Abstract
Data on the effect temperature has on the kinetics of the removal of Co2+ and Ni2+ ions under static conditions by a sorbent based on a derivative of phytic acid fabricated from rice production waste are presented. It is shown that when the temperature is raised from 20 to 60°C, the sorption capacity of the sorbent based on phytic acid increases over the period of sorption and within 180 min reaches values of 1.4 mmol g−1 for Co2+ ions and 1.3 mmol g−1 for Ni2+ ions. It is established that for the investigated range of temperatures, order n of the sorption of Co2+ and Ni2+ ions is <1, which characterizes the reactions accompanied by diffusion processes. It is found that the process of removal of Co2+ and Ni2+ ions is characterized with low activation energy (20.74 kJ mol−1 for Co2+ ions and 14.2 kJ mol−1 for Ni2+ ions). It is also demonstrated that the sorption process in the considered time frame is best described by a kinetic model of a pseudo-second order, as is indicated by respective correlation coefficients.
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Yarusova, S.B., Makarenko, N.V., Gordienko, P.S. et al. Effect of Temperature on the Kinetics of Sorption of Co2+ and Ni2+ Ions by a Sorbent Based on an Inositol Hexaphosphoric Acid Derivative. Russ. J. Phys. Chem. 92, 559–564 (2018). https://doi.org/10.1134/S0036024418030354
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DOI: https://doi.org/10.1134/S0036024418030354