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Russian Journal of Physical Chemistry A

, Volume 92, Issue 4, pp 799–803 | Cite as

Krafft Temperature of 1-Alkyl-4-Aza-1-Azoniabicyclo[2.2.2]octane Bromide Complexes with Transition Metal Salts

  • M. R. Ibatullina
  • E. P. Zhil’tsova
  • S. S. Lukashenko
  • M. M. Anuar
  • M. P. Kutyreva
  • L. Ya. Zakharova
Colloid Chemistry and Electrochemistry
  • 19 Downloads

Abstract

The Krafft temperature (ТKr) of 1-alkyl-4-aza-1-azoniabicyclo[2.2.2]octane bromides (Alk = n-C n H2n + 1, n = 14, 16, 18) (D-n) and complexes of them with transition metals [Cu(II), Ni(II), Co(II), La(III)] in water is determined via conductometry and compared their corresponding acyclic analogs (alkyltrimethylammonium bromides). The dependence of the complexes’ ТKr on the structure of the inorganic salts and the hydrophobicity of ligands is established. It is shown that the complexation of D-n with metal nitrates and the shortening of the ligand hydrocarbon radical reduce ТKr.

Keywords

cationic surfactants transition metals complexes the Krafft temperature conductometry 

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • M. R. Ibatullina
    • 1
  • E. P. Zhil’tsova
    • 1
  • S. S. Lukashenko
    • 1
  • M. M. Anuar
    • 1
  • M. P. Kutyreva
    • 2
  • L. Ya. Zakharova
    • 1
  1. 1.Arbuzov Institute of Organic and Physical ChemistryRussian Academy of SciencesKazanRussia
  2. 2.Kazan (Volga Region) Federal UniversityKazanRussia

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