Skip to main content

Preparation and Properties of Hybrid Nanostructures of Zinc Tetraphenylporphyrinate and an Amphiphilic Copolymer of N-Vinylpyrrolidone in a Neutral Aqueous Buffer Solution

Russian Journal of Physical Chemistry A volume 92, pages 329–333 (2018)Cite this article

Abstract

Water-soluble forms of a hydrophobic dye, zinc tetraphenylporphyrinate, are obtained via its solubilization by polymer particles of the micellar type formed by a copolymer of N-vinylpyrrolidone with triethylene glycol dimethacrylate. Hydrodynamic radii Rh and the size distribution of such particles in neutral aqueous buffer solutions are determined via dynamic light scattering. The electrochemical activity of the encapsulated dye is found, and its photochemical properties (absorption and fluorescence) are studied.

This is a preview of subscription content, access via your institution.

Access options

Buy single article

Instant access to the full article PDF.

USD 39.95

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

References

  1. G. D. Zanelli and A. C. Kaelin, Br. J. Radiol. 54 (641), 403 (1981).

    Article  CAS  Google Scholar 

  2. N. J. Patronas, J. S. Cohen, R. H. Knop, et al., Cancer Treat. Rep. 70, 391 (1986).

    Google Scholar 

  3. S. V. Kurmaz, N. A. Obraztsova, A. A. Balakina, and A. A. Terent’ev, Russ. Chem. Bull. 65, 2097 (2016).

    Article  CAS  Google Scholar 

  4. Y. Zhou and D. Yan, Chem. Commun., No. 10, 1172 (2009).

    Article  Google Scholar 

  5. Y. Zhou, W. Huang, J. Liu, and D. Yan, Adv. Mater. 22, 4567 (2010).

    Article  CAS  Google Scholar 

  6. S. V. Kurmaz and N. A. Obraztsova, Mendeleev Commun. 25, 350 (2015).

    Article  CAS  Google Scholar 

  7. S. V. Kurmaz, N. A. Obraztsova, E. O. Perepelitsina, et al., Mater. Today Commun. 4, 130 (2015).

    Article  CAS  Google Scholar 

  8. S. V. Kurmaz, N. A. Obraztsova, and A. V. Ivanchikhina, High Energy Chem. 48, 42 (2014).

    Article  CAS  Google Scholar 

  9. A. G. Krivenko, A. S. Kotkin, and V. A. Kurmaz, Russ. J. Electrochem. 41, 122 (2005).

    Article  CAS  Google Scholar 

  10. J. Zhang, T. Abe, and M. Kaneko, J. Porphyr. Phthalocyan. 2, 93 (1998).

    Article  CAS  Google Scholar 

  11. S. Yoshimoto, E. Tsutsumi, K. Suto, Y. Honda, and K. Itaya, Chem. Phys. 319, 147 (2005).

    Article  CAS  Google Scholar 

  12. The Porphyrin Handbook, Ed. by K. M. Kadish, K. M. Smith, and R. Guilard (Academic, New York, 2000), Vols. 1–20.

  13. Fan Yanru, Huang Yu, Wang Shixia, et al., Electrochim. Acta 190, 419 (2016).

    Article  Google Scholar 

  14. D. J. Gavaghan and S. W. Feldberg, J. Electroanal. Chem. 491, 103 (2000).

    Article  CAS  Google Scholar 

  15. N. A. Aksenova, M. A. Savko, O. Ya. Uryupina, V. I. Roldugin, P. S. Timashev, P. G. Kuz’min, G. A. Shafeev, and A. B. Solov’eva, Russ. J. Phys. Chem. A 91, 124 (2017).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Science, Chernogolovka, Moscow oblast, 142432, Russia

    S. V. Kurmaz, V. Yu. Gak, V. A. Kurmaz & D. V. Konev

Authors
  1. S. V. Kurmaz
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. Yu. Gak
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. A. Kurmaz
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. D. V. Konev
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to S. V. Kurmaz.

Rights and permissions

Reprints and Permissions

About this article

Verify currency and authenticity via CrossMark

Cite this article

Kurmaz, S.V., Gak, V.Y., Kurmaz, V.A. et al. Preparation and Properties of Hybrid Nanostructures of Zinc Tetraphenylporphyrinate and an Amphiphilic Copolymer of N-Vinylpyrrolidone in a Neutral Aqueous Buffer Solution. Russ. J. Phys. Chem. 92, 329–333 (2018). https://doi.org/10.1134/S0036024418020152

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036024418020152

Keywords

  • amphiphilic copolymer
  • zinc tetraphenylporphyrinate
  • solubilization
  • absorption
  • fluorescence
  • cyclic voltammetry