyst (Aldrich) and in a flow reactor at 300–360°C on 3 wt% Pt/Sibunit catalyst. The reactivity of perhydroanthracene isomers in dehydrogenation is shown to differ.

Keywords

catalysis hydrogenation of anthracene dehydrogenation of perhydroanthracene 

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • A. N. Kalenchuk
    • 1
    • 2
  • A. E. Koklin
    • 2
  • V. I. Bogdan
    • 1
    • 2
  • V. V. Lunin
    • 1
  1. 1.Department of ChemistryMoscow State UniversityMoscowRussia
  2. 2.Zelinsky Institute of Organic ChemistryRussian Academy of SciencesMoscowRussia

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