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Russian Journal of Physical Chemistry A

, Volume 92, Issue 4, pp 724–729 | Cite as

The Temperature Effect on the Transport Properties of 1-Alkyl-3-methylimidazolium Bis(trifluoromethylsulfonyl)imide Ionic Liquids

  • E. P. Grishina
  • N. O. Kudryakova
  • L. M. Ramenskaya
  • Yu. A. Fadeeva
Physical Chemistry of Solutions
  • 19 Downloads

Abstract

The temperature dependences of specific and equivalent conductivities, viscosity, density, and crystallization temperature are determined for three 1-alkyl-3-methylimidazolium bis(trifluoromethylsulfonyl) imide ([C n MeIm] [Tf2N], n = 2, 3, 4) ionic liquids saturated with water vapor at room temperature. It is established that in the area of positive temperatures, the relationship between viscosity and conductivity obeys the fractional Walden rule with exponents of 0.97, 0.92, and 0.92 for ionic liquids with ethyl-, propyl-, butylradicals, respectively. The temperature dependences of conductivity and viscosity are approximated using the Vogel–Fulcher–Tammann equation (R2 > 0.999), and ideal glass transition temperatures T0 are calculated for the investigated liquids. The obtained values of T0 depend largely on the chosen range of temperatures. It is shown that [C2MeIm][Tf2N] occupies a separate position with regard to [C3MeIm][Tf2N] and [C4MeIm][Tf2N].

Keywords

dialkylimidazolium ionic liquids electrical conductivity viscosity density temperature dependence glass transition temperature 

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • E. P. Grishina
    • 1
    • 2
  • N. O. Kudryakova
    • 1
  • L. M. Ramenskaya
    • 1
  • Yu. A. Fadeeva
    • 1
  1. 1.Krestov Institute of Solution ChemistryRussian Academy of SciencesIvanovoRussia
  2. 2.Ivanovo State University of Chemistry and TechnologyIvanovoRussia

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