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Efficient Generation of Chemiluminescence during the reduction of manganese(IV) ions with lactic acid

  • Photochemistry and Magnetochemistry
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Abstract

The kinetics and mechanism of chemiluminescence during the reduction of manganese(IV) ions with lactic acid in an H2SO4–AcOH medium are studied. Kinetic spectrophotometric measurements are used to determine the profiles of change in the concentrations of Mn(IV) and Mn(III) ions during the reaction. The results from kinetic spectrophotometric measurements are compared to the light yield kinetics. The quantum chemiluminescence and chemiexcitation yields reach record values.

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Authors and Affiliations

  1. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, Moscow, 119991, Russia

    Yu. B. Tsaplev

  2. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow, 119991, Russia

    Yu. B. Tsaplev

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  1. Yu. B. Tsaplev
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Correspondence to Yu. B. Tsaplev.

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Original Russian Text © Yu.B. Tsaplev, 2016, published in Zhurnal Fizicheskoi Khimii, 2016, Vol. 90, No. 12, pp. 1894–1900.

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Tsaplev, Y.B. Efficient Generation of Chemiluminescence during the reduction of manganese(IV) ions with lactic acid. Russ. J. Phys. Chem. 90, 2481–2487 (2016). https://doi.org/10.1134/S0036024416120311

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  • DOI: https://doi.org/10.1134/S0036024416120311

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