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Reactivity and mechanism of the action of C60 fullerene used as an inhibitor for the radical chain oxidation of 1,4-dioxane

  • Chemical Thermodynamics and Thermochemistry
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Abstract

The kinetics and mechanism of the antioxidative action of С60 fullerene are studied via highly sensitive manometry and kinetic spectrophotometry, based on the example of a model reaction of the initiated oxidation of 1,4-dioxane. The adequacy of the proposed mechanism according to the experimental data is analyzed by means of mathematical modeling. The mechanism behind the inhibiting process is found to be a multi-center radical reaction. The rate constants of the elementary stages are determined.

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Correspondence to A. Ya. Gerchikov.

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Original Russian Text © A.Ya. Gerchikov, G.M. Sharipova, I.V. Safarova, M.V. Sakhibgareeva, S.I. Spivak, 2017, published in Zhurnal Fizicheskoi Khimii, 2017, Vol. 91, No. 6, pp. 957–962.

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Gerchikov, A.Y., Sharipova, G.M., Safarova, I.V. et al. Reactivity and mechanism of the action of C60 fullerene used as an inhibitor for the radical chain oxidation of 1,4-dioxane. Russ. J. Phys. Chem. 91, 1010–1014 (2017). https://doi.org/10.1134/S0036024417060103

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  • DOI: https://doi.org/10.1134/S0036024417060103

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