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Oxidation and Destruction of Polyvinyl Alcohol under the Combined Action of Ozone–Oxygen Mixture and Hydrogen Peroxide

  • Chemical Kinetics and Catalysis
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Abstract

The oxidative transformations of a polyvinyl alcohol in aqueous solutions are studied under the simultaneous action of the two oxidizing agents, an ozone–oxygen mixture and a hydrogen peroxide. Effective parameters a and b, which characterize the first and second channels of carboxyl group accumulation, respectively, grow linearly upon an increase in the initial concentration of H2O2. After the temperature dependence of a and b parameters (331–363 K) in a PVA + O3 + O2 + H2O2 + H2O reaction system is studied, the parameters of the activation of COOH group accumulation are found (where PVA is a polyvinyl alcohol). New data on the effect process conditions (length of oxidation, temperature, and hydrogen peroxide concentration) have on the degree of destructive transformations of polyvinyl alcohol in the investigated reaction system are obtained.

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References

  1. S. N. Ushakov, Polyvinyl Alcohol and Its Derivatives (Akad. Nauk SSSR, Moscow, 1960), Vol. 1 [in Russian].

    Google Scholar 

  2. A. F. Nikolaev and G. I. Okhrimenko, Water-Soluble Polymers (Khimiya, Moscow, 1979) [in Russian].

    Google Scholar 

  3. Yu. S. Zimin, A. F. Ageeva, A. V. Yanysheva, et al., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol. 47 3, 119 (2004).

    CAS  Google Scholar 

  4. Yu. S. Zimin, A. F. Ageeva, K. G. Serebrennikova, et al., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol. 47 4, 37 (2004).

    CAS  Google Scholar 

  5. Yu. S. Zimin, I. M. Borisov, A. F. Ageeva, et al., Vestn. Bashk. Univ., No. 4, 35 (2005).

    Google Scholar 

  6. Yu. S. Zimin, A. F. Ageeva, I. M. Borisov, and Yu. B. Monakov, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol. 49 1, 52 (2006).

    CAS  Google Scholar 

  7. Yu. S. Zimin, A. F. Ageeva, I. M. Borisov, and Yu. B. Monakov, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol. 49 2, 58 (2006).

    CAS  Google Scholar 

  8. Yu. S. Zimin, A. F. Ageeva, G. F. Kadyrova, et al., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol. 49 6, 30 (2006).

    CAS  Google Scholar 

  9. Yu. S. Zimin, A. F. Ageeva, I. F. Shamsetdinova, et al., Bashk. Khim. Zh. 13, 118 (2006).

    CAS  Google Scholar 

  10. Yu. S. Zimin, Doctoral (Chem.) Dissertation (Inst. Org. Chem. Ural Sci. Center of RAS, Ufa, 2006).

    Google Scholar 

  11. A. F. Valieva, Cand. Sci. (Chem.) Dissertation (Inst. Org. Chem. Ural Sci. Center of RAS, Ufa, 2007).

    Google Scholar 

  12. Yu. S. Zimin, I. M. Borisov, N. S. Borisova, and A. G. Mustafin, Int. J. Chem. Kinet. 45, 821 (2013).

    Article  CAS  Google Scholar 

  13. G. G. Kutlugil’dina, D. K. Zinnatullina, and Yu. S. Zimin, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol. 58 4, 22 (2015).

    Google Scholar 

  14. Yu. S. Zimin, G. G. Kutlugil’dina, and A. G. Mustafin, Russ. J. Phys. Chem. A 90, 1993 (2016).

    Article  CAS  Google Scholar 

  15. V. P. Vendillo, Yu. M. Emel’yanov, and Yu. V. Filippov, Zavod. Lab. 25, 1401 (1959).

    CAS  Google Scholar 

  16. S. R. Rafikov, V. P. Budtov, and Yu. B. Monakov, Introduction to the Physical Chemistry of Polymer Solutions (Nauka, Moscow, 1978) [in Russian].

    Google Scholar 

  17. A. K. Pikaev and S. A. Kabakchi, Reactivity of Primary Products of Water Radiolysis (Energoizdat, Moscow, 1982) [in Russian].

    Google Scholar 

  18. E. T. Denisov and T. G. Denisova, Russ. Chem. Bull. 34, 29 (1994).

    Article  Google Scholar 

  19. N. S. Gus’kova, G. R. Timerbaeva, O. I. Valieva, et al., Butler. Soobshch. 27 13, 29 (2011).

    Google Scholar 

  20. Yu. S. Ovodov, Russ. J. Bioorg. Chem. 35, 269 (2009).

    Article  CAS  Google Scholar 

  21. A. N. Round, N. M. Rigby, A. J. MacDougall, et al., Carbohydr. Res. 331, 337 (2001).

    Article  CAS  Google Scholar 

  22. S.-H. Yoo, M. L. Fishman, A. T. Hotchkiss, et al., Food Hydrocoll. 20, 62 (2006).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Bashkir State University, Ufa, 450076, Russia

    Yu. S. Zimin, G. G. Kutlugil’dina & A. G. Mustafin

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  1. Yu. S. Zimin
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  2. G. G. Kutlugil’dina
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  3. A. G. Mustafin
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Correspondence to Yu. S. Zimin.

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Zimin, Y.S., Kutlugil’dina, G.G. & Mustafin, A.G. Oxidation and Destruction of Polyvinyl Alcohol under the Combined Action of Ozone–Oxygen Mixture and Hydrogen Peroxide. Russ. J. Phys. Chem. 92, 419–423 (2018). https://doi.org/10.1134/S003602441803038X

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  • DOI: https://doi.org/10.1134/S003602441803038X

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