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Magnetic Interaction between Iron Particles in Lithium Phosphate Systems

Russian Journal of Physical Chemistry A volume 91, pages 2686–2689 (2017)Cite this article

Abstract

The glasses from the system xFe2O3(100 – x)[P2O5 · Li2О] with 0 < x < 50 mol % are studied. These materials have been prepared and characterized by magnetic susceptibility. Iron ions generally modify in different ways the local structure of these glasses, depending on the presence of Li2O in the glass matrix. The results have shown the presence of antiferromagnetic or ferromagnetic interactions between iron ions in the studied glass and temperature range. These data revealed that the valence states and the distribution of iron ions in the glass matrix depend on the Fe2O3 content, and can determine the decreasing of magnetic momentum (μeff).

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Authors and Affiliations

  1. Technical University of Cluj Napoca, North University Center of Baia Mare, Baia Mare, 430122, Romania

    C. Andronache & D. Racolta

  2. Joint Institute for Nuclear Research, Dubna, Moscow oblast, Russia

    M. Balasoiu

  3. Horia Hulubei National Institute of Physics and Nuclear Engineering, Magurele, Romania

    M. Balasoiu

Authors
  1. C. Andronache
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  2. M. Balasoiu
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  3. D. Racolta
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Correspondence to D. Racolta.

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Andronache, C., Balasoiu, M. & Racolta, D. Magnetic Interaction between Iron Particles in Lithium Phosphate Systems. Russ. J. Phys. Chem. 91, 2686–2689 (2017). https://doi.org/10.1134/S0036024417130039

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  • DOI: https://doi.org/10.1134/S0036024417130039

Keywords

  • lithium phosphate glasses
  • magnetic properties
  • magnetic susceptibility